{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用溶胶-凝胶法合成<span style=\"color:red\">ZnAl2O4</span>.探讨了加入浓硫酸、金属离子(Zn<span style=\"color:red\">2</span>+,Al<span style=\"color:red\">2</span>+)、乙二醇及络合剂的物质的量比(R),煅烧温度对产品的影响；通过X射线衍射(XRD)和扫描电镜(SEM)对<span style=\"color:red\">ZnAl2O4</span>进行了表征；确定高纯度<span style=\"color:red\">ZnAl2O4</span>的最佳合成条件为:强酸条件,R为1∶<span style=\"color:red\">2</span>∶6∶30,700℃煅烧<span style=\"color:red\">2</span> h.将制备的<span style=\"color:red\">ZnAl2O4</span>与Sb<span style=\"color:red\">2O</span>3应用于软质聚氯乙烯(PVC)的阻燃,添加1 phr <span style=\"color:red\">ZnAl2O4</span>,极限氧指数(LOI)达28.8％,烟密度等级(SDR)达75.68％；当与Sb<span style=\"color:red\">2O</span>3混合质量比为<span style=\"color:red\">2</span>∶8时,添加10phr的阻燃效果相对较好,LOI 达35.8％,SDR达92.16％.","authors":[{"authorName":"徐建中","id":"1384710e-725b-4360-a052-e8d7aa1035bd","originalAuthorName":"徐建中"},{"authorName":"刘彩红","id":"804d58e6-114d-40c9-bcc7-7e90d30a2fd7","originalAuthorName":"刘彩红"},{"authorName":"王春征","id":"55e0ec2f-5395-4baa-86dd-63848cf38374","originalAuthorName":"王春征"},{"authorName":"焦运红","id":"39050b31-7c8f-4d3c-ae19-6f4939cb96b8","originalAuthorName":"焦运红"},{"authorName":"王成成","id":"2c304dd9-94ec-46d8-8fdb-9ceb086c3588","originalAuthorName":"王成成"}],"doi":"","fpage":"124","id":"8bce0747-610c-4095-abf4-e5a177ebee0f","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"1e5a5a14-8d47-461a-a7f9-ea4a2ecbcc34","keyword":"<span style=\"color:red\">ZnAl2O4</span>","originalKeyword":"ZnAl2O4"},{"id":"6b28f0e7-d5e3-4279-8d70-76fd19c95c33","keyword":"溶胶-凝胶","originalKeyword":"溶胶-凝胶"},{"id":"2640d065-073e-497e-880f-25706b5bac05","keyword":"聚氯乙烯","originalKeyword":"聚氯乙烯"},{"id":"0b0710c2-8106-48f9-bc02-a717d7bfccb3","keyword":"阻燃","originalKeyword":"阻燃"},{"id":"7f2748c2-6275-47f4-8cbe-2cacd5041d61","keyword":"消烟","originalKeyword":"消烟"}],"language":"zh","publisherId":"gfzclkxygc201303030","title":"<span style=\"color:red\">ZnAl2O4</span>的合成及在软质聚氯乙烯(PVC)中的阻燃应用","volume":"29","year":"2013"},{"abstractinfo":"采用基于密度泛函理论的第一性原理方法对<span style=\"color:red\">ZnAl2O4</span>的能带结构、态密度、布居分布及光学性质进行了理论计算.结果表明:<span style=\"color:red\">ZnAl2O4</span>为直接带隙半导体,能带宽度为3.91 eV；价带主要由<span style=\"color:red\">O2</span>p态和Zn3d态构成,导带主要由Al3s,3p态构成；<span style=\"color:red\">ZnAl2O4</span>为离子和共价兼有的化合物；并利用计算的能带结构和态密度分析了<span style=\"color:red\">ZnAl2O4</span>材料的复介电函数,光电导率,折射率以及消光系数等光学性质.