LIU Shan LU Deyang HUANG Tao ZHOU Yaohe National Lab of Solidification Processing
,
Northwestern Polytechnical University
,
Xi'an
,
China LIU Shan
,
lecturer
,
National Laboratory of Solidification Processing
,
Northwestern Polytechnical University
,
Xi'an 710072
,
China
金属学报(英文版)
An experimental apparatus,which has a convection generator and an aid-heater,is developed for the study of the effect of stable laminar liquid flow on the directional solidification process by the use of transparent alloy SCN-2wt-% Ace.The flow is perpendicular to primary arms. By in-situ observation and photographing at different specific moments,it has been found that such a flow can cause a great change in primary spacings of constrained columnar crystals:for cells,the spacings become smaller;but for dendrites,they become larger.The former is mainly due to the tilted growth of upstreamside branches,while the latter is mainly due to the coup- ling effect of liquid flow with solutal field around dendrite tips.The faster the liquid flows,the further smaller the cell spacing and the further larger the dendrite spacing.
关键词:
forced liquid flow
,
null
,
null
,
null
刘文鹏
,
张庆礼
,
杨华军
,
周鹏宇
,
孙敦陆
,
高进云
,
谷长江
,
罗建乔
,
王迪
,
殷绍唐
量子电子学报
doi:10.3969/j.issn.1007-5461.2011.02.018
采用固相反应法制备了Bi3+、Eu3+、Tb3+掺杂的Lu3TaO7.测量了样品的X射线衍射谱、激发和发射光谱及荧光衰减曲线.三种离子掺杂的Lu3TaO7均呈现出强的荧光发射,其中Bi3+具有峰位在431 nm处的一强发射宽带,衰减寿命为16.8μs,Eu3+、Tb3+则表现出稀土离子的特征锐发射峰,衰减寿命分别为1.26 ms和1.20 ms.因此,它们均是具有潜在应用前景的重闪烁体材料.
关键词:
材料
,
闪烁体
,
Lu3TaO7
,
发光
WADSWORTH Jeffrey and FLUSS Michael(Chemistry and Materials Science Directorate
,
Lawrence Livermore National Laboratory
,
Livermore
,
CA 94551)
金属学报(英文版)
The role of the National Laboratories is summarized from the era of post World War II to the present time. The U.S. federal government policy for the National Laboratories and its influence on their materials science infrastructure is reviewed with respect to .determining overall research strategies, various initiatives to interact with industry (especially in recent years),building facilities that serve the nation, and developing leading edge research in the materials sciences. Despite reductions in support for research in the U.S. in recent years, and uncertainties regarding the specific policies for Research &Development (R&D) in the U.S., there are strong roles for materials research at the National Laboratories. These roles will be centered on the abilities of the National Laboratories to field multidisciplinary teams, the use of unique cutting edge facilities, a focus on areas of strength within each of the labs,increased teaming and partnerships, and the selection of motivated research areas. It is hoped that such teaming opportunities will include new alliances with China, in a manner similar, perhaps, to those recently achieved between the U.S. and other countries.
关键词:
: U.S. Materials Science. U.S. National Laboratories and Facilities
,
null
Sen YANG
,
Yunpeng SU
,
Wenjin LIU
,
Weidong HUANG
,
Yaohe ZHOU
材料科学技术(英文)
The detailed laser surface remelting experiments of Cu-31.4 wt pct Mn and Cu-26.6 wt pct Mn alloys on a 5 kW CO2 laser were carried out to study the effects of processing parameters (scanning velocity, output power of laser) on the growth direction of microstructure in the molten pool and cellular spacing selection under the condition of ultra-high temperature gradient and rapid directional solidification. The experimental results show that the growth direction of microstructure is strongly affected by laser processing parameters. The ultra-high temperature gradient directional solidification can be realized on the surface of samples during laser surface remelting by controlling laser processing parameters, the temperature gradient and growth velocity can reach 106 K/m and 24.1 mm/s, respectively, and the solidification microstructure in the center of the molten pool grows along the laser beam scanning direction. There exists a distribution range of cellular spacings under the laser rapid solidification conditions, and the average spacing decreases with increasing of growth rate. The maximum, λmax, minimum, λmin, and average primary spacing, , as functions of growth rate, Vb, can be given by, λmax=12.54 , λmin=4.47 , =9.09 , respectively. The experimental results are compared with the current Hunt-Lu model for rapid cellular/dendritic growth, and a good agreement is found.
关键词:
Laser surface remelting
,
null
,
null
,
null
Physica B-Condensed Matter
Polycrystalline La0.5Lu0.2Sr0.3MnO3 samples prepared by thermal decomposition are investigated by means of electron diffraction and high-resolution transmission electron microscopy. Besides rhombohedral La0.7Sr0.3MnO3 phase (R-phase) and hexagonal LuMnO3 phase (H-phase) reported by Huang, unexpectedly, an orthorhombic lattice (O-phase) with space group Pnma is observed in the interior of R-phase grain. The lattice parameters of the orthorhombic unit cell are a(o) = 5.44 angstrom, b(o) = 7.65 angstrom and c(o) = 5.48 angstrom The formation of O-phase results from a(-)b(+)a(-) type orthorhombic distortion of MnO6 octahedra induced by partial substitution of Lu3+ for La3+. Meanwhile, based on image simulation of the interface between R and O-phases, the atomic bonding on the interface is particularly discussed. (c) 2005 Elsevier B.V. All rights reserved.
关键词:
orthorhombic lattice;octahedral;substitution;atomic bonding;la0.7-xluxsr0.3mno3 perovskites;transport-properties;magnetoresistance;films
Materials Letters
Phase separation and microstructure of La0.7Sr0.3MnO3 doped with rare earth elements (Eu, Ho, Yb and Lu) are studied using X-ray diffraction (XRD) and transmission electron microscopy (TEM). Composition and diffraction analyses demonstrate that the ionic radius of doping element plays an important role in the crystalline structure and the lattice constants of the secondary phase. When La 3 is replaced partly by Eu3+ or Ho3+, orthorhombic perovskite structure with space group Pnma is formed due to the distortion Of MnO6 octahedra. Different from the phenomenon observed by Huang et al., however, the hexagonal non-perovskite structure (YbMnO3 and LuMnO3) has appeared when La3+ and Sr2+ are substituted completely by Lu or Yb (c) 2005 Elsevier B.V. All rights reserved.
关键词:
ionic radius;crystalline structure;lattice constants;orthorhombic;perovskite;hexagonal non-perovskite;magnetoresistance;perovskites;films
LI Jie Jian-Hong MA Yu-Lai GAO Qi-jie ZHAI
钢铁研究学报(英文版)
A new approach of applying the Electric Current Pulse (ECP) with parallel electrodes to promotion of the transition from columnar to equiaxed crystals and improvement of macrosegregation was introduced. And the experiments of application of ECP in the different stage of solidification have been carried out. The results show that applying ECP in both the initial and the late stage of solidification can promote the columnar to equiaxed transition (CET). Analysis shows that during solidification application of ECP induce a large number of nuclei around the upper surface, which subsequently showers down into the melt and impinges growth front of the columnar crystal. Therefore the CET occurs. In addition, this method is also employed to influence the solidification processing of bearing steel, the results show that the structrue is changed from columnar to equaixed, indicating that ECP can enhance the homogeneity of structure and composition of bearing steel.
关键词:
columnar to equiaxed transition;casting solidification;electric current pulse;macrosegregation