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EFFECT OF REMOVING HYDROGEN FROM HEAVY RAIL STEEL BLOOMS BY STACK COOLING IN PANZHIHUA IRON AND STEEL COMPANY

XIAN Aiping LI Peiji CHEN Wenxiu WANG Yikang Institute of Metal Research , Academia Sinica , Shenyang , ChinaCHEN Renvi MEI Dongsheng Panzhihua Institute of Iron and Steel Research , Ministry of Metallurgical Industry , Panzhihua , China associate professor , Institute of Metal Research , Academia Sinica , Shenyang 110015 , China

金属学报(英文版)

The determination of dffusible hydrogen in U71Mn heavy rail steel,and hydrogen diffusivity as well as the hydrogen distribution in the cross section of blooms with stack cooling were stu- died.The results showed that,most of the hydrogen in blooms of heavv rail steel is diffusible, the hydrogen diffusivity in U71Mn rail steel blooms at room temperature is(0.85—1.02)× 10~(-6)cm~2/s,after stack cooling,the hydrogen content in bloom will decrease greatly which is helpful to form the flake-free phenomenon in the heavy rail produced by Panzhihua Iron and Steel Company.

关键词: rail steel , null , null , null

VARIATION OF HYDROGEN CONTENT IN MOLTEN HEAVY RAIL STEEL AT PANZHIHUA IRON AND STEEL COMPANY

XIAN Aiping LI Peiji CHEN Wenxiu WANG Yikang Institute of Metal Research , Academia Sinica , Shenyang , ChinaCHEN Renyi MEI Dongsheng Panzhihua Institute of Iron and Steel Research , Panzhihua , China associate professor.Institute of Metal Research , Academia Sinica , Shenyang 110015 , China

金属学报(英文版)

At panzhihua Iron and Steel Company,hydrogen content in molten heavy rail steel is rather low during smelting in the oxygen top-blown converter,and sloightly increases in tapping and pouring.Average H content varies from 2.0(dry season)to 2.4 ppm(rainy season)at smelt- ing end;2.8 ppm in ladle;and 2.1 ppm(dry season)to 2.3 ppm(rainy season)in mould, which is on a level with RH vacuum circle.The low hydrogen content in molten steel,which is due to both the very dry climate in Panzhiihua region and the LD smelting process,is the main reason why there is little flake in the heavy rail produced by Panzhihua Iron and Steel Com- pany.

关键词: smelting , null , null , null , null

The Ionization Theory of Desulphurization of the Panzhihua Blast Furnace Slag

WEI Shoukun University of Science and Technology Beijing , China.

材料科学技术(英文)

With the proper choice of the ion species present in the Panzhihua blast furnace slag, the sulphur partition ratio was calculated based on the ionization theory of the slag. It can be concluded that TiO_2 reacts as an acidtc oxide and the Panzhihua ore or concentrate cannot be treated as a semi-self-fluxing ore.

关键词: blast furnace slag , null , null

STRAIN INDUCED PRECIPITATION OF Ti(V)N(C)IN HIGHCARBON STEEL

FANG Shufang , ZHANG Jian Panzhihua Institute of Iron and Steel Research , Panzhihua , China Laboratory of Physics , Panzhihua Institute of Iron and Steel Research , Dukou City , 617000 Sichuan , China

金属学报(英文版)

The precipitation of Ti(V)N(C)in high-carbon steel PD_3 during thermomechanicol treatment at austenitic temperatures after deformation has been observed.The average size of Ti(V)N(C)particles may reduce with the increase of strain and the decrease of thermomechanical treatment temperature,and vise versa.The growth of Ti(V)N(C)particles at 920°C is found to be controlled by the interface reaction between precipitated particles and matrix.

关键词: Ti(V)N(C) , null , null

Recovery of Titanium from the Rich Titanium Slag by H2SO4 Method

Zhenqi HUANG , Minghua WANG , Xinghong DU , Zhitong SUI

材料科学技术(英文)

The blast furnace slag bearing TiO2 in Panzhihua, China, is an important resource to be utilized. In the present paper, the effects of the ratio of slag to H2SO4, the reaction temperature, the particle size of the slag, and the concentration of H2SO4 on the reaction rate and the acidolysis ratio of Ti were studied. The results indicated that the maximum acidolysis ratio reached 98%, which can serve as an experimental basis for the production of titania from the slag.

