Nuclear Engineering and Design
Liquid droplet erosion (LDE), which often occurs in bellows made of nickel-based alloys, threatens the security operation of the nuclear power plant. As the candidate materials of the bellows, Inconel 600 and Inconel 625 were both tested for resistance to cavitation erosion (CE) and jet impingement erosion (JIE) through vibratory cavitation equipment and a jet apparatus for erosion-corrosion. Cumulative mass loss vs. exposure time was used to evaluate the erosion rate of the two alloys. The surface and cross-sectional morphologies before and after the erosion tests were observed by scanning electron microscopy (SEM), the inclusions were analyzed by an energy dispersive spectroscopy (EDS), and the surface roughness was also measured by surface roughness tester to illustrate the evolution of erosion process. The results show that the cumulative mass loss of CE of Inconel 625 is about 1/6 that of Inconel 600 and the CE incubation period of the Inconel 625 is 4 times as long as that of the Inconel 600. The micro-morphology evolution of CE process illustrates that the twinning and hardness of the Inconel 625 plays a significant role in CE. In addition, the cumulative mass loss of JIE of Inconel 625 is about 2/3 that of Inconel 600 at impacting angle of 90 degrees, and almost equal to that of the Inconel 600 at impacting angle of 30 degrees. Overall, the resistance to CE and JIE of Inconel 625 is much superior to that of Inconel 600. (C) 2010 Elsevier By. All rights reserved.
关键词:
stress-corrosion cracking;aluminide intermetallic alloys;high-purity;water;mechanical-properties;crevice corrosion;solid particles;wear;behavior;microstructure;deformation;steam
Nuclear Engineering and Design
A composite coating was deposited on Inconel 600 substrate by cold spray method using pure Ni powder (60 wt.%) blended with alpha-Al(2)O(3) (40 wt.%) as feedstock. It is expected to be applied to repair the bellows eroded by the liquid droplet erosion (LDE). Microstructure of the coating was observed using optical microscope (OM) and scanning electron microscopy (SEM). Microhardness of the coating was determined by Vickers hardness tester. Cavitation erosion (CE) experiments were carried out in the distilled water. Jet impingement erosion (JIE) experiments were performed in slurry containing 1 wt.% quartz particle with the flow velocity of 15 m/s at impingement angles of 30 degrees, 60 degrees and 90 degrees, respectively. Cumulative mass loss vs. testing time was used to evaluate the erosion rate of the coating. The erosion mechanism was analyzed by OM, SEM, X-ray diffraction (XRD) and the microhardness measurement. The results show that the composite coating has compact microstructure and relatively high hardness. The resistance to CE of the coating is not as good as that of Inconel 600 substrate due to the weak bonds of the Al(2)O(3) particles. However, the results of the JIE test indicate that the slurry erosion resistance of the coating is better than that of Inconel 600 at the impact angles of 30 degrees and 60 degrees, but not at the normal impact angle. (C) 2011 Elsevier B.V. All rights reserved.
关键词:
large powder particles;composite coatings;slurry erosion;kinetic;spray;liquid impact;alloy;microstructure;steels;deposition;resistance
X.B. Tian
,
X.F. Wang
,
A.G. Liu
,
L.P. Wang
,
S. Y. Wang
,
B. Y. Tang and P. K. Chu 1)Advanced Welding Production & Technology National Key Laboratory
,
Harbin Institute of Technology
,
Harbin 150001
,
China 2)Department of Physics & Materials Science
,
City University of Hong Kong
,
China
金属学报(英文版)
The research on plasma immersion ion implantation has been conducted for a little over ten years. Much is needed to investigate including processing technlogy, plasma sheath dynamics, interaction of plasma and surface, etc. Of the processing methods elavated temperature technique is usually used in PIII to produce a thick modified layer by means of the thermal diffusion. Meanwhile plasma ion heating is more recently developed by Ronghua Wei et al[1]. Therefore the temeperature is a critical parameter in plasma ion processing. In this paper we present the theoretical model and analysize the effect of imlantation voltage, plasma density, ion mass,etc on the temperature rise.
关键词:
plasma immersion ion implantation
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null
,
null
夏小建
量子电子学报
doi:10.3969/j.issn.1007-5461.2009.06.010
采用Wei-Norman方法,求出含时变电压源的介观LC电路随时间演化的精确解,应用相空间准概率分布函数,研究了时变电源作用下介观LC电路相干态的量子特性,结果表明此函数是一个二维运动的Gauss波包,其中心电量和磁通呈余弦和正弦变化.
