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ELEVATED AND ROOM TEMPERATURE MECHANICAL BEHAVIOR OF BORON DOPED NiAl ALLOYS

TAN YiDalian University of Technology , Dalian , ChinaSHINODA THitachi Research Laboratory , Hitachi Ltd. 391-12 Hitachi , JapanMISHIMA YTokyo Institute of Technology , Nagatuta. Midori-Ku , Yokohama 227 , JapanSUZUKI TDepartment of Metallurgical Engineering , Tokyo Institute of Technology. Ookayama , Meguro-Ku , Tokyo 152 , Japan

金属学报(英文版)

The effects of boron addition on defect hardening at room temperature and on high temperature creep properties are investigated in the B2 NiAl intermetallic compound. It is found that boron addition is effective on increasing the room temperature hardeness on the Ni-rich side but it has no effect on the A1-rich side of stoichiometry. These observations are attributed to interstitial dissolution of boron in Ni-rich NiAl and to a lack of solubility and also due to an enrichment at grain boundaries on the A1-rich side. The similar effect is found in high temperature creep resistance of NiAl by boron addition. The high temperature creep resistance increases on the Ni-rich side but it does not affect the A1-rich side of off-stoiciometry.

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立方 TaN纳米粉的制备

类伟巍 , 沈龙海 , 刘丹 , 李雪飞 , 彭刚 , 崔启良 , 邹广田

无机材料学报 doi:10.3724/SP.J.1077.2007.00400

采用直流电弧法使金属钽和氮气直接反应制备出了TaN纳米粉.利用XRD、XPS、TEM等测试方法对所制备的TaN纳米粉进行了表征.结果表明: 所制备的纳米粉为单一的立方相TaN, 纳米颗粒的平均粒度为5~10nm.实验中还发现氮气的气压对制备纯立方相TaN具有关键性作用, 并讨论了立方相TaN的形成机理.

关键词: 立方相TaN , nanocrystallites , dc arc discharge method

立方TaN纳米粉的制备

类伟巍 , 沈龙海 , 刘丹 , 李雪飞 , 彭刚 , 崔启良 , 邹广田

无机材料学报 doi:10.3321/j.issn:1000-324X.2007.03.004

采用直流电弧法使金属钽和氮气直接反应制备出了TaN纳米粉.利用XRD、XPS、TEM等测试方法对所制备的TaN纳米粉进行了表征.结果表明:所制备的纳米粉为单一的立方相TaN,纳米颗粒的平均粒度为5~10nm.实验中还发现氮气的气压对制备纯立方相TaN具有关键性作用,并讨论了立方相TaN的形成机理.

关键词: 立方相TaN , 纳米粉 , 直流电弧法

Microstructural study on multilayer FeTaN/TaN (5) films

Materials Letters

The microstructure of [FeTaN/TaN](5) multilayer films has been investigated by transmission electron microscopy (TEM) and high-resolution electron microscopy (HREM) in cross section and plan view. Each layer shows a small surface roughening less than 1 nm. The FeTaN layers are composed of b.c.c. Fe with Ta incorporated substitutionally and N interstitially, denoted as Fe(Ta,N); while the TaN layers mainly consist of f.c.c. TaN phase. A [110] texture of Fe(Ta,N) has been formed in the FeTaN layers. The columnar grain structure is a typical feature in FeTaN layers. (C) 2003 Elsevier Science B.V. All rights reserved.

关键词: microstructure;thin films;magnetic materials;transmission electron;microscopy (TEM);sputtering;fetan thin-films;magnetic-properties;recording-heads;tantalum;nitride;temperature

Titanium technology in the USA - an overview

D.Eylon , S.R.Seagle

材料科学技术(英文)

The state of Ti research, development and industry is reviewed in this article. The fifty-year anniversary of Ti technology commercialization in the USA provides an opportunity for a historical perspective. Incorporation of "information-age" tools into alloy development, processing, and production invigorates the technology. Consolidation, diversification and globalization have been transforming the Ti industry in the recent years.

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High temperature naphthenic acid corrosion of steel in high TAN refining media

Anti-Corrosion Methods and Materials

Purpose - This paper aims to study the corrosion behavior of carbon steel and stainless steel in white oil with naphthenic acid under high temperature. Design/methodology/approach - The weight-loss method and surface analysis were used to study the corrosion behavior of steel in white oil with naphthenic acid. Findings - Naphthenic acids corrosion rates were directly related to experimental temperature, immersion time and total acid number (TAN). The activation energy was calculated and the process kinetics could be represented by Arrhenius-type equation. The relationship between the isothermal line in liquid phase and that in vapor phase at different TAN values had a significant distinction with the change of temperature. Originality/value - The findings have important implications for assessing the corrosivity of crude oils with high TAN value from various resources.

关键词: Corrosion;Stainless steel;Oils;Acids;refineries

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