材料期刊网

LPCVD法制备硼掺杂硅薄膜特性及氢化

姚杰 , 章佩娴 , N.Du , K.P.Chik

材料研究学报

本文报告了LPCVD 制备的掺硼硅薄膜结构和物理性质分析,发现掺杂比R 在1×10~(-5)—4×10~(-2)的范围内,材料可划分为三种不同的相结构区:非晶态硅(a-Si)、非晶态硅-硼合金(a-Si∶B)和非晶态微晶硅(μc-Si)。物理性质测量也发现三种不同的结构区具有不同的特性和氢化规律。在a-Si∶B 区,霍尔系数符号是空穴导电的正号,而μc-Si 区材料进入简并状态。氢化明显地改善了材料的物理性质和掺杂效率,但对于重掺杂微晶区材料,氢化似乎使掺杂效率降低。

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DU-Ti合金表面N+Ti+多层Ti/TiN复合膜的制备与耐蚀性

严东旭 , 刘天伟 , 龙重 , 白彬 , 张鹏程 , 黄河 , 郎定木 , 王晓红 , 朱建国

材料保护

采用单一的表面改性技术难以提高贫铀钛合金(Du-Ti)的耐蚀性能.采用等离子体浸没离子注入技术依次在Du-Ti合金表面注入N和Ti,再利用非平衡脉冲磁控溅射技术制备多层Ti/,TiN,研究了膜层的形貌、结构及耐蚀性能.结果表明:膜层厚约3μm,呈柱状结构,致密,但存在一些微缺陷,膜基结合紧密;膜层出现面心立方结构的TiN和密排六方的Ti,在DU-Ti合金界面形成了少量的UO2,没有铀的氮化物;膜层耐蚀性能较基体得到较大提高;微观缺陷是TiN层局部片状脱落的主要原因,外层TiN出现片状脱落后.注入层和内层Ti/TiN多层膜仍能有效保护基体.

关键词: 等离子体浸没离子注入 , 非平衡磁控溅射 , 复合膜 , DU-Ti合金 , 电化学腐蚀 , 耐蚀性

低温区间的Fe-N二元相图理论分析

雷明凯 , 王兴军

无机材料学报 doi:10.3321/j.issn:1000-324X.2003.04.031

采用亚点阵的化合物能模型计算低温区间Fe-N二元相图.计算结果表明,25～350℃低温区,分别存在着Q-α-Fe(N)和γ′-Fe4N,γ′-Fe4N和ε-Fe2N1-x二相平衡.Q-α-Fe(N),γ′-Fe4N,ε-Fe2N1-x均为热力学稳定相.依据Guillermet和Du的热力学性质参数计算的低温区间Fe-N二元相图与现有实验数据相符.

关键词: Fe-N二元相图 , 热力学 , 模型

Du Pont推出全新应用的聚烯烃弹性体

合成材料老化与应用

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EFFECT OF PHOTOOXIDATION ON PHOTOLUMINESCENCE OF N, N'-DIPHENYL-N, N'-DI(M-TOLYL)-BENZIDINE AND RUBRENE CODOPED PMMA THIN FILMS

Y.B. Hou

金属学报(英文版)

In this paper, the PMMA films doped with N,N'-diphenyl-N,N'-di(m-tolyl)-benzidineand rubrene were fabricated by spin coating, and the effect of photooxidation onthe photoluminescence of the doped PMMA thin films was investigated. The resultsshowed that under the irradiation of 350nm UV light, N,N'-diphenyl-N,N'-di(m-tolyl)-benzidine can sensitized rubrene and results in the enhancement in the photooxrationof rubrene. The effect of photooxidation on the photoluminescence from rubrene w asmore obvious. Both lifetime measurement and in situ measurement of photolumines-cence showed that rubrene molecules exist in two chemical surroundings.