且静态介电函数ε1(0)=3.35,静态折射率n0 =1.83.","authors":[{"authorName":"可祥伟","id":"d267a840-cf00-42dc-a5c3-360662cf8b47","originalAuthorName":"可祥伟"},{"authorName":"张蓉","id":"1d9dd677-c52c-4d23-82c4-7bee32cf0851","originalAuthorName":"张蓉"},{"authorName":"杨春燕","id":"cc3e3797-6371-45a5-a92e-f93cc2dc8bb2","originalAuthorName":"杨春燕"},{"authorName":"刘骞","id":"088bf10d-9c62-4fc9-aedd-ec8c9cb992aa","originalAuthorName":"刘骞"},{"authorName":"张利民","id":"657cebd9-4e95-4a87-bef4-f6a3028195be","originalAuthorName":"张利民"}],"doi":"","fpage":"268","id":"59d2838e-6940-4262-8889-1c9fa1f3216c","issue":"2","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"28d67d03-3ee8-463e-a960-aed0e775c896","keyword":"<span style=\"color:red\">ZnAl2O4</span>","originalKeyword":"ZnAl2O4"},{"id":"31b17932-e9d3-4515-acf0-0bb49c586d3b","keyword":"电子结构","originalKeyword":"电子结构"},{"id":"bf527491-0bc4-428d-ad73-85249551751d","keyword":"布居分布","originalKeyword":"布居分布"},{"id":"0d0d84a3-fc89-4cdf-ad18-09de478d6389","keyword":"光学性质","originalKeyword":"光学性质"}],"language":"zh","publisherId":"rgjtxb98201302015","title":"<span style=\"color:red\">ZnAl2O4</span>的电子结构及光学性质的第一性原理计算","volume":"42","year":"2013"},{"abstractinfo":"通过传统的固相反应合成掺杂<span style=\"color:red\">ZnAl2O4</span>和La3+(来自La<span style=\"color:red\">2O</span>3)的Ca0.61 Nd0.26TiO3-MgTiO3复合陶瓷粉体,干压成型后在空气气氛下常压烧结制备<span style=\"color:red\">ZnAl2O4</span>和La3+掺杂Ca0.61Nd0.26TiO3-MgTiO3复合陶瓷样品.分别研究了La3+和<span style=\"color:red\">ZnAl2O4</span>的掺杂量对复合陶瓷样品的微观形貌、相组成和介电性能的影响.结果表明:<span style=\"color:red\">ZnAl2O4</span>具有细化晶粒的作用;Ca0.61Nd0.26TiO3-MgTiO3复合陶瓷样品的致密度随La3+和<span style=\"color:red\">ZnAl2O4</span>含量的增加而增加;介电常数和谐振频率温度系数随<span style=\"color:red\">ZnAl2O4</span>含量的增加而减小,随La<span style=\"color:red\">2</span> <span style=\"color:red\">O</span>3添加量变化不大;品质因数值随<span style=\"color:red\">ZnAl2</span> <span style=\"color:red\">O4</span>含量的增加先增加后减小.制备出的<span style=\"color:red\">ZnAl2O4</span>和La3+掺杂Ca0.61Nd0.26TiO3-MgTiO3复合陶瓷致密度达到94％以上,介电常数在40～50之间,谐振频率温度系数小于40×10-6℃1,品质因数大于38 000 GHz,可以用于通信技术领域.","authors":[{"authorName":"张茜","id":"b270246f-9be1-49b8-893b-2d44455f93d9","originalAuthorName":"张茜"},{"authorName":"董桂霞","id":"1c0d7da2-a566-4e26-a4ba-b11d9b6b39ee","originalAuthorName":"董桂霞"},{"authorName":"吕易楠","id":"013f4543-5070-47e8-8ff7-b2b9602a1433","originalAuthorName":"吕易楠"},{"authorName":"韩伟丹","id":"4ad13ad6-d152-4607-9f04-d4cb36b41c98","originalAuthorName":"韩伟丹"},{"authorName":"李媛媛","id":"2af1316b-dcc6-4f17-b98c-4066043112a7","originalAuthorName":"李媛媛"}],