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用薄板坯连铸连轧工艺生产北极高寒地区用API X70管线钢

AndreaCarboni , AlessandroPigani , GamalMegahed , S.K.Paul

钢铁

介绍了埃及Ezz带钢厂新近投产的由达涅利供货的技术装备。用这套灵活的薄板坯轧制(fTSR)设备生产在北极高寒地区使用的PAIX70管线钢,几炉钢水的试浇试轧结果已经证明,达涅利薄板坯连铸技术特别适合生产高强度低合金钢热轧带卷,即便是用于极为严酷的使用环境,其各项性能指标仍可超过标准规定的质量要求。

关键词: 薄板坯;HSLA;API X70;管线钢;北极地区应用

Creep rupture Behavior of K40S alloy at elevated temperatures

材料科学技术(英文)

Creep testing was conducted on K40S alloy. The detailed creep deformation and fracture mechanisms under constant load were studied. The results show that the stress exponent ranges between 7 and 14.4 at elevated temperature 973similar to1173 K, and that the activation energy is approximately 449.1 kJ/mol. During creep, the grain boundary sliding cut off primary carbides at the boundary, generating the "O" model cracks. The creep failure mode of K40S alloy is transgranular ductile and cracks originate at the primary carbides. A long carbide and matrix interface is often a preferential path for crack propagation. The creep mechanism is discussed in light of the creep microstructure, the stress exponent and the activation energy.

关键词: K40S alloy;creep;fracture;crack propagation;activation-energies;superalloy;term

Bain对应和K-S模型的数学描述

王宝奇 , 谷南驹 , 郭素珍 , 马晓莉

金属学报

利用Bain点阵对应对K-S模型的晶格改建过程进行了严密的数学描述.对于不同的马氏体正方度,提出了计算第一切变、第二切变及晶格调整的计算依据,并给出了普遍的计算公式.以Fe-1.4C和纯铁为例,计算了马氏体相变的点阵畸变.进一步分析表明,K-S模型实质是Bain模型的旋转.计算的结果与实测的取向关系相符合.

关键词: K-S模型 , null , null

Bain对应和K-S模型的数学描述

王宝奇 , 谷南驹 , 郭素珍 , 马晓莉

金属学报 doi:10.3321/j.issn:0412-1961.2002.05.006

利用Bain点阵对应对K-S模型的晶格改建过程进行了严密的数学描述.对于不同的马氏体正方度,提出了计算第一切变、第二切变及晶格调整的计算依据,并给出了普遍的计算公式.以Fe-1.4C和纯铁为例,计算了马氏体相变的点阵畸变.进一步分析表明,K-S模型实质是Bain模型的旋转.计算的结果与实测的取向关系相符合.

关键词: K-S模型 , 马氏体相变 , 点阵畸变

Cs-K混合蒸气中Cs(8D)+K(4S)碰撞能量转移

沈异凡 , 沈晓燕

量子电子学报 doi:10.3969/j.issn.1007-5461.2004.01.003

在Cs-K混合蒸气中,两步激发Cs原子到8D态,观察了Cs(8D)+K(4S)→Cs(5D)+K(4P)碰撞能量合并逆过程(REP,reverse energy pooling).应用双调制技术探测K(4P)原子发射的荧光,基态K原子密度用光学吸收方法测量.得到了REP速率系数,讨论了其它过程对速率系数的影响.

关键词: 光谱学 , 激发态原子 , 能量合并逆过程 , 速率系数

KⅧ-TbLⅣ离子3s3p 3P1-3s2 1S0 的自旋禁戒跃迁

牟致栋 , 魏琦瑛

原子核物理评论 doi:10.3969/j.issn.1007-4627.2004.01.015

在对KⅧ-TbLⅣ离子3s3p 3P1能级结构的多组态相互作用理论HXR方法计算的基础上, 分析了各种效应对等电子序列离子能级结构的影响, 找出了能级沿等电子序列变化的规律性. 预测计算了K Ⅷ-Tb LⅣ离子3s3p 3P1的能级. 由此进一步计算了KⅧ-TbL Ⅳ离子自旋禁戒跃迁3s3p 3P1-3s2 1S0的谱线波长、振子强度和跃迁概率.

