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ROOM TEMPERATURE AND 750℃ ISOTHERMAL SECTION OF Ag-Pd-Gd(Gd≤25 AT.-%)PHASE DIAGRAM

ZHANG Kanghou CHEN Lili Kunming Institute of Precious Metals , Kunming , China ZHANG Kanghou , Kunming Institute of Precious Metals , Kunming 650221 , China

金属学报(英文版)

The room temperature section and the 750℃ isothermal section of the Ag-Pd-Gd ternary phase diagram containing 0—25 at.-% Gd are constructed by X—ray diffraction analysis and optical microscopy.Each section consists of 3 single phase regions,3 bi-phase regions and I tri-phase region respectively.

关键词: Ag-Pd-Gd ternary system , null

Mechanism of zinc damaging to blast furnace tuyere refractory

Xuefeng YANG

金属学报(英文版) doi:10.1016/S1006-7191(08)60123-4

The phenomena of tuyere upward-warp have been found at No.6 blast furnace in Kunming Steel Company China after its blow-in, which has made a great impact on the practical production of the furnace. Thus, a number of efforts have been made to elucidate the mechanism of this phenomenon. The results of investigation and tests revealed that the enrichment and expansion of zinc in the tuyere bricks is the main factor leading to the tuyere upward-warp. The eroding behavior of zinc is that the inner structure of the tuyere bricks turns from dense to loose with entering, enriching and expanding of zinc, which forms spot-like→stripe-like→ditch-like→vein-like→tumor-like eroding passage. Additionally, it is found that the sequence of deleterious elements entering the tuyere refractory is K, Na, Zn and Pb, respectively. Finally, the phenomena and process of zinc crystallization and growth in the refractory have been clearly observed and recorded during this investigation.

关键词: Blast furnace , tuyere , refractory , zinc , erosion , deleterious elements

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