HL. Huang
,
J.H Xing
,
G.L. Liu and G.Y Zhang(Department of Electrouic Science and Engineering
,
Liaoning University Shenyang 110036
,
China)(Department of Physics
,
Liaoning University Shenyang 110036
,
China)(Shenyang Polytechnic University Shenyan 110023
,
China)(Northeast Microelectronic Institute of Ministry of Electronic Industry Shenyang 110032
,
China)
金属学报(英文版)
The electronic structures of (CdSe)n/(ZnSe)m strained-lager soperfattice (SLS) were investigated by the recursion method in the tight-bindiop opproximation. The total,local, and partial density of states were calculated for n=1, m=5.The total density of states (TDOS) for bulk CdSe, ZnSe and n=1, 3, m=1, 3, 5, for SLS were investigated.Fermi energy, the band gap, the valence of an atom, and the ionization potential and the electron affinity were discassed.
关键词:
density of state
,
null
,
null
,
null
,
null
Journal of Superconductivity and Novel Magnetism
The local structure and the g factors (g(x), g(y), and g(z)) of the Cu(2+) site in Y(2)BaCuO(5) are theoretically studied using the perturbation formulas of the g factors for a 3d(9) ion in orthorhombically elongated octahedra. The orthorhombic field parameters in these formulas are determined from the superposition model and the local geometry of the system. From the calculations, the oxygen octahedron is found to undergo the local elongation Delta Z (approximate to 0.05 angstrom) along c-axis and the relative bond length variation Delta X (approximate to 0.1 angstrom) along a- and b-axes, respectively. The calculated g factors based on the above local structure are in good agreement with the experimental data. The relationships between the anisotropies of the g factors and the low symmetrical (orthorhombic) distortions of the Cu(2+) site in Y(2)BaCuO(5) are discussed.
关键词:
Crystal fields and spin Hamiltonians;Electron paramagnetic resonance;Cu(2+);Y(2)BaCuO(5);crystal
于萍
,
王亚权
腐蚀学报（英文）
研究了添加0.1mass%稀土Y的铸造K38G高温合金在1000℃的恒温氧化行为.结果表明,较之不含Y的合金，含Y铸态K38G合金的氧化速率显著降低； 氧化时形成双层的外氧化膜，表层为以Cr2O3和TiO.2为主的混合氧化物层，内层为连续的Al2O3层；没有内氧化和内氮化，没有氧化膜的剥落，加入稀土Y有效地提高了氧化膜的粘附性能.
关键词:
高温氧化
,
null
,
null
,
null
于萍
,
王亚权
腐蚀学报（英文）
doi:10.3969/j.issn.1002-6495.2007.03.010
研究了添加0.1 mass%稀土Y的铸造K38G高温合金在1000℃的恒温氧化行为.结果表明,较之不含Y的合金,含Y铸态K38G合金的氧化速率显著降低;氧化时形成双层的外氧化膜,表层为以Cr2O3和TiO2为主的混合氧化物层,内层为连续的Al2O3层;没有内氧化和内氮化,没有氧化膜的剥落,加入稀土Y有效地提高了氧化膜的粘附性能.
关键词:
高温氧化
,
K38G
,
高温合金
,
稀土元素
,
Y
于萍
,
王亚权
,
王文
腐蚀学报（英文）
对加入0.05mass%～0.5mass%稀土Y铸造的K38G高温合金800 ℃恒温的氧化行为进行了研究.结果表明,含Y铸态K38G合金的氧化动力学曲线偏离了抛物线规律，接近于立方规律；Y有效抑制了该合金的内氧化；当Y含量达0.5mass%时，该合金中析出富Y相，降低了其氧化抗力.
关键词:
高温氧化
,
null
,
null
袁诗璞
电镀与涂饰
氯化钾镀锌液配方中,氯化钾的含量通常是200～ 250 g/L,但在生产维护时分析镀槽中的氯化钾有时高达近400 g/L.认为以EDTA滴定法及硝酸银滴定法分别测总锌与总氯,然后从总氯中减去氯化锌所占氯的量而计算出氯化锌含量的常规化验方法有一定的局限性,尤其不适用于大生产已久的镀液.介绍了控制氯化钾含量的方法:先调整pH,接着通过赫尔槽试验分析并调整锌离子浓度,然后分析并调整光亮剂及硼酸,最后通过试验确定氯化钾补加量.
关键词:
镀锌
,
氯化钾
,
分析
,
调整
,
赫尔槽试验
Physica Status Solidi B-Basic Research
The perturbation formulas of EPR g factors g(\\) g(perpendicular to) and hyperfine structure constants A(\\) A(perpendicular to) for the trigonal octahedral 3d(7) cluster are derived considering not only the configuration interaction effect due to the admixture among ground and excited states, but also the covalency effect due to the admixture between the d electrons of the 3d(7) ion and the p electrons of ligands. In these formulas, the parameters related to both effects and the trigonal field parameters are estimated from the optical spectra and the structural parameters of the studied system. According to these formulas, the EPR parameters g(\\), g(perpendicular to), A(\\) and A(perpendicular to) for Co2+ in the octahedral sites of Y3Al5O12 and Y3Ga5O12 garnets are satisfactorily explained from the optical spectra and the structure data. The role of the covalency effect is discussed.
关键词:
superposition model;phase-transition;absorption;linbo3;ions
