International Journal of Modern Physics B
We simulate numerically the dynamic properties of new soliton with quasi-coherent two quanta in the improved model by fourth-order Runge-Kutta way. We observed that the window of formation of new soliton is shifted toward smaller values of coupling constants when compared with the Davydov's soliton with one quantum and Forner's soliton with two quantum model. The new soliton formation starts at (chi 1 + chi 2) = 20 PN, and pinning starts from (chi 1 + chi 2) = 86 PN. The pinned solitons are also observed if both quanta are on the same end of the chain in the initial state. The behaviors of new soliton are varied under influences for variations of characteristic parameters arising from the structure nonuniformity of protein molecules. Although the new soliton is also sensitive to the dipole-dipole interaction and diagonal disorder, the sensitivity to the impurity is weaker than that of the Davydov's and Forner's solitons. Therefore, the new soliton is robust against the fluctuations of coupled constant, dipole-dipole interaction and diagonal disorder arising from the impurity or structure nonuniformity, when compared with that of the Davydov's and Forner's solitons.
关键词:
protein;bio-energy transport;soliton;structure nonuniformity;characteristic parameter;davydov soliton;living systems;improved model;thermodynamic;properties;biological temperature;finite-temperature;quantum;dynamics;disorder;lifetime
Feng Shi
材料科学技术（英文）
Precipitation behaviors of Fe-18Cr-18Mn-0.63N and Fe-18Cr-18Mn-2Mo-0.69N high-nitrogen austenitic stainless steels during isothermally aging at 850°C have been investigated by optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). The experimental results show that precipitation displays a discontinuous cellular way and the precipitates are identified as Cr2N in Fe-18Cr-18Mn-0.63N steel. The addition of Mo makes precipitation occur not only at the grain boundary but also inside the grain and precipitation also displays discontinuous cellular way. The precipitates at the grain boundary and in the cell are both identified as Cr2N phase and χ phase and the precipitates inside the grain are identified as Χ phase in Fe-18Cr-18Mn-2Mo-0.69N steel. The nucleations of Χ phase and Cr2N phase at the grain boundary are both governed by the diffusion of Cr atoms. The formation and growth of χ phase inside the grain are induced by the impoverishment of N atoms with increasing aging time.
关键词:
Austenitic stainless steel
向红亮何福善刘东
金属学报
对固溶处理后的铸造超级双相不锈钢材料进行时效处理, 利用OM, SEM, XRD和TEM分析了时效温度对析出相的影响. 结果表明, 固溶后经时效处理, 金属间相在铁素体内和铁素体/奥氏体晶界析出; 650℃时效时, 析出的金属间相主要是χ相; 750℃时效时析出σ相和χ相, 此时σ相由χ相演变而来; 850℃时效下则直接析出σ相; 950℃时效后, 少量的σ相仅在铁素体/奥氏体晶界产生.
关键词:
铸造超级双相不锈钢
,
aging temperatures
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σ phase
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χ phase
杨子元
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魏群
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郝跃
人工晶体学报
doi:10.3969/j.issn.1000-985X.2005.03.024
利用Newman的晶场叠加模型,建立了晶体微观结构与电子顺磁共振(EPR)参量之间的定量关系.采用全组态完全对角化方法,对YAG:V2+晶体的局域晶格畸变及其EPR参量进行了系统的研究,结果表明:V2+离子掺入YAG晶体后,V2+离子的局域结构产生压缩三角晶格畸变,沿[111]晶轴方向V2+离子上方的三个O2-配体与下方的三个O2-配体均偏离[111]轴1.96°,从而成功地解释了YAG:V2+晶体的EPR参量.同时研究也表明,SS与SOO磁相互作用对EPR参量的贡献不可忽略.
关键词:
YAG:V2+晶体
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局域晶格畸变
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EPR参量
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磁相互作用
张松袁广银卢晨丁文江
金属学报
doi:10.3724/SP.J.1037.2010.00177
采用金属型铸造和慢速凝固, 在不同冷却速率下制备了Mg-10Gd-3Y-1.8Zn-0.5Zr(质量分数, %) (GWZ1032K)合金. 采用SEM, TEM和XRD研究了冷却速率不同的GWZ1032K 合金的组织和相构成. 在GWZ1032K合金中, α-Mg基体中的层片状14H-LPSO结构随着冷却速率的下降而增加, 在冷却速率为0.005℃/s的试样中充满了整个晶粒;随着合金冷却速率降低, GWZ1032K合金中晶界第二相分别由5℃/s时的(Mg, Zn)3RE相转变为0.5 和0.1℃/s时的(Mg, Zn)3RE相和14H-LPSO结构的χ相共存;在0.01和0.005℃/s时只有14H-LPSO结构的$\chi$相. 结果显示在接近于平衡凝固的缓慢冷速条件下, 更容易形成具有稳定结构的层片状14H-LPSO结构和χ相.在冷却速率为0.5和0.1℃/s时, (Mg, Zn)3RE共晶相和χ相共存, (Mg, Zn)3RE共晶相和χ相的位向关系为 [110]χ phase//[223](Mg, Zn)3RE和∠g(001)χ phase g(110) (Mg, Zn)3RE=8.4°.
关键词:
14H-LPSO结构
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solidification rate
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Mg-Gd-Y-Zn alloy
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χ phase
Materials Characterization
Segregation of yttrium induces the formation of Y0.25Zr0.75O2-x and Y0.5Zr0.5O2-y microdomains, with L1(2)- and L1(0)-like ordered structures, in ZrO2-6mol%Y2O3 ceramics in both the sintered and annealed states. The compositions of precipitates such as (chi L), (chi S), (chi SS), and small precipitates formed inside XL, in Cu-11.88Al-5.06Ni-1.63Mn-0.96Ti (wt.%) shape memory alloys have been determined. Under electron beam irradiation, four types of dynamic behavior of the G.P. zones were observed in the Al-6.58Zn-2.33Mg-2.40Cu (wt.%) alloy. The G.P. zone and "G.P. zone-like" defect structures were also distinguished. Lattice distortion profile in the GaAs/InxGa1-xAs superlattice and two-dimensional lattice distortion around a 60 degrees dislocation core in the InAs(x)P(1-)x/InP superlattice were determined. (C) Elsevier Science Inc., 2000. All rights reserved.
关键词:
shape-memory alloys;zirconia;phase;ti;diffraction;crystal
Japanese Journal of Applied Physics Part 1-Regular Papers Brief Communications & Review Papers
We report a comparative study among four kinds of polyaniline (PANI) synthesized with four different kinds of acids, under the same conditions for synthesis; PANI-HCl, PANI-H2SO4, PANI-H3PO4 and PANI-C4H6O6. We measured the temperature dependence of the dc conductivity sigma(dc)(T) and the magnetic susceptibility chi(tot)(T) The room-temperature conductivity of HCl and H2SO4-polyaniline was 5-8 times higher than that of H3PO4 and C4H6O6-polyaniline, in which the values of 18.1, 16.8, 3.8 and 1.85 S/cm were found, respectively. The best fit for our de conductivity data was obtained using the quasi-one-dimensional variable-range hopping (QID VRH) model between nearest neighbors. Polyaniline reported in this paper leads to a high magnetic susceptibility chi(tot) (at T = 295 K) of 10(-4) emu/mol.2rings. This is one or two orders of magnitude higher than those reported earlier for polyaniline. Data on sigma(dc)(T) and chi(tot)(T) are also discussed.
关键词:
polyaniline;dc conductivity;magnetic susceptibility;quasi-one-dimensional variable-range hopping;electron localization;charge-transport;emeraldine