关键词: photoluminescence , null

p+-n--n结的势垒分布

赵普琴 , 杨锡震 , 李桂英 , 王亚非

液晶与显示 doi:10.3969/j.issn.1007-2780.2001.01.010

GaP∶N绿色LED发光效率的提高有赖于对其结构参数的优化。根据载流子分布的连续性，由泊松方程自洽求解，得出了半导体n--n结势垒分布的计算方法。在此基础上，计入n-区内的电位降，计算了商用发光二极管p+-n--n结构的势垒分布，为整体结构的参数优化准备了必要的条件。

关键词: 磷化镓 , 发光二极管 , 势垒

Thermodynamic Properties of FeCN and FeCBN Melts

CHEN Erbao , WANG Shijun , DONG Yuanchi , WU Baoguo , ZHOU Yun

钢铁研究学报(英文版)

The saturated solubility of carbon and nitrogen in FeCN and FeCBN melts was measured experimentally at 1 485 ℃ to obtain the activity interaction coefficients between components in these melts. A new method was used to treat experimental results. Using thermodynamic derivation and calculation, some important interaction coefficients between components in these melts were obtained.

关键词: FeCN melt;FeCBN melt;FeCB melt;interaction coefficient;thermodynamic property

Dispersion behavior of laser-synthesized Si3N4 nanopowders in N-N-dimethylformamide

Ceramics International

The dispersion behavior of Si3N4 nanopowders prepared by laser-induced gas-phase reaction in a non-aqueous solvent, N-N-dimethylformamide (DNIF) was studied, and triethanolamine (TEA) was selected as a dispersant. One hundred and sixty-six-day sedimentation tests were used to study the stability of the suspensions. Photon correlation spectroscopy was employed to measure the sizes of aggregates and coagulation rates. TEA was proved an effective dispersant for nano-Si3N4 in DMF, presoaking treatment could enhance the effect of the dispersant. TEA 1.0 wt.% referred to Si3N4 and a 1-month-presoaking gave the best dispersion, the dispersion stability was improved from several minutes to several months, and the average size of the aggregates was reduced to about a twenty-fifth. The dispersion ability of TEA was believed being related to its strong affinities both to the powder surface and to the solvent. (C) 2002 Elsevier Science Ltd and Techna S.r.l. All rights reserved.

关键词: Si3N4;dispersion;nanopowders;N-N-dimethylformamide;triethanolamine;composite;powders

The electronic structure and the ferromagnetic properties of Cu(mal)(DMF) (n)(mal = malonate dianion, DMF = N,N-dimethylformamide)

Journal of Magnetism and Magnetic Materials

We present first-principles study on the magnetic properties of the 3D metal-ligand coordination polymer [Cu(mal)(DMF)]n within the framework of density functional theory ( DFT) by using the full-potential linearized augmented plane-wave (FP-LAPW) method. The total and partial density of states ( DOS), the band structure, and the atomic spin magnetic moment of [ Cu( mal)( DMF)] n are calculated. The calculation reveals that [ Cu( mal)( DMF)] n is a ferromagnetic semiconductor. The calculated spin magnetic moment is about 1.000 mu B per molecule, which is in agreement with experimental value. (c) 2007 Elsevier B.V. All rights reserved.

关键词: first-principles;electronic structure;ferromagnetic properties;complexes;acid

通过J/Ψ→N(N-)M衰变研究N*时的核子极点效应

沈彭年 , 梁伟红 , 邹冰松

原子核物理评论 doi:10.3969/j.issn.1007-4627.2004.02.009

研究了J/Ψ→ p(p-)π衰变过程中核子极点图的贡献,特别是由离壳效应带来的贡献.发现衰变宽度对形状因子是敏感的.在通过用J/Ψ→ p(p-)π衰变研究N*时,核子极点图作为背景道的贡献是非常重要的; 在通过J/Ψ→ p(p-)η和 p(p-)η研究N*时,核子极点图的贡献可忽略不计; 在通过J/Ψ→ p(p-)ω研究N*时,核子极点图有明显的贡献.

关键词: J/Ψ衰变 , 核子激发态