Q.S. Liu1
,
2
,
3)
,
L.C. Zhao3)
,
G.X. Dong2) and N.J. Gu1) 1) Heibei University of Technology
,
Tianjin 300130
,
China 2) Tianjin Institute of Technology
,
Tianjin 300191
,
China 3) Harbin University of Technology
,
Harbin 150001
,
China
金属学报(英文版)
Theconstruction changinginthereversetransformation ofthestress induced εMin Fe 17 Mn 10 Cr 5 Si 4 Ni alloy is carefully inspected in transmission electron microscope, and then stress induced εM procedure of reverse transformation is analyzed. The behavior of reverse transformationisdissimilar when the organization of εMis different. The reversetransfor mation ofεM withtheshapeofsingle plateandstripisrelativelyeasy,anditsreversibilityincrystallographiciseasilytocarryout,fortheεM with multilayerstructure,thereversetrans formationtakes placein isolatedlayers, fortheεMthat grows well,thereversetransforma tion isrelatively difficult becauseofthe ductile harmonization between itsinternalorganiza tion structures.
关键词:
stress induced εM
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null
,
null
徐佩
,
卢旭鑫
,
汪传斌
,
杨善中
,
孙晓红
,
丁运生
高分子材料科学与工程
为改善多壁碳纳米管(MWNT)在低密度聚乙烯(LDPE)中的分散性及复合材料的界面特性,采用溴化-1-十六烷基-3-甲基咪唑基离子液体([C16min]Br)对MWNT进行表面改性,并用Raman光谱对改性效果进行了表征.将经过修饰的碳纳米管(MIL)与LDPE熔融共混得到MIL/LDPE复合材料,采用场发射扫描电子显微镜(FESEM)和阻抗分析仪(LCR)对复合材料的结构与介电性能进行了分析.结果表明,相比与MWNT/LDPE(渗流阈值为5.2%,介电常数为82,介电损耗为0.93),MIL/LDPE(渗流阈值为9.1%,介电常数为169,介电损耗为0.51)介电常数增大,介电损耗降低.并且在低温时,MIL/LDPE介电常数随温度的变化甚小,显示出良好的温度-介电常数特性.
关键词:
咪唑基离子液体
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碳纳米管
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低密度聚乙烯
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介电性能
李玉伟
,
陈继红
,
唐东明
,
张豹山
,
鹿牧
,
陆怀先
功能材料与器件学报
doi:10.3969/j.issn.1007-4252.2010.02.011
制备了一系列具有铁磁/反铁磁交换偏置作用的[NiO/Fe65Co35]10多层膜,使用振动样品磁强计(VSM)测量了样品的静磁参数,利用微带线法测量了样品4GHz-10GHz的磁谱,首次制备并测得了自然共振频率(fr)在6GHz以上,最高到f=9.6GHz的薄膜样品.结果表明交换偏置场(Hex)、各向异性场(Hua)、以及矫顽力(Hc)随铁磁层厚度(tFM)增大而减小;基于Landau-Lifishitz (L-L)方程对静磁参量和磁谱进行了比较,发现样品自然共振频率较L-L方程计算值偏大30%以上.
