刘文鹏
,
张庆礼
,
杨华军
,
周鹏宇
,
孙敦陆
,
高进云
,
谷长江
,
罗建乔
,
王迪
,
殷绍唐
量子电子学报
doi:10.3969/j.issn.1007-5461.2011.02.018
采用固相反应法制备了Bi3+、Eu3+、Tb3+掺杂的Lu3TaO7.测量了样品的X射线衍射谱、激发和发射光谱及荧光衰减曲线.三种离子掺杂的Lu3TaO7均呈现出强的荧光发射,其中Bi3+具有峰位在431 nm处的一强发射宽带,衰减寿命为16.8μs,Eu3+、Tb3+则表现出稀土离子的特征锐发射峰,衰减寿命分别为1.26 ms和1.20 ms.因此,它们均是具有潜在应用前景的重闪烁体材料.
关键词:
材料
,
闪烁体
,
Lu3TaO7
,
发光
季振国
,
周荣福
,
毛启楠
,
霍丽娟
,
曹虹
无机材料学报
doi:10.3724/SP.J.1077.2009.09217
利用反应磁控溅射法制备了半导体锡锑氧化物薄膜 (TAO). 根据霍尔效应测试结果,当Sn/Sb 原子比处于0.22~0.33范围内时,TAO薄膜是p型导电的,在此范围之外,TAO薄膜是n型导电的. 光学带隙测量结果表明,不同Sn/Sb比的TAO薄膜的禁带宽度基本相同(～3.9eV).构造了一个全透明的PN结,其中n区为Sn/Sb原子比为0.5的TAO薄膜, p区为Sn/Sb原子比为0.33的TAO薄膜.n区TAO的电极用铟锡氧化物(ITO),p区TAO的电极用Cu薄膜.实验结果表明,由于两种导电类型的TAO薄膜具有相同的禁带宽度,上述透明PN结构具有典型的准同质PN结的整流特性.
关键词:
透明半导体薄膜
,
锡锑氧化物
,
PN结
Nuclear Engineering and Design
Liquid droplet erosion (LDE), which often occurs in bellows made of nickel-based alloys, threatens the security operation of the nuclear power plant. As the candidate materials of the bellows, Inconel 600 and Inconel 625 were both tested for resistance to cavitation erosion (CE) and jet impingement erosion (JIE) through vibratory cavitation equipment and a jet apparatus for erosion-corrosion. Cumulative mass loss vs. exposure time was used to evaluate the erosion rate of the two alloys. The surface and cross-sectional morphologies before and after the erosion tests were observed by scanning electron microscopy (SEM), the inclusions were analyzed by an energy dispersive spectroscopy (EDS), and the surface roughness was also measured by surface roughness tester to illustrate the evolution of erosion process. The results show that the cumulative mass loss of CE of Inconel 625 is about 1/6 that of Inconel 600 and the CE incubation period of the Inconel 625 is 4 times as long as that of the Inconel 600. The micro-morphology evolution of CE process illustrates that the twinning and hardness of the Inconel 625 plays a significant role in CE. In addition, the cumulative mass loss of JIE of Inconel 625 is about 2/3 that of Inconel 600 at impacting angle of 90 degrees, and almost equal to that of the Inconel 600 at impacting angle of 30 degrees. Overall, the resistance to CE and JIE of Inconel 625 is much superior to that of Inconel 600. (C) 2010 Elsevier By. All rights reserved.
关键词:
stress-corrosion cracking;aluminide intermetallic alloys;high-purity;water;mechanical-properties;crevice corrosion;solid particles;wear;behavior;microstructure;deformation;steam
Nuclear Engineering and Design
A composite coating was deposited on Inconel 600 substrate by cold spray method using pure Ni powder (60 wt.%) blended with alpha-Al(2)O(3) (40 wt.%) as feedstock. It is expected to be applied to repair the bellows eroded by the liquid droplet erosion (LDE). Microstructure of the coating was observed using optical microscope (OM) and scanning electron microscopy (SEM). Microhardness of the coating was determined by Vickers hardness tester. Cavitation erosion (CE) experiments were carried out in the distilled water. Jet impingement erosion (JIE) experiments were performed in slurry containing 1 wt.% quartz particle with the flow velocity of 15 m/s at impingement angles of 30 degrees, 60 degrees and 90 degrees, respectively. Cumulative mass loss vs. testing time was used to evaluate the erosion rate of the coating. The erosion mechanism was analyzed by OM, SEM, X-ray diffraction (XRD) and the microhardness measurement. The results show that the composite coating has compact microstructure and relatively high hardness. The resistance to CE of the coating is not as good as that of Inconel 600 substrate due to the weak bonds of the Al(2)O(3) particles. However, the results of the JIE test indicate that the slurry erosion resistance of the coating is better than that of Inconel 600 at the impact angles of 30 degrees and 60 degrees, but not at the normal impact angle. (C) 2011 Elsevier B.V. All rights reserved.
关键词:
large powder particles;composite coatings;slurry erosion;kinetic;spray;liquid impact;alloy;microstructure;steels;deposition;resistance
Physics of Life Reviews
Commentaries by Philip W.T. Pong, Nongyue He, S.D. Liang, Tao Song, Yuri Gaididei and Sergey Volkov and Alexander Y. Grosberg on my review article (Pang, 2011 [1]) are answered. The validity of Davydov's mechanism of bio-energy transport, the completeness of theory, outstanding problems, the normalization and validity of wave function of the system in Pang' model as well as other related problems are elucidated in detail. (C) 2011 Elsevier B.V. All rights reserved.
关键词:
biological temperature;3 channels;soliton;model
成艳
,
蔡伟
,
李洪涛
,
郑玉峰
,
赵连城
功能材料
采用多弧离子镀的方法在Ti-50.6%(原子分数)Ni形状记忆合金表面沉积了钽镀层.通过X射线光电子能谱(XPS)剖面分析发现TiNi合金表面钽镀层厚度均匀,并且在镀层与基体之间形成一薄层过渡层.将镀钽TiNi合金曝露于空气中后,通过XPS的全谱和高分辨谱图对其表面的成分和价态分析发现,镀钽层表面由于钽在空气中自然氧化形成了一层很薄的钽的氧化膜,最表面为高价钽的氧化物(Ta2O5),次表面为低价钽氧化物的混合物TaO2、TaO和TaOx(x＜1).
关键词:
TiNi形状记忆合金
,
多弧离子镀
,
钽
,
镀层
李江鸿
,
张红波
,
熊翔
,
肖鹏
,
黄伯云
稀有金属材料与工程
报道了一种在C/C复合材料基体上制各抗烧蚀TaC涂层的新方法.采用红外光谱、XRD及SEM表征了生成TaC涂层的Ta源:TaO2F·rH2O·TaF5.采用SEM观察了不同温度下转变生成的TaC涂层的形貌.在1200℃高温热处理,TaC涂层形貌为细颗粒状,在1800℃高温热处理后,TaC涂层为柱状晶.TaC的生成机制为:TaO2F·rH2O·TaF5高温分解凝聚生成的Ta2O5沉积在C/C复合材料基体表面,碳原子在Ta2O5中扩散反应生成TaC,TaC涂层形貌可由生成Ta2O5的凝聚成核理论解释.
关键词:
TaC涂层
,
制备
,
生成机制
