黄爱华
,
金鸣林
,
李和兴
,
房永征
材料导报
试验是以2种含不同QI的煤沥青为原料,采用变径反应管进行热转化反应制备有序性中间相的研究.试验采用偏光显微镜和扫描电镜(SEM)观察了原料各反应阶段的微观结构,考察了QI对热转化过程中中间相有序生长的影响,分析了热转化过程中软化点及族组分的变化.结果表明:少量的喹啉不溶物含量不会阻碍中间相有序的发展.高QI(2.03%)原料易生成镶嵌结构的中间相体,高温处理后样品呈轴状、短纤维、层片松散的石墨化焦结构;含低QI(0.11%)的原料能生成较好的、大区域的中间相体,域结构的中间相体在外力导向和内部裂解气流的作用下容易生成有序的半焦,高温处理后呈大区域、片层紧密、有序性强的细纤维焦结构.同时研究发现,在热转化过程中可通过测定软化点(SP)和TI含量来确定中间相转化程度.软化点约低于250℃、TI为75%左右时为初始中间相区域体形成阶段、半焦生成的前期.
关键词:
煤沥青
,
热转化反应
,
喹啉不溶物
,
中间相
李志宏
,
柳卫平
,
白希祥
,
郭冰
,
连钢
,
颜胜权
,
王宝祥
,
陆昀
,
曾晟
,
苏俊
原子核物理评论
doi:10.3969/j.issn.1007-4627.2005.01.006
利用8Li次级束测量了质心系能量7.8 MeV 2H(8Li, 9Li)1H反应的角分布, 导出了8Li(d, p)9Li反应的天体物理S因子及9Li→8Li+n虚衰变的渐近归一化系数.
关键词:
8Li(d,p)9Li反应
,
角分布
,
天体物理S因子
,
渐近归一化系数
HUANG Jianshun CHEN Junming Shanghai Institute of Metallurgy
,
Academia Sinica
,
Shanghai
,
China Research Associate
,
Shanghai Institute of Metallurgy
,
Academia Sinica
,
Shanghai 200050
,
China
金属学报(英文版)
Crystal structure of γ-Li_xFe_2O_3,inserted Li electrochemically,was studied by Moss- bauer spectroscopy together with X-ray diffraction,XPS and electrochemical method,On the insertion of Li at low current density,the crystal structure is keeping original spinel; while at higher current density or by thermal activation,owing to violent movement of Li~+ ions,part of crystal structure transforms into rock type similar to face-centered cubic structure of ferrous oxide.The transition channels during insertion of Li~+ ions and limitation of Li~+ ions inserted were discussed.
关键词:
null
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null
,
null
Journal of Materials Research
The effect of Li(3)N additive on the Li-Mg-N-H system was examined with respect to the reversible dehydrogenation performance. Screening Study with varying Li(3)N additions (5, 10, 20, and 30 mol%) demonstrates that all are effective for improving the hydrogen desorption capacity. Optimally, incorporation of 10 mol% Li(3)N improves the practical capacity from 3.9 wt% to approximately 4.7 wt% hydrogen at 200 degrees C, which drives the dehydrogenation reaction toward completion. Moreover, the capacity enhancement persists well over 10 de-/rehydrogenation cycles. Systematic x-ray diffraction examinations indicate that Li(3)N additive transforms into LiNH(2) and LiH phases and remains during hydrogen cycling. Combined structure/property investigations suggest that the LiNH(2) "seeding" should be responsible for the capacity enhancement, which reduces the kinetic barrier associated with the nucleation of intermediate LiNH(2). In addition, the concurrent incorporation of LiH is effective for mitigating the ammonia release.
关键词:
complex hydrides;improvement;mixtures;imides;amide;h-2
MANG Weishi WANG Guozhi ZHANG Yongchang HU Zhuangqi SHI Changxu Institute of Metal Research
,
Academia Sinica
,
Shenyang
,
China Yongchang Associate Professor
,
Institute of Metal Research
,
Academia Sinica
,
Shenyang 110015
,
China
金属学报(英文版)
A rapidly solidified microcrystalline Al-Li-Cu-Mg-Zr alloy and its superplasicity have been investigated.An optimum tensile elongation of 585% was obtained at 540℃ and strain rate 1.67×10~(-2)s~(-1).The superplastic Al-Li alloy is manufaetured using thermomechanical pro- cessing:solution,overaging,warm rolling and recrystallization.Microstructural changes in thermomechanical processing and cavitation occurred during superplastic deformation have been observed.The superplastic failure of alloy may be caused mainly by nucleation and growth of cavities as well as the linkage around grains.
关键词:
superplasticity
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null
,
null
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null