"doi":"10.13801/j.cnki.fhclxb.20160612.003","fpage":"859","id":"91a3a1f3-a833-4010-b3e9-e2391d9a6d83","issue":"4","journal":{"abbrevTitle":"FHCLXB","coverImgSrc":"journal/img/cover/FHCLXB.jpg","id":"26","issnPpub":"1000-3851","publisherId":"FHCLXB","title":"复合材料学报"},"keywords":[{"id":"d5a6910f-47a9-4c97-a646-2827da17dde1","keyword":"复合陶瓷","originalKeyword":"复合陶瓷"},{"id":"1901ef00-8755-4332-88ea-72f105764f3c","keyword":"Ca0.61 Nd0.26 TiO3","originalKeyword":"Ca0.61 Nd0.26 TiO3"},{"id":"ac2eded6-c2bc-4224-86fa-8f067250a861","keyword":"MgTiO3","originalKeyword":"MgTiO3"},{"id":"459d5ba5-e407-46ea-8d08-3b002400f93f","keyword":"<span style=\"color:red\">ZnAl2O4</span>","originalKeyword":"ZnAl2O4"},{"id":"17d5a281-0827-4469-a76a-d02fa3847255","keyword":"介电性能","originalKeyword":"介电性能"},{"id":"bb1dbbcd-e6ad-430e-95cb-8c28048048ee","keyword":"致密性","originalKeyword":"致密性"}],"language":"zh","publisherId":"fhclxb201704021","title":"<span style=\"color:red\">ZnAl2O4</span>和La<span style=\"color:red\">2O</span>3对Ca0.61Nd0.26TiO3-MgTiO3复合陶瓷介电性能的影响","volume":"34","year":"2017"},{"abstractinfo":"利用喷雾热解技术,在硅片衬底上生长了锰掺杂<span style=\"color:red\">ZnAl2O4</span>光致发光纳米薄膜.XRD分析测试结果表明,当AlCl3在Zn(OH)<span style=\"color:red\">2</span>中的含量高于20%,衬底温度高于100℃时,在衬底上形成<span style=\"color:red\">ZnAl2O4</span>-ZnO纳米复合薄膜;该复合薄膜经0.1mol/L盐酸处理后,形成<span style=\"color:red\">ZnAl2O4</span>尖晶石矿纳米薄膜.同时研究了金属锰离子掺杂<span style=\"color:red\">ZnAl2O4</span>纳米薄膜的光致发光性能,荧光光谱实验结果表明这种利用喷雾热解技术生长的掺锰<span style=\"color:red\">ZnAl2O4</span>尖晶石纳米薄膜,在525nm附近有一发光带,为Mn<span style=\"color:red\">2</span>+的<span style=\"color:red\">4</span>T1(<span style=\"color:red\">4</span>G)-6A1(6S)跃迁.","authors":[{"authorName":"杨永德","id":"934e7bed-5fb4-4df4-9115-4f9cf2728b35","originalAuthorName":"杨永德"}],"doi":"10.3969/j.issn.1007-4252.2005.04.021","fpage":"492","id":"34831915-e9c8-445f-8ba6-57d33900f1d7","issue":"4","journal":{"abbrevTitle":"GNCLYQJXB","coverImgSrc":"journal/img/cover/GNCLYQJXB.jpg","id":"34","issnPpub":"1007-4252","publisherId":"GNCLYQJXB","title":"功能材料与器件学报   "},"keywords":[{"id":"0da8d359-1fac-47f8-8141-f303198af407","keyword":"铝酸锌纳米薄膜","originalKeyword":"铝酸锌纳米薄膜"},{"id":"125b3e1d-0ae9-47e5-83ba-bae2c79ed5b9","keyword":"喷雾热解法","originalKeyword":"喷雾热解法"},{"id":"81a0b97b-09de-4aed-a56d-83234cbb3430","keyword":"光致发光","originalKeyword":"光致发光"}],"language":"zh","publisherId":"gnclyqjxb200504021","title":"<span style=\"color:red\">ZnAl2O4</span>:Mn光致发光纳米薄膜的制备","volume":"11","year":"2005"},{"abstractinfo":"用超声-化学沉淀法制备了纳米铝酸锌(<span style=\"color:red\">ZnAl2O4</span>)粉末.