关键词:
铁磁
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反铁磁
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交换偏置场
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各向异性场
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交换耦合能密度
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自然共振频率
Acta Materialia
We present a comprehensive computational analysis of the deformation of ultrafine crystalline pure Cu with nanoscale growth twins. This physically motivated model benefits from our experimental studies of the effects of the density of coherent nanotwins on the plastic deformation characteristics of Cu, and from post-deformation transmission electron microscopy investigations of dislocation structures in the twinned metal. The analysis accounts for high plastic anisotropy and rate sensitivity anisotropy by treating the twin boundary as an internal interface and allowing special slip geometry arrangements that involve soft and hard modes of deformation. This model correctly predicts the experimentally observed trends of the effects of twin density on flow strength, rate sensitivity of plastic flow and ductility, in addition to matching many of the quantitative details of plastic deformation reasonably well. The computational simulations also provide critical mechanistic insights into why the metal with nanoscale twins can provide the same level of yield strength, hardness and strain rate sensitivity as a nanostructured counterpart without twins (but of grain size comparable to the twin spacing of the twinned Cu). The analysis also offers some useful understanding of why the nanotwinned Qu with high strength does not lead to diminished ductility with structural refinement involving twins, whereas nanostructured Cu normally causes the ductility to be compromised at the expense of strength upon grain refinement. (c) 2006 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
关键词:
nanocrystalline materials;nanoscale twins;crystal plasticity;copper;computational model;ni multilayer system;single-crystals;nanocrystalline metals;localized;deformation;plastic-deformation;activation volume;cu;microstructures;simulations;patterns
杨忠诚
,
谢发勤
,
姚小飞
,
吴向清
,
郭梦洛
材料导报
采用QU-100分别与NM500耐磨钢和0Cr18Ni9Ti不锈钢组成摩擦副,进行高温摩擦磨损实验,研究了温度对其干摩擦磨损性能的影响.结果表明:随着温度的升高,NM500的平均摩擦系数从常温的0.55降至600℃的0.41,磨损率从常温的1.23×10-4mm3·N-1·m-1降至600℃的0.33×10-4mm3·N-1·m-1;0Cr18Ni9Ti的平均摩擦系数从常温的0.306升至600℃的0.423,磨损率从常温的1.76×10-4mm3·N-1·m-1降至600℃的0.81×10-4mm3·N-1·m-1.高温形变和致密氧化膜的生成使NM500的摩擦系数和磨损率均随温度的升高而降低,而氧化膜的破坏导致0Cr18Ni9Ti的摩擦系数随温度的升高而升高.相同温度下NM500的磨损率小于0Cr18Ni9Ti,前者的耐磨性能优于后者.
关键词:
NM500
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0Cr18Ni9Ti
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温度
,
干摩擦磨损
王松
,
王兵
,
单娟娟
高分子材料科学与工程
以黄芩素(BAI)作为模板分子,α-甲基丙烯酸(MAA)为功能单体,乙二醇二甲基丙烯酸酯(EGDMA)为交联剂,偶氮二异丁腈(AIBN)为引发剂,采用沉淀聚合法不同溶剂体积制备了系列分子印迹聚合物.紫外光谱研究了模板与功能单体相互作用情况,傅里叶变换红外光谱、场发射扫描电子显微镜对其结构进行了表征,并通过动力学吸附和选择性吸附实验对其吸附动力学和热力学以及特异性识别进行了研究.结果表明,模板分子和功能单体之间通过氢键自组装形成1:4配合物;不同溶剂体积对聚合物微球的结构影响显著:随着溶剂体积增加,印迹聚合物微球粒径增加,而吸附量减小;其动力学吸附符合准二级动力学模型,吸附热力学表明其吸附以物理吸附为主;聚合物微球对不同结构底物槲皮素(Qu)和氯霉素(CAP)的吸附表现出低的吸附量,分离因子分别为17.69和26.03.
关键词:
黄芩素
,
分子印迹
,
微球
,
沉淀聚合
陈康
,
许希武
,
马凯
材料科学与工程学报
基于Ju和Chen提出的颗粒增强复合材料的一般细观力学方法,采用Qu给出的一阶近似修正的Eshelby张量,本文建立了考虑夹杂之间相互影响的含任意分布弱界面颗粒增强多相复合材料等效模量预测的一般细观力学方法,通过体积均匀化方法得到了一组细观力学本构方程.分别推导了忽略夹杂之间相互影响的弱界面多相复合材料宏观模量表达式以及考虑夹杂之间相互影响的弱界面两相复合材料的宏观模量表达式.此外,还给出了几种特殊复合材料体系在考虑界面弱化下的宏观等效性能参数的解析表达式,在界面粘结完好的假设下,给出的表达式均可以退化成经典的细观力学预测结果.在考虑夹杂之间相互影响的情况下,本文预测结果与实验数据吻合很好,验证了模型的有效性.
关键词:
夹杂之间相互影响
,
轻微弱化界面
,
细观力学
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等效性能参数
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颗粒增强复合材料