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PREDICTION ON THERMODYNAMIC PROPERTIES OF TERNARY LIQUID ALLOYS FROM WILSON EQUATION

TAO Dongping Kunming Institute of Technology , Kunming , China Lecturer , Department of Metallurgy , Kunming Institute of Technology , Kunming 65041 , China

金属学报(英文版)

An attempt was made on applying the Wilson equation to predict the thermodynamic proper- ties of ternary liquid alloys.The activity of each component in ternary liquid alloys was found to be conveniently calculated from the equation with the related binary bimolecular interaction parameters.The calculated values are in fair agreement with experimental data,and are veri- fied to be reliable by the criterion of classical thermodynamics.

关键词: thermodynamic property , null , null

Mechanism of zinc damaging to blast furnace tuyere refractory

Xuefeng YANG

金属学报(英文版) doi:10.1016/S1006-7191(08)60123-4

The phenomena of tuyere upward-warp have been found at No.6 blast furnace in Kunming Steel Company China after its blow-in, which has made a great impact on the practical production of the furnace. Thus, a number of efforts have been made to elucidate the mechanism of this phenomenon. The results of investigation and tests revealed that the enrichment and expansion of zinc in the tuyere bricks is the main factor leading to the tuyere upward-warp. The eroding behavior of zinc is that the inner structure of the tuyere bricks turns from dense to loose with entering, enriching and expanding of zinc, which forms spot-like→stripe-like→ditch-like→vein-like→tumor-like eroding passage. Additionally, it is found that the sequence of deleterious elements entering the tuyere refractory is K, Na, Zn and Pb, respectively. Finally, the phenomena and process of zinc crystallization and growth in the refractory have been clearly observed and recorded during this investigation.

关键词: Blast furnace , tuyere , refractory , zinc , erosion , deleterious elements

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