超声辐射Al(NO3)3·9H<span style=\"color:red\">2O</span>、Zn(NO3)<span style=\"color:red\">2</span>·6H<span style=\"color:red\">2O</span>和沉淀剂得到沉淀物,再在850℃烘5 h制得平均粒径40 nm的纳米<span style=\"color:red\">ZnAl2O4</span>粉末.得到的纳米<span style=\"color:red\">ZnAl2O4</span>粉末用X射线衍射(XRD),扫描电子显微镜(SEM),傅立叶转换红外光谱(FT-IR)进行表征并得到确认.","authors":[{"authorName":"刘波","id":"73878808-34c9-485d-b5a5-79cfffe77198","originalAuthorName":"刘波"},{"authorName":"吕维忠","id":"7f3779c6-18c3-4207-a393-9d915cc06520","originalAuthorName":"吕维忠"},{"authorName":"罗仲宽","id":"ee74930d-a062-434e-9e37-f6dd39da7ec8","originalAuthorName":"罗仲宽"},{"authorName":"任祥忠","id":"9920d4af-cecd-4c46-a178-062dd76524b9","originalAuthorName":"任祥忠"},{"authorName":"张培新","id":"da915f80-6cea-4033-a5c7-d9910753675c","originalAuthorName":"张培新"},{"authorName":"刘剑洪","id":"f0d54132-32f5-445c-9af7-1a8cbf5cd3f7","originalAuthorName":"刘剑洪"}],"doi":"","fpage":"319","id":"d32a27a3-35b6-4767-a3df-5648fff95411","issue":"z2","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"ccf400c0-4d54-4279-b52f-84063e95530e","keyword":"尖晶石型","originalKeyword":"尖晶石型"},{"id":"7b70b270-d8ae-484e-a9c3-12ca4fa9b6f7","keyword":"纳米颗粒","originalKeyword":"纳米颗粒"},{"id":"f3c1f948-40b1-4c69-8920-b6baa0f3e497","keyword":"<span style=\"color:red\">ZnAl2O4</span>","originalKeyword":"ZnAl2O4"},{"id":"94ff8f6d-58ba-4277-b3f4-32ff8cce7c70","keyword":"超声波化学","originalKeyword":"超声波化学"},{"id":"1855dfc8-a6d9-4621-9fa2-1360b5e1adb9","keyword":"制备","originalKeyword":"制备"},{"id":"d54189f4-c708-4a63-8eb3-b12397fb8654","keyword":"表证","originalKeyword":"表证"}],"language":"zh","publisherId":"xyjsclygc2008z2083","title":"超声-化学沉淀法制备纳米尖晶石型铝酸锌","volume":"37","year":"2008"},{"abstractinfo":"提出了新的掺杂离子局域结构畸变模型,称之为配体离子移动模型,建立了此模型下晶体微观结构与电子顺磁共振(EPR)参量之间的定量关系.首次在考虑SS(spin-spin)、SOO(spin-other-orbit)和OO(orbit-orbit)作用的基础上,采用全组态完全对角化方法,对<span style=\"color:red\">ZnAl2O4</span>∶Cr3+晶体的局域晶格畸变、EPR参量及其电子精细光谱进行了系统的研究,结果表明,Cr3+离子掺入<span style=\"color:red\">ZnAl2O4</span>晶体后,<span style=\"color:red\">O2</span>-离子在氧平面上向远离[111]轴的方向移动了(0.01777±0.00007)nm.从而成功地解释了<span style=\"color:red\">ZnAl2O4</span>∶Cr3+晶体的EPR参量.