材料期刊网

R. erythropolis对赤铁矿和石英的吸附?捕收作用

杨慧芬 , 唐琼瑶 , 王传龙 , 张露 , 李甜

中国有色金属学报

为考察红城红球菌(Rhodococcus erythropolis,R. erythropolis)作为赤铁矿捕收剂使用的可能性及效果,对R. erythropolis形貌、细胞壁成分及其吸附前后赤铁矿、石英表面电性、疏水性进行分析,对赤铁矿、石英单矿物以及赤铁矿与石英矿1:1(质量比)混合矿进行浮选实验,对其在赤铁矿表面的吸附状况及吸附机理进行研究.结果表明,杆状R. erythropolis表面既含有非极性基团,又含有极性基团,使得其表面具有较高的负电性和较强的疏水性,因而对赤铁矿的吸附作用明显大于对石英的吸附作用.当以此细菌为捕收剂、在溶液 pH 值为6、R. erythropolis用量为75 mg/L时,赤铁矿的回收率为89.68%,而石英的回收率仅为26.25%.混合矿经过一次浮选,可获得铁品位和回收率分别为50.08%和76.41%的铁精矿.R. erythropolis在赤铁矿表面发生复杂的化学吸附且使赤铁矿颗粒形成疏水絮团,从而证实R. erythropolis可作为赤铁矿的捕收剂使用.

关键词: R. erythropolis , 微生物 , 赤铁矿 , 石英 , 吸附 , 絮团 , 捕收剂

碳纳米管和碳化硅对铜混合纳米复合材料显微组织和干滑动磨损行为的影响

H. M. MALLIKARJUNA , C. S. RAMESH , P. G. KOPPAD , R. KESHAVAMURTHY , K. T. KASHYAP

中国有色金属学报(英文版) doi:10.1016/S1003-6326(16)64449-7

研究了多壁碳纳米管和碳化硅包覆铜增强铜基混合纳米复合材料的显微组织和摩擦性能。碳纳米管含量为1%~4%，碳化硅含量固定在4%。铜杂化纳米复合材料的合成过程包含球磨、冷压、烧结，随后热压。对混合纳米复合材料进行了密度、晶粒尺寸和硬度测试。在不同载荷条件下，在销?钢盘摩擦仪上采用干滑动磨损评估纳米复合材料的摩擦性能。结果表明，与纯铜相比，混合纳米复合材料的晶粒尺寸明显减小，4%碳纳米管增强杂化纳米复合材料的显微硬度提高了80%。混合纳米复合材料中碳纳米管含量的增加导致材料的摩擦因数和磨损率降低。

关键词: 铜 , 碳纳米管 , 碳化硅 , 显微硬度 , 磨损机制 , 纳米复合材料

多壁碳纳米管增强的Cu-Sn合金的显微组织和干滑动磨损行为

H. M. MALLIKARJUNA , K. T. KASHYAP , P. G. KOPPAD , C. S. RAMESH , R. KESHAVAMURTHY

中国有色金属学报(英文版) doi:10.1016/S1003-6326(16)64269-3

通过粉末冶金技术制备多壁碳纳米管(MWCNTs)增强的Cu?Sn合金纳米复合材料。CNTs的质量分数从0以0.5%的增量逐步增加到2%，研究纳米复合材料的密度、硬度、电导率和摩擦磨损行为。结果表明：纳米复合材料的密度随CNTs含量的增加而降低；添加CNTs能显著提高纳米复合材料的硬度；相对于没有增强的合金，纳米复合材料具有低的摩擦因数和更好的耐磨性。当外加负载为5 N时，与Cu?Sn合金相比，含量为2%的多壁碳纳米管增强的 Cu?Sn 合金纳米复合材料的摩擦因数和磨损量分别降低了72%和68%。报道了复合材料磨损表面的磨损机理。此外，合金的电导率随CNTs含量的增加而降低。

关键词: Cu-Sn合金 , 碳纳米管 , 纳米复合材料 , 粉末冶金 , 显微组织 , 干滑动磨损

Subsolidus phase relations and crystal structures of R-Ca-Cu-O (R = Nd, Sm, Gd, Tm) systems

Journal of Solid State Chemistry

The subsolidus phase relations of R2O3-CaO-CuO ternary systems (R = Nd, Sm, Gd, Tm) have been investigated by X-ray powder diffraction. All samples were synthesized at about 950degrees in air. There exists a ternary compound Ca14-xRxCu24O41 (x = 4 for R = Nd, Gd and x = 5 for R = Sm) and a ternary solid solution Ca2+xR2-xCu5O10 (R = Nd, Sm, Gd, Tm) with a wide composition range Deltax of about 0.6. The compound Ca14-xRxCu24O41 possesses a layered orthorhombic structure and is isostructural to Sr14-xCaxCu24O41. The lattice parameters a and c of the compound are basically independent of the ionic radius of R, while the lattice parameter b and unit-cell volume V decrease substantially with the decrease of the ionic radii of R. The Ca2+xR2-xCu5O10 solid solution is isostructural to Ca2+xY2-xCu5O10, the structure of which is based on an orthorhombic "NaCuO2-type" subcell containing infinite one-dimensional chains of edge-shared square planar cuprate groups crosslinked by the layered cations Ca and R that locate in the inter-chain tunnels. (C) 2002 Elsevier Science (USA). All rights reserved.

