María L. Faroppa
,
Juan J. Musci
,
María E. Chiosso
,
Claudia G. Caggiano
,
Hernán P. Bideberripe
,
José L. García Fierro
,
Guillermo J. Siri
,
Mónica L. Casella
催化学报
doi:10.1016/S1872-2067(16)62531-7
制备了Pd含量为1 wt%、不同Pb/Pd摩尔比的γ-Al2O3负载Pd-Pb双金属催化剂,并用于常压、45°C和pH =11条件下H2O2氧化甘油反应中.催化剂的形貌和分散度采用扫描电镜-X射线电子散射谱和透射电镜进行了表征；双金属催化剂中合金相用X射线光电子能谱进行了验证.单金属Pd催化剂上反应结束后甘油转化率为19%,但随着Pb的加入甘油转化率增大到约100%.所制四个不同Pb/Pd原子比的双金属催化剂PdPb0.25, PdPb0.50, PdPb1.00和PdPb1.60均可氧化甘油至二羟基丙酮(DIHA),反应结束后DIHA选择性分别可达59%,58%,34%和25%.
关键词:
钯
,
双金属钯-铅催化剂
,
过氧化氢
,
甘油氧化
,
甘油酸
,
羟基乙酸
International Journal of Modern Physics B
The perturbation formulae of EPR parameters g factors g(x), g(y) and g(z) for the lowest Kramers doublet of 4f(1) ion in orthorhombic symmetry are established. In these formulae, the contributions of the covalency effects, the admixture between J = 7/2 and J = 5/2 states as well as the second-order perturbation (which is not considered in the previous works) via crystal-field and orbital angular momentum interactions are all included. According to these formulae, and by using the superposition model, the g-factors g., g(y) and g(z) for Ce3+ center in YBa2CU3O6+x superconductor are calculated. The results are discussed.
关键词:
YBa2Cu3O6+x;EPR;superposition model;Ce3+;crystal-field
Optical Materials
The perturbation formulas of the EPR g factors g,, g and g. for a 4f(11) 1 ion in orthorhombic symmetry are established. In these formulas, the contributions to the g factors arising from the second-order perturbation terms and the admixture of various states are taken into account. The above formulas are applied to the orthorhombic Er3+ centers in YAG, YGG and LuGG garnets. By analyzing their g factors, we find that the polar angles theta(j)(') of the impurity-ligand bonds related to the Z axis of the crystals in these Er3+ centers are smaller than the host angles theta(j) in pure crystals, whereas the azimuthal angles, related to the X axis in the impurity centers are larger than the corresponding phi(j) in the hosts. The g factors and their anisotropies Delta g [= g(z) - (g(x) + g(y))/2] and delta g (= g(x) - g(y)) for Er3+ in the garnets based on the above local structural parameters are in good agreement with the observed values. In addition, the angular distortions Delta theta (= theta(j)(') - theta(j)) or Delta phi (= phi(j)(') - phi(j)) obtained by analyzing the EPR data in this work are different from Delta theta(2), or Delta phi(2) (for only the second set of ligands, i.e., j = 2) based on the superposition model crystal-field analysis in the previous work. The validity of the results is discussed. (c) 2004 Elsevier B.V. All rights reserved.
关键词:
electron paramagnetic resonance (EPR);defect structure;crystal-field;and spin hamiltonians;Er3+;garnets
Spectroscopy and Spectral Analysis
The complete high-order perturbation formula of g factor for 3d(3) ions in cubic octahedral site was derived. In the formula, both the contribution Delta g(CF) to g-shift Delta g(=g-g(s), where g(s) =2. 002 3) due to crystal-field (CF) mechanism (related to the interactions of CF excited states with the ground state) and that (Delta g(CT)) due to charge-transfer (CT) mechanism (related to the interactions of CT excited states with the ground state, which is omitted in crystal-field theory) are included. By using the formula and the parameters obtained from the optical spectra of CaZrO(3) : Mn(4+) crystal, the g factor of CaZrO(3) : Mn(4+) was calculated. The result is consistent with the experimental value. The calculations show that the contribution is opposite in sign and about 62% in magnitude compared with the contribution Delta g(CF). It appears that both CF and CT mechanisms should be considered in the calculation of g factor for the high valence 3d(3) (e. g., Mn(4+) and Fe(3+)) ions in crystals.