同时研究也表明,OO磁相互作用并不引起新的能级分裂,只使能级产生移动,能级移动达到10cm-1的量级,但对ZFS参量的贡献甚微.","authors":[{"authorName":"杨子元","id":"7629fad0-1200-4c69-9051-b5e86b4cee08","originalAuthorName":"杨子元"},{"authorName":"魏群","id":"22402eea-8e3e-4824-b3f5-bbbf3e034fb3","originalAuthorName":"魏群"}],"doi":"","fpage":"1011","id":"41c3839e-e58c-4757-b0d3-33c3d23607b0","issue":"7","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"65d91d58-eeeb-4760-976e-b28e30c9a88a","keyword":"<span style=\"color:red\">ZnAl2O4</span>:Cr3+晶体","originalKeyword":"ZnAl2O4:Cr3+晶体"},{"id":"7f292ac1-5350-4191-8859-19c6b6be8498","keyword":"配体离子移动模型","originalKeyword":"配体离子移动模型"},{"id":"89ff7af2-5863-4534-a0a5-a316150d1b5a","keyword":"局域晶格畸变","originalKeyword":"局域晶格畸变"},{"id":"96d457c8-90b2-40d7-aa29-df005442c60a","keyword":"磁相互作用","originalKeyword":"磁相互作用"}],"language":"zh","publisherId":"gncl200507012","title":"<span style=\"color:red\">ZnAl2O4</span>:Cr3+晶体局域结构研究","volume":"36","year":"2005"},{"abstractinfo":"用改进的聚丙烯酰胺凝胶法制备颗粒近似呈球形且粒度均匀的<span style=\"color:red\">ZnAl2O4</span>纳米颗粒,并制备了3种锌铝摩尔比的ZnA1<span style=\"color:red\">O</span>样品.XRD结果表明,当锌铝摩尔比为1:1.8和1:<span style=\"color:red\">2</span>时,在900℃煅烧干凝胶制备的样品均为纯相的ZnAhO<span style=\"color:red\">4</span>粉体.SEM结果表明,锌铝摩尔比为1:<span style=\"color:red\">2</span>制备的样品其颗粒尺寸随着煅烧温度的提高而增大,且在900℃出现严重的团聚.荧光光谱分析结果表明,激发波长为352 nm时出现一个469 nm的蓝光发射峰.基于实验结果,研究了其络合机理和发光机理.","authors":[{"authorName":"孙光壮","id":"9224faa2-b1d9-48bc-bce9-1f53b8cc5bc6","originalAuthorName":"孙光壮"},{"authorName":"王仕发","id":"574b8da3-64f6-4db6-bff5-c2e7f7fa8ccb","originalAuthorName":"王仕发"},{"authorName":"孙光爱","id":"b3597d63-20d1-432d-bdbb-49205faa7673","originalAuthorName":"孙光爱"},{"authorName":"向霞","id":"dcd79510-3e15-4dfc-b0cf-b0917df8324f","originalAuthorName":"向霞"},{"authorName":"祖小涛","id":"b7c0e0c9-547d-4322-9f53-0fb7d6ccbf23","originalAuthorName":"祖小涛"}],"doi":"","fpage":"721","id":"5e59fedb-ee7b-4853-a075-a9fb309a7110","issue":"10","journal":{"abbrevTitle":"CLYJXB","coverImgSrc":"journal/img/cover/CLYJXB.jpg","id":"16","issnPpub":"1005-3093","publisherId":"CLYJXB","title":"材料研究学报"},"keywords":[{"id":"f3031a50-4e92-49c5-8e86-1cf88eafeff7","keyword":"无机非金属材料","originalKeyword":"无机非金属材料"},{"id":"b9966ee6-46a2-4c5d-8b79-641078660647","keyword":"聚丙烯酰胺凝胶法","originalKeyword":"聚丙烯酰胺凝胶法"},{"id":"5c2f473a-68a6-4374-87b3-42aca165c345","keyword":"<span style=\"color:red\">ZnAl2O4</span>","originalKeyword":"ZnAl2O4"},{"id":"4517c659-4aad-425f-8cdf-b076e27a1ff3","keyword":"蓝光发射","originalKeyword":"蓝光发射"},{"id":"2b6b1d41-1d05-44a9-b5d8-b71948504cd9","keyword":"络合机理","originalKeyword":"络合机理"}],"language":"zh","publisherId":"clyjxb201510001","title":"聚丙烯酰胺凝胶合成尖晶石纳米铝酸锌的络合机理及发光性能","volume":"29","year":"2015"},{"abstractinfo":"以Al<span