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Prediction of Activities in Fe-Based Ternary Liquid Alloys by Hoch-Arpshofen Model

YANG Hong-wei , , LIAN Chao , TAO Dong-ping

钢铁研究学报(英文版)

Thermodynamic properties for an alloy system play an important role in the materials science and engineering. Therefore, theoretical calculations having the flexibility to deal with complexity are very useful and have scientific meaning. The Hoch-Arpshofen model was deduced from physical principles and is applicable to binary, ternary and larger system using its binary interaction parameters only. Calculations of the activities of Fe-based liquid alloys are calculated using Hoch-Arpshofen model from data on the binary subsystems. Results for the activities for Fe-Au-Ni, Fe-Cr-Ni, Fe-Co-Cr and Fe-Co-Ni systems at required temperature are presented by Hoch-Arpshofen model. The average relative errors of prediction are 78%, 45%, 49% and 27%, respectively. It shows that the calculated results are in good agreement with the experimental data except Fe-Au-Ni system, which exhibits strong interaction between unlike atoms. The model provides a simple, reliable and general method for calculating the activities for Fe-based liquid alloys.

关键词: Hoch-Arpshofen model , activity , Fe-based liquid alloy

各向异性板料屈服轨迹的研究

吴向东 , 万敏 , 周贤宾

材料科学与工艺 doi:10.3969/j.issn.1005-0299.2004.04.015

针对建立的十字形双向拉伸试验系统,利用有限元模拟优化得到的十字形试件,采用载荷控制方式对SPEN钢板和2024-O铝合金板进行了不同加载路径下的双向拉伸试验,得到了不同硬化阶段下的实验屈服轨迹,并与现有屈服准则Hill48、Hill79、Hill90、Hill93、Gotoh、Hosford、Barlat-Lian以及Mises的理论屈服轨迹进行了对比.结果表明:对于SPEN钢板,Hosford各向异性屈服准则得到的理论屈服轨迹与实验屈服轨迹符合得最好,其次是Mises屈服准则,Hill48屈服准则最差;对2024-O铝合金板,Barlat89、Hosford屈服轨迹与实验屈服轨迹符合得最好,Mises屈服准则最差.

关键词: 双向拉伸试验 , 十字形试件 , 各向异性 , 屈服准则

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