关键词:
electron paramagnetic resonance;g factor;charge transfer mechanism;crystal and ligand field theory;CaZrO(3);Mn(4+);atomic screening constants;scf functions;luminescence;manganese
Physica B-Condensed Matter
In this paper, by using only one adjustable parameter V' (the trigonal-field parameter), the zero-held splitting D, the g factors g(parallel to) and Delta g (= g(parallel to) -g(perpendicular to)) for CsMgCl3:V2+ crystal have been calculated from the high-order perturbation formulas based on the two spin-orbit coupling parameter model. The calculated results show good agreement with the observed values. A comparison between the calculated results from various crystal field theories are also made. It is found that the difference between signs D and Delta g for CsMgCl3:V2+ crystal is caused by the contributions from the excited multiplets, particularly those arising from the free ionic term (2)G. (C) 1998 Elsevier Science B.V. All rights reserved.
关键词:
crystal and ligand field theory;electron paramagnetic resonance;spin-orbit coupling;V2+ ion;CsMgCl3;crystal;spectra;ions
吴国杰
,
董奋强
,
崔英德
,
李妮妮
,
何春林
材料导报
研究了鱼蛋白(FP)接枝聚合丙烯酸(AA)和丙烯酰胺(AM)制备蛋白改性高吸水性树脂的方法.通过对产品吸(盐)水性能的测试,得到合成产品的合适条件为:鱼蛋白、引发剂和交联剂相对单体的量分别约为7.5%、1.0%和0.025%,丙烯酸与丙烯酰胺的质量比为9:1,丙烯酸中和度为90%,单体质量分数为18%.在此条件下制备的高吸水性树脂,其吸水倍率达1061g/g,吸盐水倍率达136g/g.并用红外光谱对产物进行了表征.
关键词:
鱼蛋白
,
丙烯酸
,
丙烯酰胺
,
接枝
,
高吸水性树脂
Physica B-Condensed Matter
The perturbation formula of g factor for 3d(7) ion in cubic octahedral crystals has been obtained from a cluster approach. In the formula, the parameters related to the configuration interaction and the covalency reduction effect can be obtained from the optical spectra of the crystal under study and so no adjustable parameters are applied. From the formula, the g factors for Co2+ in fluoroperovskites LiBaF3, KMBF3, KZnF3 and CsCdF3 are calculated. The calculated results are in agreement with the observed values. The g factor following the order of LiBaF3 : Co2+ < KMgF3 : Co2+ < KZnF3: Co2+ < CsCdF3 : Co2+ is also explained. (C) 2000 Elsevier Science B.V. All rights reserved.
关键词:
electron paramagnetic resonance;crystal- and ligand-field theory;Co2+;LiBaF3;KMgF3;KZnF3;CsCdF3;perovskite;transition;impurities;crystals
KAVEHArzani
,
BEHDADGhaderiAshtiani
,
AMIRHOSSEINHajiAboutorabKashi
无机材料学报
doi:10.3724/SP.J.1077.2012.12050
Mesoporous carbon CMK-3 was synthesized by using SBA-15 silica mesoporous as hard template and characterized through nitrogen adsorption/desorption and low angle X-ray diffraction. As-prepared material with large pores and high surface area was used to remove Orange G dye from aqueous solution. Adsorption experiments were carried out as batch studies at variety of contact times, pH, initial dye concentrations, temperatures and salt concentrations. Langmuir and Freundlich isotherm models were employed to simulate the equilibrium data of anionic dye. It was found that the equilibrium data were well represented by the Langmuir isotherm, yielding maximum monolayer adsorption capacity of 189 mg/g. Experimental data were analyzed using pseudo-first order and pseudo-second order kinetic models and obtained results indicated that kinetics followed a pseudo-second order equation.
关键词:
CMK-3; Orange G; adsorption isotherm; kinetic
