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LC4铝合金稀土转化膜耐蚀性及影响因素

张巍 , 李久青 , 许江涛 , 陈昆

腐蚀学报(英文) doi:10.3969/j.issn.1002-6495.1999.06.004

开发了IC4铝合金稀土转化膜碱性两步成膜工艺ZH1,利用正交优化设计方法确定了最佳工艺参数.采用多种实验方法研究了经ZH1处理的LC4铝合金在氯化物环境中的耐蚀性及其影响因素,结果表明:经ZHI工艺处理过的LC4铝合金耐全面腐蚀和点蚀性能均有明显提高,稀土转化膜既抑制了腐蚀的阴极过程,也抑制了阳极过程.具有ZH1转化膜的LC4铝合金对氯离子浓度和pH值的变化不甚敏感.

关键词: 高强铝合金 , 稀土转化膜 , 耐蚀性学科

Intensified alkaline leaching pretreatment of refractory gold concentrates at common temperature and pressure

Transactions of Nonferrous Metals Society of China

A new process for the hydrometallurgy of refractory gold concentrates was presented. The process comprises grinding-leaching, intensified alkaline leaching (IAL), cyanidation and adsorption. In a stirring-type pulverizing-leaching tower mill, the concentrate is ground to <35. 6 μm of 95. 5 % while simultaneously leached by NaOH of 12 kg/t, then carried out intensified alkaline leaching for 48 h by NaOH of 108 kg/t in enhanced agitation tanks with the pulp concentration of 40% solids at the environmental temperature of 9. 5 &SIM; 13. 5 &DEG;C and the environmental pressure of 10(5) Pa. The oxidation rate of As is 94. 9%, and 47. 6% for S. The total consumption of NaOH is only 20% of that theoretically calculated under the conditions of full oxidation at the same oxidation rates of arsenic to arsenate and sulfur to sulfate. The gold leaching rate by NaCN in 24 h is increased from 9. 2% before pretreatment to 94. 2%. The consumption of NaCN is 7. 5 kg/t, which is one times less than that before pretreatment. The extraction cost of gold is about 422 Yuan/t.

关键词: refractory gold concentrates;grinding-leaching;intensified alkaline;leaching (IAL);pretreatment;common temperature and pressure

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