关键词:
量子光学
,
LC回路
,
介观电路
,
相干态
,
量子态演化
,
相空间的准概率分布函数
WEI Jihe Xi'an Institute of Metallurgy and Construction Engineering
,
China.
材料科学技术（英文）
The oxidation of alloying elements during the ESR of stainless steel has been studied. The model previously developed by WEI and Mitchell for the chemical reactions and mass transfer processes during ESR was applied to the remelting of the high Cr steel 1Cr18Ni9(Ti).The laboratory data for the unsteady state A.C.ESR were analyzed and dealt with by the model.When the remelting process reached a steady state,an oxidant(Fe_2O_3 powder)or a deoxidant(Ca-Si powder or metallic Ca)was added to the slag bath.The results showed that this model is applicable to the remelting of stainless steel rather precisely, and it is expected that the model may offer a reliable basis for the control of composition during practical ESR of high alloy steel. Also,the oxidation of Cr in the steel must be noticed when its content is high;but it is entirely possible to adjust the Cr content of ingot within a considerable range,using a special technique by means of the slag-metal reactions during the remelting.
关键词:
ESR
,
null
,
null
,
null
,
null
涂娜
,
江向平
,
李小红
,
傅小龙
,
杨帆
人工晶体学报
采用传统固相法制备了(1-x)Bi4Ti3 O12-xSrBi2 Nb2 O9(BIT-SBN,x=0,0.025,0.050,0.100,0.150,0.200)铋层状无铅压电陶瓷.系统研究了SrBi2 Nb2 O9掺杂对Bi4Ti3 O12基陶瓷物相结构、微观结构以及jie电性能的影响.结果表明:所有陶瓷样品均为单一的铋层状结构;当SBN掺量为0.100时,样品具有最佳的电性能:d33=21 pC/N,相对密度ρ =98.1％,机电耦合系数kp=8.26％,εr=220,介电损耗tanδ =0.29％,剩余极化强度Pr=9.128 μC/cm2,Tc=594℃.同时,SBN的引入增强了样品的抗老化性和热稳定性.
关键词:
Bi4Ti3O12
,
SrBi2Nb2O9
,
铋层状
,
铁电陶瓷
,
介电性能
金属学报(英文版)
桑危郑牛樱裕桑牵粒裕桑希巍。希啤。龋伲模遥希牵牛巍。桑危模眨茫牛摹。模眨茫裕桑蹋拧。拢遥桑裕裕蹋拧。裕遥粒危樱桑裕桑希巍。桑巍。罚保罚怠。粒蹋眨停桑危眨汀。粒蹋蹋希?##2##3##4##5INVESTIGATIONOFHYDROGENINDUCEDDUCTILEBRITTLETRANSITIONIN7175ALUMINUMALLOY$R.G.Seng:B.JZhong,MG.ZengandP.Geng(DepartmentofMaterialsScierce,ScienceCollege,NorthearsternUniveisity,Shenyang110006,ChinaMaruscriptreceived4September1995inrevisedform20April1996)Abstrac:Effectsofhydrogenonthemechanicalpropertiesofdifferentlyaged7175aluminumalloyswereinvestigatedbyusingcathodicH-permeation,slowstrainratetensionandsoon.Theresultsindicatethatboththeyieldstressandthepercentagereductionofareadecreasewithincreasinghydrogenchargingtime,andthedegreeofreductiondecreasesasagingtimeincreasesforthesamehydrogenchargingtime.Keywords:hydrogeninducedductile-brittletransition,7175aluminumalloy,mechanicalproperty,cathodicH-permeation1.IntroductionForalongtimehydrogenembrittlementproblemwasthoughttobeabsentinhighstrengthaluminiumalloybecausethesolutiondegreeofhydrogeninaluminumatcommontemperatureandpressureisverysmall.However,hydrogenembrittlementphenomenonwasfoundinaluminumalloyduringtheinvestigationofstresscorrosionandcorrosionfatigue[1-5].Therehavebeenonlyafewreportsofhydrogeninducedsofteningandhardening.Inthispaper,theeffectsofhydrogenonmechanicalpropertiesof7175aluminumalloywereinvestigatedbyusingcathodicalchargingwithhydrogenandslowtensiontests.2.ExperimentalProcedureTheexperimentalmaterialwas7175aluminumalloyforgingintheformofa43mminthicknessandwithcomposition(wt%).5.41Zn,2.54Mg.1.49Cu,0.22Cr,0.1Mn.0.1Ti,0.16Fe.0.11Si,balancedbyA1.Alloyplateof1.5mminthicknesswasobtainedbyhot(465℃)andtoldrollingto83%reductioninthickness.Thelongaxisofhydrogenchargedspecimensisalongtherollingdirection.Allspecimensweresolidsolutionedat480℃for70min,followedtyimmediatequenchinginwaterandthenagedat140℃for6h(A),16h(B)and98h(C).Thetreatmentof6hiscorrespondingtotheunderagedstate.16hthefirstpeak-agedstateand98hthesecondpeak-agedstate.Thespecimenswerepolishedsuccessivelyusingemerypaperbeforehydrogencharging.Thetensilespecimenswerecathodicallychargedina2NH_2SO_4solutionwithasmallamountofAs_2O_3forpromotinghydrogenabsorption,andwithacurrentdensityof20±1mA/cm￣2atroomtemperature.ThehydrogencontentanalysiswascarriedoutonanLT-1Amodelionmassmicroprobeafterthesputteringdepthreached8nm.Theioncurrentsofhydrogenandaluminuminvariousagedstateswererecordedunderthesamecondition.ThetensiletestswereperformedonanAG-10TAmodeltestmachinewhichwascontrolledbycomputer.3.ExperimentalResultsTheratioofioncurrentstrengthofhydrogentoaluminumisrelatedtohydrogenconcentrationinhydrogenchargedspecimen.TheresultswereshowninTable1Thehydrogencontentincreaseswiththeincreaseincharingtime.Ofthethreeagedstates,theunderagedspecimenhasthehighesthydrogencontent.Theratioofyieldstrengthofhydrogenchargedandunchargedspecimenschangeswithhydrogenchargingtime,asshowninFig.1Itcanbeseenthattheyieldstrengthofhydrogenchargedspecimendecreasewithincreasinghydrogenchargingtime.Atthesamechargingtime,theyieldstressdecreasestheleastinthesecondpeak-agedstate,anddecreasesthemostintheunderagedstate.Itindicatesthattheunderagedspecimenismostsensitivetohydrogeninducedsoftening,whichisconsistentwiththeresultsofanotherhighstrengthaluminumalloy[6].TherelativechangesoftheradioofreductionofareawithhydrogenchargingtimearesummarizedinFig.2,whereΨ￣0andΨ￣Harethepercentagereductionofareaofthesamplewithoutandwithhydrogenchargingrespectively.Theradioofreductionofareareduceswhenhydrogenchargingtimeincreases,andthedecreasingdegreeofreductionofareaincreaseswithincreasingagingtime,ie,,theunderagedstateisthemostsensitivetohydrogenembrittlement.4.DiscussionItisknownfromtheresultsabovethatcathodicalchargingwithhydrogenleadstotheobviousdecreaseinthetensilestrengthandplasticityThisisbecausealargeamountofsolidsolutionhydrogenentersthespecimenintheprocessofhydrogenchargingSolidsolutionhydrogenisliabletoenterthecentreofdislocationundertheactionofdislocationtrap,henceraisingthemovabilityofdislocation.Thereforethedislocationsinhydrogenchargedspecimenmoveeasierthaninunchargedspecimen.soresultinginthereductionofyieldstrength[7].Whendislocationstartstomove,thecrystallatticeresistance(P-Nforce)whichitmustovercomeisgivenby:whereμismodulusofshear,visPoissonratio,aisspanofslipplane,bisatomspanofslipdirection.Moreover.theotherresistanceofdislocationmotionmayarisefromtheelasticinteractionofdislocation,theactionwithtreedislocationandetc.,itcanbeexpressedasfollows:whereαisconstant,XisdislocationspanSotheresistanceofdislocationmotioncanbewrittenasfollows:Becausehydrogenatomsreducetheatombondingstrengthafterhydrogencharging,shearmodulusμdecreasesandresultsinthereductionoff,therebytheyieldstressdecreases.Asthecentreofdislocationistheseriousdistortionzoneoflattice.thestresscanberelaxedafterhydrogenatomstuffing,andthesystemenergydecreases.Thusthecentreofdislocationisastrongtrapofhydrogen[8].Therefore,amovabledislocationcaptureshydrogenandmigratestograinboundaries.phaseboundariesorsurfaceofthespecimen,promotingthecrackiesformationandgrowth,thuscausingthelossofplasticity.Sincethelocalenrichmentofhydrogenisrealizedbydislocationtransporting(inthestageofdeformation),thelargerthereductionofyieldstress.theearlierarehydrogenatomstransportedtotheplaceofenrichment.Inaddition,thedamageofatombondingstrengthinducedbyhydrogenmakesthefracturestressdecrease[9]:whereCHishydrogenconcentration.σ_thisfracturestrengthbeforehydrogenchargingandisfracturestrengthafterhydrogencharging.Eq.(4)showsthatthematerialsmaybefracturedatalowerstraini.e.,brittlefractureoccurs.5.Conclusions(1)Hydrogencontentofdifferentlyagedspecimensincreaseswithincreasinghydrogenchargingtimethecapabilityofthealloytoabsorbhydrogeninunderagedstateisthestrongest.(2)Theyieldstressaswellasthepercentagereductionofareaof7175aluminumalloydecreaseashydrogenchargingtimeincreasesundervariousagedstates.(3)Underagedstateismostsensitivetohydrogeninducedsofteningandhardening.(4)Anexplanationwasofferedforthephenomenonofhydrogeninducedsofteninginthestageofdeformation,andhardeninginthestageoffracture.REFERENCES｜｜1G.KKock,Corrosion35(1979)73.2M.K.TsengandH.LMarcus,Scr.Metall.15(1981)427.3PSFao.M.GaoandR.P.Wei,Scr.Metall.19(1985)265.4R.G.SongandM.K.TsengJ.NortheasternUniversity15(1994)5(inChinese).5R.K.Viswanadham,T.S.sunandJ.A.S.Green,Metall.Trans.11A(1980)85.6J.Liu,M.KTsengandB.R.Liu.NonferrousMiningandMetallrgy5(1989)33(inChinese).7LChen,WXChen,ZHLiuandZ.Q.Hu,InFrocofthe1stNationalConfonAl-LiAlloys(Sheryang.China,1991)p.328(inChinese).8Z.HLiuL.ChenW.XChenY.X.ShaoandZ.Q.Hu,InProc.ofthe1stNationalConfonAl-LiAlloys(Shenyang,China,1991)p.334(inChinese).9R.A.OrianiandF.H.Josephic,ActaMetall.22(1974)1065.##61G.KKock,Corrosion35(1979)73.2M.K.TsengandH.LMarcus,Scr.Metall.15(1981)427.3PSFao.M.GaoandR.P.Wei,Scr.Metall.19(1985)265.4R.G.SongandM.K.TsengJ.NortheasternUniversity15(1994)5(inChinese).5R.K.Viswanadham,T.S.sunandJ.A.S.Green,Metall.Trans.11A(1980)85.6J.Liu,M.KTsengandB.R.Liu.NonferrousMiningandMetallrgy5(1989)33(inChinese).7LChen,WXChen,ZHLiuandZ.Q.Hu,InFrocofthe1stNationalConfonAl-LiAlloys(Sheryang.China,1991)p.328(inChinese).8Z.HLiuL.ChenW.XChenY.X.ShaoandZ.Q.Hu,InProc.ofthe1stNationalConfonAl-LiAlloys(Shenyang,China,1991)p.334(inChinese).9R.A.OrianiandF.H.Josephic,ActaMetall.22(1974)1065.##A##BINVESTIGATION OF HYDROGEN INDUCED DUCTILE BRITTLE TRANSITION IN 7175 ALUMINUM ALLOY$$$$R.G.Seng: B.J Zhong, MG. Zeng and P. Geng(Department of Materials Scierce, Science College,Northearstern Univeisity, Shenyang 110006, China Maruscript received 4 September 1995 in revised form 20 April 1996)Abstrac:Effects of hydrogen on the mechanical properties of differently aged 7175 aluminum alloys were investigated by using cathodic H-permeation, slow strain rate tension and so on. The results indicate that both the yield stress and the percentage reduction of area decrease with increasing hydrogen charging time, and the degree of reduction decreases as aging time increases for the same hydrogen charging time.
关键词:
:hydrogen induced ductile-brittle transition
,
null
,
null
,
null
