章海霞
,
李中奎
,
张建军
,
郑欣
,
FRUCHARTDaniel
,
HLILEl
,
Kébir
,
孙军
,
周廉
材料研究学报
通过分析NZ2合金在360℃、18.6 MPa含锂水和400℃、10.3 MPa蒸汽中腐蚀后氧化膜的晶体结构,研究了腐蚀过程中氧化膜晶体结构的转变及其对锆合金耐腐蚀性能的影响. 结果表明:NZ2合金腐蚀后氧化膜的结构以单斜氧化锆为主, 还有一定量畸变了的四方氧化锆.四方氧化锆主要由氧化膜内的压应力稳定. 随着腐蚀时间的延长,氧化膜与金属间的界面向前推进, 当氧化锆中的压应力不足以稳定四方相时,四方氧化锆转变为单斜氧化锆. 从氧化膜与金属间的界面到氧化膜的外表面,四方相的含量不断降低, 界面处的四方相含量最高. NZ2合金在360℃含锂水中腐蚀时,氧化膜内四方相向单斜相的转变速度比在400℃蒸汽中腐蚀时四方相向单斜相的转变速度低得多.四方相向单斜相的转变是决定锆合金抗腐蚀性能的主要因素, 四方相转变得越快,其含量越低, 腐蚀速率越高.
关键词:
材料失效与保护
,
null
,
null
段沐枫
,
李宁
,
郑莹莹
,
肖军
,
李勇
宇航材料工艺
K-cor是应用Z-pin增强技术的一种新型高性能结构.本文以NHZP-1树脂为基体研究适合K-cor结构的半固化Z-pin拉挤工艺,得到固化度为51.25％的Z-pin为满足制备要求的最佳参数,并制作悬空装置采用两步法进行半固化Z-pin的植入和压弯,探索出压弯和后固化工艺.在此基础上,对试制的K-cor夹层结构进行平拉和剪切试验研究.结果发现,折弯长度是K-cor夹层结构的另一重要参数,较长的折弯长度会增加Z-pin与蒙皮的结合面积从而提高结构的拉伸性能.
关键词:
复合材料
,
半固化Z-pin
,
K-cor夹层结构
,
制备工艺
,
力学性能
陈篪
金属学报
本文证明我们所建议的关系: (da/dN)-C[(△K)~2-K_2~2/K_1~2-(△K)~2]~p能够很好地表达R=(K_(min)/K_(max))=常数时(da/dN)随△K的全部变化,其中P值在1左右,C约在3×10~(-3)—10~(-2)毫米/周之间。
关键词:
刁贵强
,
余林
,
孙明
,
余倩
,
范方强
,
那秀辉
催化学报
以葡萄糖和高锰酸钾为原料,采用溶胶-凝胶法合成了birnessite(K_(1.35)MnO_2,简写为Bir)和cryptomelane(K_(0.27)MnO_2,简写为Cry)型氧化锰;采用X射线衍射、原子吸收光谱等考察了凝胶处理方法、反应物浓度比、焙烧温度和反应时间等对氧化锰晶型的影响.结果表明,采用不同方法处理凝胶可实现对Bir和Cry型氧化锰的可控合成.以不同的处理方法,葡萄糖和高锰酸钾的浓度比为O.74,反应20s制成凝胶,并在400℃焙烧2h,可分别制取高结晶度和高纯度的Bir和Cry型氧化锰.Bir和Cry型氧化锰在二甲醚燃烧反应中表现出优异的催化性能,且Cry型氧化锰的催化活性更高.
关键词:
溶胶-凝胶法
,
氧化锰
,
可控合成
,
二甲醚
,
催化燃烧
Materials Letters
Single crystals of K-doped blue bronze Rb0.15K0.15MoO3 and Rb0.3MoO3 have been investigated by measurements of the X-ray photoemission spectrum (XPS), electrical resistivity and thermoelectric power, respectively. Analysis of the XPS data reveals that two final states representing alternate screening channels coexist in Rb0.15K0.15MoO3. Compared with the pure bronze, the Mo sites of the doped sample contain less 4d electrons which reflected in the movement of Mo3d spectrum. Due to the discrepancy of electronic structure, the K ion doping results in the notable increase of the single particle activation energy and decrease of the thermoelectric power in the charge density wave state. (C) 2007 Elsevier B.V. All rights reserved.
关键词:
blue bronze;charge-density-wave;electronic structure;nonlinear transport;k0.30moo3;tl0.3moo3;k0.3moo3;moo3
稀土学报(英文版)
Cyclic oxidation test is a fundamental method to assess lifetime of materials in high temperature environment. Cycle length or cyclic frequency is one important variable in cyclic oxidation testing. In present work, cyclic oxidation tests were performed on cast K38 alloys with 0 wt.%, 0.1 wt.%, and 0.5 wt.% yttrium additions at 1 273 K respectively. Two cyclic frequencies were used to investigate the influence of cycle length (1 h vs. 20 h) on the high temperature oxidation behavior of superalloy. The results showed that the degradation of cast K38 alloy critically was dependent on the cyclic frequency. The yttrium addition was beneficial to reducing scale-growth rate, improving the scale adhesion and stress releasing, thereby increased the spallation resistance. It could be drawn that the effect of cyclic frequency was highly dependent on the scale adherence to the substrate.
关键词:
K38 superalloy;yttrium;cyclic oxidation;cyclic frequency;rare earths;high-temperature oxidation;adhesion;segregation;scales;spallation;chromia;alloys;growth;oxides
Physics Letters A
Except for a Peierls transition at T(p) = 180 K, a new transition around T = 270 K in K0.3MoO3 single crystals has been found as evidenced by the anomalies in electrical, magnetic and thermodynamic properties. This transition may be caused by the variation of carrier characteristics or of the charge transfer between cations and anions.
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