Min ZHAO
材料科学技术（英文）
TiB2P/Al composite was successfully fabricated by squeeze casting technology. Its mechanical and tribological properties were evaluated. The elimination of Ti-Al intermetallic compound was confirmed by X-ray diffraction (XRD) studies. At 45% volume fraction, the bending strength at ambient temperature was 934 MPa. And the fracture modes included ductile failure of Al matrix and brittle fracture of TiB2 particles. In dry sliding wear mode, severe plastic deformation and adhesive wear were found on the worn surfaces of the SiCP/Al composite. But no obvious characteristics of adhesion or abrasion wear were observed on that of the TiB2P/Al composites. At the steady stage, the friction coefficient of the SiC2P/Al composite was about 0.6. While that of TiB 2P/Al composite was only about 0.16~0.17.
关键词:
TiB2
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null
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null
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null
Q.S. Liu1
,
2
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3)
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L.C. Zhao3)
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G.X. Dong2) and N.J. Gu1) 1) Heibei University of Technology
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Tianjin 300130
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China 2) Tianjin Institute of Technology
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Tianjin 300191
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China 3) Harbin University of Technology
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Harbin 150001
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China
金属学报(英文版)
Theconstruction changinginthereversetransformation ofthestress induced εMin Fe 17 Mn 10 Cr 5 Si 4 Ni alloy is carefully inspected in transmission electron microscope, and then stress induced εM procedure of reverse transformation is analyzed. The behavior of reverse transformationisdissimilar when the organization of εMis different. The reversetransfor mation ofεM withtheshapeofsingle plateandstripisrelativelyeasy,anditsreversibilityincrystallographiciseasilytocarryout,fortheεM with multilayerstructure,thereversetrans formationtakes placein isolatedlayers, fortheεMthat grows well,thereversetransforma tion isrelatively difficult becauseofthe ductile harmonization between itsinternalorganiza tion structures.
关键词:
stress induced εM
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null
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null
徐佩
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卢旭鑫
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汪传斌
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杨善中
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孙晓红
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丁运生
高分子材料科学与工程
为改善多壁碳纳米管(MWNT)在低密度聚乙烯(LDPE)中的分散性及复合材料的界面特性,采用溴化-1-十六烷基-3-甲基咪唑基离子液体([C16min]Br)对MWNT进行表面改性,并用Raman光谱对改性效果进行了表征.将经过修饰的碳纳米管(MIL)与LDPE熔融共混得到MIL/LDPE复合材料,采用场发射扫描电子显微镜(FESEM)和阻抗分析仪(LCR)对复合材料的结构与介电性能进行了分析.结果表明,相比与MWNT/LDPE(渗流阈值为5.2％,介电常数为82,介电损耗为0.93),MIL/LDPE(渗流阈值为9.1％,介电常数为169,介电损耗为0.51)介电常数增大,介电损耗降低.并且在低温时,MIL/LDPE介电常数随温度的变化甚小,显示出良好的温度-介电常数特性.
关键词:
咪唑基离子液体
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碳纳米管
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低密度聚乙烯
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介电性能
刘建国
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安振涛
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张倩
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杜仕国
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姚凯
,
王金
材料导报
doi:10.11896/j.issn.1005-023X.2017.04.030
为评估氧化剂硝酸羟胺的热稳定性,使用标准液体铝皿于3 K/min、4 K/min、5 K/min加热速率下进行热分析.借助非等温DSC曲线的参数值,应用Kissinger法和Ozawa法求得热分解反应的表观活化能和指前因子,根据Zhang-Hu-Xie-Li公式、Hu-Yang-Liang-Xie公式、Hu-Zhao-Gao公式以及Zhao-Hu-Gao公式,计算硝酸羟胺的自加速分解温度和热爆炸临界温度,并对热分解机理函数进行了研究.设计了7条热分解反应路径,采用密度泛函理论B3LYP/6-311++G(d,p)方法对硝酸羟胺的热分解进行了动力学和热力学计算.计算结果表明,硝酸羟胺热分解的自加速分解温度TsADT=370.05 K,热爆炸临界温度Te0=388.68K,Tbp0=397.54 K,热分解最可几机理函数的微分形式为f(a) =17×(1-α)18/17.硝酸羟胺热分解各路径中,动力学优先支持路径Path 6、Path 5、Path 4和Path 1生成NO和NO2,其次是Path 2、Path 7和Path 3生成N2和N2O.温度在373 K以下时,Path 1'反应无法自发进行,硝酸羟胺无法进行自发的热分解.从热力学的角度来看,硝酸羟胺在370.05K以下储存是安全的.