style=\"color:red\">2</span>( SO<span style=\"color:red\">4</span>)3和Zn( NO3)<span style=\"color:red\">2</span>为原料,采用水热法合成铝酸锌微粉体,通过扫描电镜和XRD分析发现<span style=\"color:red\">ZnAl2O4</span>晶型良好,粒径小,呈纤维状均匀分布；进一步研究湿敏特性,结果表明:测试频率对阻抗-相对湿度(RH)特性曲线影响较大,阻抗随频率的增加而迅速减小,10KHz时在33％～95％的范围内曲线的线性度好,在相同的湿度下,试样的电容随频率的增加而减小,在低频100HZ下,电容随相对湿度的升高而增大.","authors":[{"authorName":"余德钦","id":"1f497fa8-9f34-4e38-be93-a7f3c94955b0","originalAuthorName":"余德钦"},{"authorName":"林彦旭","id":"a3de7d7e-cedc-45dd-801e-6f2fe28c05ca","originalAuthorName":"林彦旭"},{"authorName":"卢成浩","id":"5eeb3c7d-3ec4-47dd-83b8-1e91f4601b5f","originalAuthorName":"卢成浩"},{"authorName":"李锦堂","id":"ce98320d-dfe0-4b6a-a12d-e7faacfba34e","originalAuthorName":"李锦堂"},{"authorName":"罗学涛","id":"896a49f0-b667-45ba-af9a-3ce683586a32","originalAuthorName":"罗学涛"}],"doi":"10.3969/j.issn.1007-4252.2012.04.013","fpage":"332","id":"dff7e197-b11f-47d1-8af2-32b2f00dec45","issue":"4","journal":{"abbrevTitle":"GNCLYQJXB","coverImgSrc":"journal/img/cover/GNCLYQJXB.jpg","id":"34","issnPpub":"1007-4252","publisherId":"GNCLYQJXB","title":"功能材料与器件学报   "},"keywords":[{"id":"3bd6a5db-4725-450d-8b8d-2df5c45228cf","keyword":"铝酸锌","originalKeyword":"铝酸锌"},{"id":"fb619f3a-8fa9-43dc-a883-69d9875af725","keyword":"水热合成","originalKeyword":"水热合成"},{"id":"d08906e2-9e9b-44aa-94e0-de37b77bc1dd","keyword":"湿敏特性","originalKeyword":"湿敏特性"}],"language":"zh","publisherId":"gnclyqjxb201204013","title":"水热法合成<span style=\"color:red\">ZnAl2O4</span>及其湿敏性能研究","volume":"18","year":"2012"},{"abstractinfo":"采用溶胶-凝胶法制备Eu3+掺杂的<span style=\"color:red\">ZnAl2O4</span>/SiO<span style=\"color:red\">2</span>(ZAS)块状透明微晶玻璃发光材料.利用X射线衍射(XRD),透射电子显微镜(TEM)和荧光光谱(PL)等测试手段,系统研究了不同Eu3+掺杂浓度对ZAS发光性能的影响以及不同热处理温度对ZAS∶Eu3发光性能的影响.结果表明,ZAS∶Eu3+在611 nm处具有强烈的红光发射峰,发射强度随着Eu3+掺杂浓度的增加,出现浓度淬灭效应,当掺杂量为20mol％时,发光强度最大;随着热处理温度的升高,存在高温淬灭效应,当热处理温度为900℃时,材料发光强度最优.CIE色度图分析表明,ZAS∶0.20Eu3+是一种潜在、优良的红光显示微晶玻璃材料.","authors":[{"authorName":"崔祥水","id":"c8047c87-a48f-4f18-aabb-f53715b92994","originalAuthorName":"崔祥水"},{"authorName":"李巍","id":"f4db4bc7-ab96-49f7-853b-431bc22bc52e","originalAuthorName":"李巍"},{"authorName":"张劭锦","id":"db8c2f8b-b85c-4a86-814d-03f98f697ce4","originalAuthorName":"张劭锦"},{"authorName":"陈文哲","id":"6fe67980-d35c-411e-acc6-46ba6ed57964","originalAuthorName":"陈文哲"}],"doi":"","fpage":"632","id":"1081c81e-1403-4ec0-8d5e-ee15ae010855","issue":"3","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"3c3d0712-166c-4be3-a814-5f78b45daee1","keyword":"溶胶-凝胶法","originalKeyword":"溶胶-凝胶法"},{"id":"f735a0e1-0a7d-4110-9100-5e71f4ccf696","keyword":"<span