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Fe掺杂YbMnO3晶体的磁性增强研究

刘悦 , 孔勇发 , 许京军 , Sang-Wook Cheong

人工晶体学报

通过固相反应和熔融法制备了不同掺杂浓度的Fe掺杂锰酸镱(YbMnO3)晶体,并研究了晶体的铁磁性和反铁磁性性质.不同浓度掺杂YbMn1-xFexO3的晶格参数的变化及XRD物相分析显示,Fe离子进入了YbMnO3晶体的晶胞.磁学性质的测量表明,YbMn0.45Fe0.55O3晶体中存在明显提高的铁磁性质;与YbMnO3晶体相比,YbMn0.45Fe0.55O3晶体的尼尔温度由81 K大幅提高到116 K,同时晶体的反铁磁强度提高了两个数量级.YbMn1-xFexO3晶体具有比YbMnO3晶体更加优异的磁学性质.

关键词: YbMnO3晶体 , 铁磁性质 , 尼尔温度 , 熔融法

Mean-field theory for ferroelectricity in Ca(3)CoMnO(6)

Physical Review B

An elastic Ising model for CoMnO(6) chain is proposed to explain the ferroelectricity induced by collinear magnetic order in Ca(3)CoMnO(6), and then a mean-field theory with interchain spin interactions based on this model is developed. With inclusion of the dynamics of polarization domains at finite temperature, we address the rationality of our theory by the good agreement of the calculated electric polarization and dielectric susceptibility with the reported data on Ca(3)Co(2-x)Mn(x)O(6) (x approximate to 0.96) [Y. J. Choi, H. T. Yi, S. Lee, Q. Huang, V. Kiryukhin, and S.-W. Cheong, Phys. Rev. Lett. 100, 047601 (2008)], a typical diatomic Ising spin chain system, while the predicted magnetic susceptibility shows some difference from experiment, the reason of which is discussed.

关键词: calcium compounds;cobalt compounds;dielectric polarisation;ferroelectricity;Ising model;magnetic susceptibility;multiferroics;optical susceptibility;one-dimensional oxides;magnetic-properties;multiferroics;ca3co1+xmn1-xo6

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