关键词:
硝酸羟胺
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热分析
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热稳定性
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热分解机理
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密度泛函理论
中国腐蚀与防护学报
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关键词:
Europhysics Letters
Noncollinear magnetic investigations of the ground state in PrFeAsO have been performed by the density-functional theory. We calculated the total energy and made structure optimization, and the electronic density of states of PrFeAsO was analyzed. There are three different magnetic structures in PrFeAsO defined by experiments. Based on these magnetic structures, we studied four collinear and four noncollinear cases. The ground state is found to take the ordering proposed by Zhao, in which the FeAs plane is of stripe antiferromagnetism and Pr spins are perpendicular to Fe spins. The electronic density of states indicates that for PrFeAsO the increase of the electron Coulomb interaction leads to a decrease in conductivity. Copyright (C) EPLA, 2011
关键词:
high-temperature superconductivity;phase-diagram;oxypnictides;instability
王玉东
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付鹏
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李晓光
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刘民英
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赵清香
高分子材料科学与工程
用差示扫描量热(DSC)研究了尼龙612的等温结晶动力学.实验结果表明,在所研究的等温结晶温度范围内(184℃、186℃、188℃、190℃、192℃),尼龙612达到最大结晶速率时的时间、半结晶期和动力学结晶速率常数分别为:O.12min、0.19 min、0.22 min、0.29 min、0.59 min;0.15 min、0.22 min、0.24 min、0.33 min、0.64 min和22.03 min<'-1>、23.28min<'-1>、8.85 min<'-1>、5.15 min<'-1>、1.93 min<'-1>.等温结晶过程符合Avrmi方程,二次结晶现象不明显.在等温结晶过程中得到的Avrmi指数n在1.81～2.32之间,由理论分析可知,尼龙612等温结晶是一维生长和二维盘状生长.由Arrhenius方程求得尼龙612的等温结晶活化能ΔE=-209.5 kJ/mol.
关键词:
尼龙612
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等温结晶动力学
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结晶活化能
靳瑞敏
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陈兰莉
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罗鹏辉
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郭新峰
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卢景霄
材料导报
用玻璃作衬底在不同温度下用PECVD法直接沉积非晶硅(a-Si∶H)薄膜,在400℃和500℃分别光退火5min、10min、20min、30min、40min、60min、120min,用拉曼光谱分析前后样品,发现随着晶化时间的延长晶化效果越好,500℃退火的薄膜比400℃的晶化效果好.
关键词:
PECVD法
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非晶硅薄膜
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光退火晶化
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拉曼光谱
殷红旗
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刘永长
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宁保群
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徐荣雷
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张尧卿
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韩雅静
材料科学与工程学报
doi:10.3969/j.issn.1673-2812.2007.01.030
本文研究了T91钢冷却过程中,不同冷却速度(10 k/min(200 k/min)对相变速度和产物的影响.研究表明不同的冷却速度生成的组织差别较大,在较低速冷却下(10 k/min和30 k/min)的组织为较多的先共析铁素体和板条马氏体,中速冷却(30 k/min和50 k/min)基本都为板条马氏体,在较高速冷却过程中(100 k/min和200 k/min)组织中除了板条马氏体还出现了片状马氏体,另外冷却速度还影响了相变开始点和相变速度.
关键词:
T91
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冷却速度
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相变
