林鸿
,
段远源
工程热物理学报
利用密度平移的方法对Peng-Robinson状态方程计算的液相密度进行了修正,给出了其描述平移量的关联式.对22种卤代烃纯物质的计算结果表明,修正后的PR方程能够很好地计算液相密度,并且能很好地再现纯物质的临界压缩因子,计算精度可以满足工程应用的需要.
关键词:
PR状态方程
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密度漂移
,
卤代烃
,
临界压缩因子
李志宏
,
柳卫平
,
白希祥
,
郭冰
,
连钢
,
颜胜权
,
王宝祥
,
陆昀
,
曾晟
,
苏俊
原子核物理评论
doi:10.3969/j.issn.1007-4627.2005.01.006
利用8Li次级束测量了质心系能量7.8 MeV 2H(8Li, 9Li)1H反应的角分布, 导出了8Li(d, p)9Li反应的天体物理S因子及9Li→8Li+n虚衰变的渐近归一化系数.
关键词:
8Li(d,p)9Li反应
,
角分布
,
天体物理S因子
,
渐近归一化系数
HUANG Jianshun CHEN Junming Shanghai Institute of Metallurgy
,
Academia Sinica
,
Shanghai
,
China Research Associate
,
Shanghai Institute of Metallurgy
,
Academia Sinica
,
Shanghai 200050
,
China
金属学报(英文版)
Crystal structure of γ-Li_xFe_2O_3,inserted Li electrochemically,was studied by Moss- bauer spectroscopy together with X-ray diffraction,XPS and electrochemical method,On the insertion of Li at low current density,the crystal structure is keeping original spinel; while at higher current density or by thermal activation,owing to violent movement of Li~+ ions,part of crystal structure transforms into rock type similar to face-centered cubic structure of ferrous oxide.The transition channels during insertion of Li~+ ions and limitation of Li~+ ions inserted were discussed.
关键词:
null
,
null
,
null
Journal of Materials Research
The effect of Li(3)N additive on the Li-Mg-N-H system was examined with respect to the reversible dehydrogenation performance. Screening Study with varying Li(3)N additions (5, 10, 20, and 30 mol%) demonstrates that all are effective for improving the hydrogen desorption capacity. Optimally, incorporation of 10 mol% Li(3)N improves the practical capacity from 3.9 wt% to approximately 4.7 wt% hydrogen at 200 degrees C, which drives the dehydrogenation reaction toward completion. Moreover, the capacity enhancement persists well over 10 de-/rehydrogenation cycles. Systematic x-ray diffraction examinations indicate that Li(3)N additive transforms into LiNH(2) and LiH phases and remains during hydrogen cycling. Combined structure/property investigations suggest that the LiNH(2) "seeding" should be responsible for the capacity enhancement, which reduces the kinetic barrier associated with the nucleation of intermediate LiNH(2). In addition, the concurrent incorporation of LiH is effective for mitigating the ammonia release.
关键词:
complex hydrides;improvement;mixtures;imides;amide;h-2
MANG Weishi WANG Guozhi ZHANG Yongchang HU Zhuangqi SHI Changxu Institute of Metal Research
,
Academia Sinica
,
Shenyang
,
China Yongchang Associate Professor
,
Institute of Metal Research
,
Academia Sinica
,
Shenyang 110015
,
China
金属学报(英文版)
A rapidly solidified microcrystalline Al-Li-Cu-Mg-Zr alloy and its superplasicity have been investigated.An optimum tensile elongation of 585% was obtained at 540℃ and strain rate 1.67×10~(-2)s~(-1).The superplastic Al-Li alloy is manufaetured using thermomechanical pro- cessing:solution,overaging,warm rolling and recrystallization.Microstructural changes in thermomechanical processing and cavitation occurred during superplastic deformation have been observed.The superplastic failure of alloy may be caused mainly by nucleation and growth of cavities as well as the linkage around grains.
关键词:
superplasticity
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null
,
null
,
null
