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CRYSTAL DEFECTS AND GRAIN INTERFACE STRUCTURE OF ION-NITRIDED LAYERS

SUN Dongsheng LI Fengzhao Shandong Polytechnic University , Jinan , Laboratory of Atomic Imaging of Solids , Institute of Metal Research , Academia Sinica , Shenyang , ChinaDAI Jiyan LI Douxing Laboratory of Atomic Imaging of Solids , Institute of Metal Research , Academia Sinica , Shenyang , China associate professor , Institute of Materials Engineering , Shandong Polytechnic University , Jinan 250014 , China

金属学报(英文版)

Observation under high resolution electron microscope shows that the continuous bombing of high speed ions produces a great amount of vacant site defects.The assembly of vacancies forms vacant dish,and the collapase of vacant dish forms stacking fault tetrahedrons and oth- er crystal defects.The interfaces between phase ε(Fe_(2-3)N)and phase γ'(Fe_4N)are smooth, straight and coherent,and they have the orientation relationships of(11)//(0001)and [110]/[110] .

关键词: crystal defect , null , null , null

HIGH RESOLUTION STUDY OF TWINS IN Al_(20)Cu_2Mn_3 PHASE

LI Chunzhi WANG Shuncai JIN Yan Institute of Aeronautical Materials , Beijing , Laboratory of Atomic Imaging of Solids , Institute of Metal Research , Academia Sinica , Shenyang , China

金属学报(英文版)

The dispersoid phase Al_(20)Cu_2Mn_3 in a 2024 Al alloy is commonly composed of twins,An ob- servation of corresponding high resolution image shows that the twin boundary plane is a glide plane other than mirror one.Two neighbouring components of twins are not symmetry of re- flection or rotation,but of glide reflection.The“diamond”glide plane is(101)and the glide vector is(1/4)(-).Components of twins in the phase take shape of prism with the longitudinal edge being parallel to[010]and side faces being{101}and{100}.

关键词: twin , null , null , null

FRACTAL NATURE OF A FRACTURE SURFACE IN LAYERED SOLIDS

Chinese Physics Letters

We study the crack propagation in layered solids and find that when there exists an easy-fractured layer, the fractal surface becomes more rough, which is characterized by larger fractal dimensions.

关键词: dimension

Melting and superheating of crystalline solids: From bulk to nanocrystals

Progress in Materials Science

Melting of solids is a common phenomenon in nature. It is also one of the most important phase transformations in materials science and engineering. In recent years, extensive experimental and theoretical investigations in conjunction with computer simulations on melting of solids, with various geometries ranging from bulk forms to nanometer-sized clusters, have greatly enhanced our understanding of the nature of melting. This paper reviewed the up-to-date research results on this classical and cutting-edge topic. Emphasis was made on melting and superheating of nano-sized particles and thin films including thermodynamic and kinetic analyses of the size effect and the interfacial structure effect on melting processes. (C) 2007 Elsevier Ltd. All rights reserved.

关键词: isolated tin nanoparticles;embedded pb nanoparticles;kinetic stability;limit;energy ion-scattering;equation-of-state;small particles;electron-microscopy;molecular-dynamics;al(110) surface;al matrix

Synthesis of nanocrystalline materials from amorphous solids

Advanced Materials

The key to the formation of nanocrystallites from amorphous solids lies in the annealing temperature. This aspect of the preparation of nanocrystalline materials is covered, as are other attractive features of this method, for example, that it can be applied to most alloy and pure element systems, large quantities of nanocrystalline samples can be produced, and the grain size can be controlled. The properties of these materials are also described and it is concluded that more studies on 3D bulk: porosity-free, and clean samples are needed.