关键词: R2O3-CaO-CuO (R = Nd, Sm, Gd, Tm) systems;phase relations;Ca10R4Cu24O41 (R = Nd, Sm, Gd) structure;Ca2+xR2-xCu5O10 (R = Nd, Sm,;Gd, Tm) structure;ternary-system;approximately 950-degrees-c;high-pressure;superconductivity;diagram;air;er;compatibilities;property;oxide

R-line thermal shift and thermal broadenings of R, R' and B lines for ruby

Communications in Theoretical Physics

The unified theoretical calculation of thermal shifts (TS) of R-1 and R-2 lines and thermal broadenings (TB) of R, R' and B lines for ruby was carried out for the first time. The calculated results are in very good agreement with a great number of experimental data. Especially by using quantum theory and taking into account all the admixtures of wavefunctions within d(3) electronic configuration, all the Gamma M in electron-phonon interaction (EPI), the electronic energy spectrum and lattice-vibration Spectrum, the very important contributions to TS and TB from single-phonon direct process were theoretically calculated in detail. The microscopic essentials of various contributions are revealed, and the mistakes in previous work are remedied.

关键词: diamond anvil cell;pressure measurement;spectroscopy;temperatures

Theoretical calculations of thermal broadenings and transition probabilities of R, R ' and B line-groups for ruby

Communications in Theoretical Physics

On the basis of the unified calculation of the thermal shifts of R-1 line, R-2 line and ground-state-splitting as well as the thermal broadenings of R, R' and B line-groups for ruby, by taking into account all the levels and admixtures of wavefunctions within d(3) electronic configuration and all the GammaM in electron-phonon interaction, the transition probabilities of direct and Raman processes have theoretically been calculated. The thermal broadenings, of R, R' and B line-groups have successfully been interpreted in terms of the direct and Raman processes of acoustic phonons. The theoretically predicted transition probabilities are in good agreement with the experimental ones.

关键词: crystal fields;electron-phonon interaction;thermal broadening;transition probability;direct and Raman processes;shifts

Phase diagram of R-Fe-Co pseudoternary system with R <= 33.3% (mole fraction, R = Sm0.5Dy0.5)

Transactions of Nonferrous Metals Society of China

Phase equilibria of the R-Fe-Co pseudoternary system with R less than or equal to 33.3% ( mole fraction, R = Sm0.5Dy0.5) were determined in an isothermal section at 1073 K and a vertical section of RFe2-RCo2 by using OM, X-ray diffractometer, EP-MA DTA techniques. There are seven intermetallic phases: (Sm, Dy) (Fe, Co)(2), (Sm, Dy) (Fe, Co)(3), (Sm, Dy)(6) (Fe, Co)(23), (Sm, Dy)(2) (Fe, Co)(7), (Sm, Dy) (Fe, Co)(5), Th2Ni17-type and Th2Zn17-type (Sm, Dy)(2)(Fe, Co)(17). The (Sm, Dy)(6)(Fe, Co)(23) phase dissolves 36% Co(mole fraction) at 1073 K. However, the (Sm, Dy)(2)(Fe, Co)(7) phase in R-2(Fe1-xCox)(7) alloys dissolves about 19% Fe(mole fraction) at 1073 K.

关键词: rare earth-iron-cobalt;phase diagram;structure;compounds;sm-co;magnetic-properties;binary-system;magnetostriction

NEUTRON DIFFRACTION STUDY ON R_2Fel_(17)N_x(R=Y,Dy,Nd)

YANG Jilian ZHANC Baisheng DINC Yongfan China Institute of Atomic Engergy , Beijing , ChinaYANG Yingchang ZHANG Xiaodong Peking University , Beijing , ChinaPAN Shuming General Research Institute for Non-Ferrous Metals , Beijing , China associate professor , P.O.Box 275 , Branch No.30 , Beijing 102413 , China

金属学报(英文版)

The N occupying sites and magnetic structures in R_2Fe_(17)N_x(R=Y,Dy,Nd)are de- termined by neutron diffraction.The effects of the site occupation of N on magnetic properties are discussed primarily.

关键词: neutron diffraction , null , null , null , null , null

SPIN REORIENTATION AND EXCHANGE INTERACTIONS IN (ND, R)2FE14B (R = Y, GD)

Journal of Magnetism and Magnetic Materials

Exchange fields in both (Nd, Y)2Fe14B and (Nd, Gd)2Fe14B series are determined by analyzing spin reorientation. Results calculated for the two systems suggest that the R-R exchange interactions between R ions are comparable with the crystal-field interaction and that their effect might be taken into account for reproducing the spin-reorientation temperature.

关键词: magnetization process;crystal;nd2fe14b;r2fe14b;transition

R&D STATUS ON INTERMETALLICS IN CHINA

CHEN Guoliang(State Key Laboratory for Advanced Metals and Materials University of Science and Technology Beijing Beijing 100083 , China)SHI Changxu (Academia Sinica , Beijing 100864 , China)

金属学报(英文版)

This paper briefiy introduces the R&D of intermetallics in China. R&D on intermetallics in a national scale in China began near ten years ago. The investigation in past years focused on the fundamental research and materials development. A significant progress has been made. Various components that made of Ti3Al Ni3Al, TiAl and Fe3Al have been successfully manufactured Some of them have been evaluted. It is expected that some intermetallic alloys will be produced in an industrial scale in the near future.

关键词: :intermetallic alloys , null , null , null