关键词: KⅧ-TbLⅣ离子 , 自旋禁戒跃迁 , 波长 , 振子强度和跃迁概率

Hot corrosion behaviour of a cobalt-base super-alloy K40S with and without NiCrAlYSi coating

Corrosion Science

A NiCrAlYSi coating was deposited by arc ion plating on a cobalt-base super-alloy K40S to improve its hot corrosion resistance at 1173 K in air. The K40S suffered from accelerated corrosion and formed non-protective scale with poor adherence when its surface was beneath Na(2)SO(4) and Na(2)SO(4) containing 25 wt.% NaCl salt deposits. After the K40S was coated with NiCrAlYSi coating, a protective alpha-Al(2)O(3) scale was formed on the coating. Although the NiCrAlYSi coating changed into NiCoCrAlYSi during corrosion processes, it still possessed good corrosion resistance. In addition, the corrosion mechanisms were discussed on a basis of basic fluxing model. (C) 2011 Elsevier Ltd. All rights reserved.

关键词: Cobalt;Super-alloys;Metal coatings;EPMA;Hot corrosion;temperature oxidation behavior;aluminide coatings;cyclic oxidation;sprayed coatings;microstructure;superalloys;resistance;yttrium

Preparation and oxidation behavior of NiCrAlYSi coating on a cobalt-base superalloy K40S

Corrosion Science

Arc ion plating had been employed on a cobalt-base superalloy K40S to deposit a NiCrAlYSi coating to improve its oxidation resistance at 1323-1423 K in air. The K40S superalloy had poor oxidation resistance because a non-protective and easy spalling surface oxides scale mixed of Cr2O3 and CoCr2O4 was formed on its surface. After coated with NiCrAlYSi coating, a dense and protective alpha-Al2O3 scale was formed on the coating and excellently improved its oxidation resistance. Inter-diffusion obviously occurred between the coating and the substrate K40S superalloy in oxidation process, which resulted from Co atoms in K40S outwards diffused. A richen Cr and W carbides inter-diffusion layer was formed, which could acted as a diffusion barrier that barred Al atoms in coating inwards diffusion. Though the NiCrAlYSi changed into NiCoCrAlYSi during oxidation process, it still possessed a good oxidation resistance and. had a considerable long-term life. (C) 2008 Elsevier Ltd. All rights reserved.

关键词: cobalt-base superalloy K40S;NiCrAlYSi coating;arc ion plating;high;temperature oxidation;inter-diffusion;aluminide coatings;cyclic oxidation;alloys

Paul阱中射频源倍频作用下囚禁离子运动特性

陈图淼 , 聂宗秀

量子电子学报 doi:10.3969/j.issn.1007-5461.2003.01.010

基于以前的研究结果,采用函数级数展开法,研究了Paul阱中在非理想射频囚禁场作用下、考虑二次谐波φ=U-V1cosΩt-Vscos 2Ωt时囚禁离子运动特性,得到了单个囚禁离子运动Mathieu方程的解析解和z方向离子运动的特征频率(宏运动,微运动)随倍频参数的变化规律.

关键词: 运动特性 , 倍频效应 , Paul

Fatigue crack propagation behavior of K40S cobalt-base superalloy at elevated temperature

Transactions of Nonferrous Metals Society of China

Fatigue crack propagation behavior of K40S cobalt-base superalloy under ambient atmosphere at 700 degreesC and 900 degreesC was investigated. The detailed fatigue crack propagation and fracture mechanism under the alternating loads were studied. The results show that, there is a defined threshold for K40S alloy at elevated temperatures. The fatigue threshold is 23. 9 MPa . m(1/2) at 700 degreesC and 12 MPa . m(1/2) at 900 V. The significant decrease of the threshold with increasing temperature is associated with the oxidation induced embrittlement at crack tip. Observation on the fatigue fracture surfaces indicates a ductile fracture mechanism related to the fatigue crack growth.

关键词: cobalt-base superalloy;fatigue crack propagation;fatigue threshold;ductility;growth-behavior;alloy;steel

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