关键词: ultrafine grain-structure;alloys;selenium;sizes

Crystallization kinetics of amorphous solids under pressure

Physical Review B

The pressure effect on crystallization kinetics of amorphous solids was investigated by means of thermodynamic analysis. A model was developed to describe the nucleation process under pressure by considering the crystalline/amorphous (c/a) interface that plays a dominant role in the nucleation process. Applying the model to three types of crystallization process, polymorphous (a-Se), primary (Al89La6Ni5), and eutectic (Ni80P20), we found the calculated results can give reasonable explanations for the experimental observations. The calculation suggests that for a-Se and Ni80P20 amorphous alloy, the initial stage of nucleation is a volume expansion process due to the c/a interface formation, resulting in an increase in the nucleation work with an increment of pressure. Hence the crystallization temperature of the amorphous phase rises when a pressure is applied, while for the Al-La-Ni amorphous alloy, the nucleation barrier decreases at higher pressures. The coincidence between the calculation and the experimental results illustrates that the cia interface formation is the governing factor in the crystallization kinetics of the amorphous solids. [S0163-1829(99)03534-1].

关键词: activation volume;nanocrystalline state;metallic glasses;diffusion;alloy;selenium;phase;se;transformations;microstructure

Quantitative Analysis of Non-Crystalline and Crystalline Solids in Blast Furnace Slag

WANG Haifeng , ZHANG Chunxia , QI Yuanhong

钢铁研究学报(英文版)

China is short of water seriously. But granulation of blast furnace slag (BFS) with water has many disadvantages, such as high water consumption and difficulty in heat recycling. So developing a new dry granulation technique to treat BFS is very important. The applicability of BFS directly depends on the content of non-crystalline solids in the slag after treatment. So it is of theoretical and practical significance to analyze the content of non-crystalline solids in the slag quantitatively and simply. Metallographical test is mainly adopted to quantify the non-crystalline in BFS now with the shortages such as making sample complexly, determining difficultly and personally. For the diffraction intensity of non-crystalline is proportionate to the content of non-crystalline in BFS, X-ray diffraction method was adopted to quantify the non-crystalline and the crystalline solids in BFS. The quantificational coefficient between the crystalline and the non-crystalline solids of BFS is 0.70 whose main composition is: w(CaO)38.2%,w(SiO2)35.7%,w(Al2O3)16.3%,w(MgO)8.3%. The relatively error of using X-ray diffraction instrument to quantitative analyse non-crystalline content of BFS is less than 1%.

关键词: Blast Furnace Slag;Non-Crystalline;Crystalline;Quantificational Analysis

PREPARATION AND REACTIVITIES OF COMPOSITE NANOCRYSTALLINE SOLIDS PREPARED BY MECHANICAL ALLOYING

Journal of Non-Crystalline Solids

The formation of Fe-SiC composite, nanocrystalline solids through ball milling is reported. The effects of mechanical deformation, crystallite size and gaseous elements on the solid state reaction between Fe and SiC are also investigated. The formation of Fe3C after a long milling time is attributed to the kinetics of the reaction between nanocrystalline Fe and SiC.

关键词:

Characterisation of initial atmospheric corrosion carbon steels by field exposure and laboratory simulation

Corrosion Science

The early stages of the evolution of atmospheric corrosion of carbon steels exposed in both a laboratory simulated and a natural atmosphere environment in Shenyang have been observed by in situ scanning electron microscopy. In the case of laboratory cyclic wet-dry tests, even though the chloride content level is very low, filiform corrosion is initiated in the early stage. The filiform corrosion grows in random directions, forming a network of ridges. White nodules nucleate and grow on the ridges during continued corrosion and eventually connect with each other to form the initial corrosion scale. Pits were also found on the surface beneath corrosion products. In the case of a natural atmospheric environment, both filiform corrosion and other localized corrosion, such as pitting and inter-granular attack take place in the initial stage. It is obvious that there is variety of localized corrosion in the initial stage of atmospheric corrosion. (C) 2007 Elsevier Ltd. All rights reserved.

关键词: steel;atmospheric corrosion;initial stage;localized corrosion;in-situ;iron;electrolyte;thickness

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