style=\"color:red\">ZnAl2O4</span>/SiO<span style=\"color:red\">2</span>微晶玻璃","originalKeyword":"ZnAl2O4/SiO2微晶玻璃"},{"id":"4d5490d9-eed3-4247-b3c5-1e03c6efe0d3","keyword":"发光性能","originalKeyword":"发光性能"}],"language":"zh","publisherId":"rgjtxb98201503012","title":"Eu3+掺杂<span style=\"color:red\">ZnAl2O4</span>/SiO<span style=\"color:red\">2</span>微晶玻璃制备与发光性能","volume":"44","year":"2015"},{"abstractinfo":"采用一步水热法制备了ZnO/<span style=\"color:red\">ZnAl2O4</span>纳米复合物,通过浸渍法负载CuS、CdS和Bi<span style=\"color:red\">2</span>S3对其进行修饰,并在模拟太阳光照射下研究负载样品的光催化活性。用XRD、SEM、TEM、BET和FL等技术对所得样品进行表征,以NaOH 和Na<span style=\"color:red\">2</span>SO3作为光催化还原二氧化碳过程的牺牲剂,考察了硫化物种类及其负载量对ZnO/<span style=\"color:red\">ZnAl2O4</span>光催化还原活性的影响。结果表明,负载CuS和CdS均可提高ZnO/<span style=\"color:red\">ZnAl2O4</span>光催化还原活性,而负载Bi<span style=\"color:red\">2</span>S3却有所降低。当CuS负载量为1wt%时,样品光催化还原活性最佳,反应6 h后所得还原产物甲醇的生成量为8.21 mmol/gcat,在相同条件下较原样提高了约3.2倍。对CuS/ZnO/<span style=\"color:red\">ZnAl2O4</span>的光催化机理进行了初步探讨。","authors":[{"authorName":"张丽","id":"989ccc9f-a1b6-4b72-8691-9647daa08f3d","originalAuthorName":"张丽"},{"authorName":"张秀秀","id":"bd316b19-8ba9-4006-bcf7-e46866ff28aa","originalAuthorName":"张秀秀"},{"authorName":"戴超华","id":"bbe9f83f-dbb4-4677-bb37-e89104b4c556","originalAuthorName":"戴超华"},{"authorName":"欧阳杰","id":"6d18e94c-561a-4568-9569-9ea8f179cb78","originalAuthorName":"欧阳杰"},{"authorName":"阎建辉","id":"1b9b90fb-1891-4b9c-8f30-0e30dcdfd942","originalAuthorName":"阎建辉"}],"doi":"10.15541/jim20150567","fpage":"731","id":"5cbf59d5-f6a5-45f8-b095-d4caa34e7ff4","issue":"7","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"ab8c1031-a3a0-476e-a6ff-381b77ec023e","keyword":"ZnO/<span style=\"color:red\">ZnAl2O4</span>","originalKeyword":"ZnO/ZnAl2O4"},{"id":"1cd2f5f2-eb19-4b60-9f08-b1fcd8aabeba","keyword":"硫化物","originalKeyword":"硫化物"},{"id":"d1880f0a-bb78-4d91-89be-50661c7c047c","keyword":"光催化还原CO<span style=\"color:red\">2</span>","originalKeyword":"光催化还原CO2"}],"language":"zh","publisherId":"wjclxb201607010","title":"硫化物负载ZnO/<span style=\"color:red\">ZnAl2O4</span>复合空心球及其光催化还原CO<span style=\"color:red\">2</span>","volume":"31","year":"2016"}],"totalpage":9517,"totalrecord":95162}