Mehdi Ebrahimian-Hosseinabadi Fakhredin Ashrafizadeh Mohammadreza Etemadifar Subbu S. Venkatraman
材料科学技术（英文）
In this paper, preparation of nano-biphasic calcium phosphate (nBCP), mechanical behavior and load-bearing of poly (lactide-co-glycolide) (PLGA) and PLGA/nBCP are presented. The nBCP with composition of 63/37 (w/w) HA/β-TCP (hydroxyapatite/β-tricalcium phosphate) was produced by heating of bovine bone at 700°C. Composite scaffolds were made by using PLGA matrix and 10-50 wt% nBCP powders as reinforcement material. All scaffolds were prepared by thermally induced solid-liquid phase separation (TIPS) at -60°C under 4 Pa (0.04 mbar) vacuum. The results of elastic modulus testing were adjusted with Ishai-Cohen and Narkis models for rigid polymeric matrix and compared to each other. PLGA/nBCP scaffolds with 30 wt% nBCP showed the highest value of yield strength among the scaffolds. In addition, it was found that by increasing the nBCP in scaffolds to 50 wt%, the modulus of elasticity was highly enhanced. However, the optimum value of yield strength was obtained at 30 wt% nBCP, and the agglomeration of reinforcing particles at higher percentages caused a reduction in yield strength. It is clear that the elastic modulus of matrix has the significant role in elastic modulus of scaffolds, as also the size of the filler particles in the matrix.
关键词:
Scaffold
Applied Physics Letters
Amorphous Ge1-xSx(x=0.61, 0.67, and 0.72) semiconductor alloys have been found formed by ball milling of powder mixtures of elemental Ge and S. The amorphization process and the ball-milled products have been investigated by x-ray diffraction, transmission electron microscopy, and Raman scattering. The results show that amorphous Ge-S alloys may form in a self-heating reaction, driven by the large heat of formation of amorphous and/or liquid Ge-S alloys. The structure of mechanically alloyed amorphous Ge-S alloys is similar to but not exactly identical with that of rapidly cooled amorphous Ge-S alloys. The amorphization transition mechanism reported is believed to be suitable for preparing other amorphous semiconductor alloys with similar thermodynamic conditions.
关键词:
magnetic-properties;ni-zr;amorphization;powders;transition;interdiffusion;germanium;systems;glasses;metals
Ting DU Longmei WANG Yeming WU Yuqing ZHANG Aisheng LIU Central Iron and Steel Research Institute
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Beijing
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100081
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China
材料科学技术（英文）
The temperature dependences of the equilibrium constants for the reactions RES_((S))=[RE]+[S]. (RE=Ce,La,Nd,Sm,Y),of the standard Gibbs energies for the RES formed and of the interaction coefficients between RE elements and S for the Fe-base,Ni-base and Cu-base solutions are sum- marized.
关键词:
thermodynamics
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null
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null
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null
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null
Applied Physics Letters
Transport in S(2) molecules sandwiched between Au electrodes is investigated with a combination of density functional theory and the non-equilibrium Green's function method. We consider four different configurations and find that their conductances are related to the details of the bonding geometry. When S(2) connects to pyramidal-shaped electrodes at the top site, the transmission is governed by a resonance and is strongly affected by the bias. In contrast, the transport of the remaining three configurations is through several closely spaced broad molecular orbitals, and the transmission coefficient is almost flat around the Fermi level. (C) 2012 American Institute of Physics. [doi:10.1063/1.3665614]
关键词:
conductance;molecule
孙新阁
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霍立兴
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张玉凤
腐蚀学报（英文）
采用楔形张开加载恒位移实验研究了X65管线钢在H2S溶液中的应力腐蚀开裂行为，并得出了X65管线钢母材、焊缝和热影响区的临界应力强度因子KISCC分别为55.7093 MPa•m 1/2、33.3189 MPa•m1/2和38.0711 MPa•m1/2；平台处的裂纹扩展速率da/dt分别为3.38×10－9m/s、3.5×10－9 m/s和3.5×10－9m/s.研究结果还表明，焊缝比母材具有更高的应力腐蚀敏感性.
关键词:
管线钢
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null
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null
