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EFFECTS OF ACTIVE ELEMENTS Y AND Ce ON HIGH TEMPERATURE OXIDATION OF Fe-25Cr-40Ni ALLOY

YU Fanghua YANG Guohua Shanghai Institute of Nuclear Research , Academia Sinica , Shanghai , ChinaHAN Rongdian WENG Huimin University of Science and Technology of China , Hefei , ChinaSHEN Jianian Corrosion Science Laboratory , Institute of Corrosion and Protection of Metals Academia Sinica , Shenvang , China

金属学报(英文版)

The effects of small amount(≥0.05%)of active elements Y and Ce in Fe-25Cr-40Ni al- loy have been investigated on the kinetics of early stage of high temperature oxidation as well as composition and microsructure of oxide film by ion backscattering and slow positron beam.The results show that Y and Ce can reduce evidently the high tem- perature oxidation rate of FeCrNi alloy at early stage and can effectively enhance the Cr_2O_3 formation and retard the oxide formation of Fe and Ni in the surface layer thus the microstructure of the oxide film is improved.Y and Ce enter the oxide film and concentrate within several tens nanometres from surface of the outer layer.The mech- anism of oxidation resistance for Ce is different from Y.Ce can decrease the density of vacancy defects in oxide layer,so the cations are restrained from diffusion outward through vacancies.While Y can control the outward diffusion of cations through va- cancies at the early statge of oxidation(shorter than 12 min),aften that restrained the cations from diffusion outward along grain boundaries up to 60 min oxidation.

关键词: ion backscattering , null , null , null , null

CORRELATION BETWEEN STRESS COMPONENTS AND STRESS CORROSION CRACKS IN BRASS Lecturer,Department of Materials Physics,University of Science and Technology Beijing,Beijing 100083,China

QIAO Lijie LIU Rui XIAO Jimei University of Science and Technology Beijing , Beijing , China

金属学报(英文版)

The effects of stress components on nucleation sites and propagation directions of stress cor- rosion cracks in brass were investigated with specimens under mode Ⅱ and mode Ⅲ loadings. The results indicated that under mode Ⅱ loading,stress corrosion cracks nucleated on the site with maximum normal stress component and propagated along the plane perpendieular to the maximum normal stress,under mode Ⅲ loading,the stress corrosion crack was not evident on the 45°plane due to the general corrosion in aqueous solution with high NH_4OH concentra- tion,while stress corroded in aqueous solution with low NH_4OH concentration, numerous cracks with spacings of 10—150μm were found on the 45°plane with maximum normal stress and no stress corrosion cracks was observed on the plane with maximum shear stress.

关键词: stress corrosion cracking , null , null , null

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