关键词: Slag bearing TiO2 , null , null , null

Application of Adaptive Threading Technique to Hot Strip Mill

DING Jingguo , HU Xianlei , JIAO Jingmin , SHE Guangfu , LIU Xianghua

钢铁研究学报(英文版)

Thickness deviation of hot strip rolling needs to be strictly controlled in the computer system. An adaptive threading technique was researched, in which the measured data from threaded stands were used to predict thickness and material hardness errors, to modify the setup for the remaining unthreaded stands. After the adaptive threading model was used online on the hot strip mill of the Panzhihua Iron and Steel Group Co Ltd, the thickness deviation was decreased obviously. The hit rate of thickness control of different steel grades increases.

关键词: hot strip mill;adaptive threading;thickness deviation;stretch equation

Comprehensive Utilization of Complex Titania Ore

YUAN Zhangfu , PAN Yifang , ZHOU E , XU Cong , LI Shuqing

钢铁研究学报(英文版)

To fully utilize Panzhihua titanium resources, a new process was proposed. In the process, Panzhihua ilmenite concentrate was first reduced in a rotary hearth furnace (RHF) to produce a titaniumrich material and iron. The titaniumrich material was then used in a new chlorination process to produce TiCl4. The comparison of different groups of experimental results or calculation results showed that the utilization ratio of material was improved by using the titaniumrich material after pretreatment other than low level titanic ilmenite directly and the combined fluidized beds (FTF) were more likely to reduce bed height and reaction time than the single fluidized beds (Single F or Single T) under the condition of the same chlorination conversion ratio. Finally, the influence of reduction temperature and the antiagglomeration capacity of the combined fluidized bed was analyzed.

关键词: ilmenite;rotary hearth furnace;fluidized bed;antiagglomeration

A NEW PROCESS FOR PRODUCING HIGH GRADE GRAPHITE FOR USE IN MANUFACTURING Mg-C BRICKS IN

Y.Z. Lan , S. Zhang

金属学报(英文版)

Based on the characteristics of graphite ore from Panzhihua district, the present research tried to find a new technology to increase the purity of the graphite carbon from 93% to 97%. Study was conducted on leaching agents, time, temperature, stirring speed and concentration of leaching solution affecting the process. The technological parameters chosen were: L / S=3:1, reaction time 30min, 5% concentration of sulfuric acid, reaction temperature 70℃, stirring speed 200rev/min. The results of the continuing tests with one kilogram showed that the graphite content can be increased from 93% to 97%, which reaches the requirement for high grade graphite. When waste acid from coke making is used to leach graphite, the result is also satisfactory, but the treatment of waste solution containing organic substances has to be further investigated.

关键词: graphite ore , ore , High , grade , Chemical , metho

Control Model of Bloom Dynamic Soft Reduction

CHEN Yong , JI Cheng , ZHU Miaoyong , WU Guorong

钢铁研究学报(英文版)

There are significant effects of process parameters on internal qualities of bloom, and these process parameters are as follows: position and reduction amount, reduction distribution, reduction rate, and so on. Developing a control model is the key to apply soft reduction technology successfully. As the research object, 360 mm×450 mm bloom caster in PISCO (Panzhihua Iron and Steel Co) has been studied, and the research method for control model of dynamic soft reduction has been proposed. On the basis of solidification and heat transfer model, the position of soft reduction and reduction distribution of each frame are determined according to the bloom temperature distribution and solid fraction in bloom center calculated. Production practice shows that the ratio of center porosity which is less than or equal to 10, increased to 9727%, ratio of central segregation which is less than or equal to 05, increased to 8091%, and ratio of central carbon segregation index which is more than or equal to 110, decreased to 4% with the applying model of dynamic soft reduction.

关键词: bloom continuous casting;dynamic soft reduction;control model;center porosity;central segregation

Dynamic Soft Reduction Technology for Bloom Casting

CHEN Yong , et al

钢铁研究学报(英文版)

The dynamic soft reduction technology for 360mm×450mm bloom casting and its application results at PISCO (Panzhihua Iron & Steel Co.) were presented. In order to analyze the influence of the soft reduction on internal defects of bloom, such as center porosity and central segregation, experiment for contrasting process with or without soft reduction for bloom was investigated. The operation shows that after applying the soft reduction of bloom alloy steel, the ratio of center porosity whose defect level is below 1.0 increased from 66.67% to 85.71%, ratio of central segregation whose defect level is below 1.0 increased from 94.44% to 100%, ratio of central shrinkage cavity which is free increased from 88.89% to 96.42%, and central segregation index of carbon decreased from mean value of 1.15 to 1.05. These results have provided important technology supports for PISCO to optimize the steel product structure, and to improve the production of high quality, property, and value added products.

关键词: continuous casting bloom;dynamic soft reduction;alloy steel;internal quality

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