TANG Zhengyou
,
DING Hua
,
DU Linxiu
,
DING Hao
,
ZHANG Xin
钢铁研究学报(英文版)
In order to control retained austenite, the effect of hot deformation in the intercritical region on the microstructure of hotrolled transformationinduced plasticity (TRIP) steel was studied on a Gleeble 1500 hot simulator. Compressive strains varying in amounts from 0 to 60% were imposed in the intercritical region, and effects on the formation of polygonal ferrite, carbidefree bainite and retained austenite were determined. With increasing the hot deformation amount and the ferrite content and decreasing the carbidefree bainite content, the volume fraction of retained austenite decreases. Increased dislocation density, grain refinement of ferrite and carbon enrichment are the main factors which control retained austenite stability.
关键词:
TRIP steel;intercritical (α+γ) region;hot deformation;retained austenite
DING Hao
,
DING Hua
,
QIU Chunlin
,
TANG Zhengyou
,
ZENG Jianmin
,
YANG Ping
钢铁研究学报(英文版)
The mechanical property and forming limit experiments were carried out on a high manganese TRIP/TWIP steels with 18.8% manganese. And the forming limit diagram was obtained. This high manganese steel shows outstanding mechanical properties combining high strength and good formability. Its FLD0 is about 38%. The effects of conventional mechanical property on the FLD0 were analyzed. With the contents of Mn increasing, FLD0 increases, which indicates TWIP effect is advantageous to enhance formability. Combining with three classical models and volume invariable principle, a FLD model was established, which fits high manganese steels very well.
关键词:
high manganese TRIP/TWIP steel;mechanical properties;formability;forming limit diagram
Acta Physica Sinica
Molecular dynamics (MD) simulation is performed to study the vacancy-interstitial annihilation in crystalline silicon. We choose the Stillinger-Weber potential, which is commonly used for silicon, to describe the interaction between atoms. The system is relaxed under 300K and 1400K respectively. We have found that < 111 > is the preferred recombination direction and propose the presence of an energy barrier in the < 110 > direction. From the calculated value of energy barrier along < 110 > we give a reasonable explanation for the difference between Tang's and Zawadzki's data.
关键词:
molecular dynamics;vacancy and interstitial;diffusion;point-defects;diffusion;mechanisms
中国腐蚀与防护学报
N。1Atmospheric Corrosivlty for Steels………………………………………………… .LIANG Caideng HO[I i。-tat（6）Caustic Stress Corrosion Cr。king of Alloy 800 Part 2.The Effect of Thiosul执e……………………………………… KONG De-sheng YANG Wu ZHAO Guo-zheng HUANG De.ltL。ZHANG Yu。。he CHEN She。g-bac（13）SERS slid E16CttOCh6iniC81 Stlldy Of Illhibit1Oli M6ch＆tllsth Of ThlollY68 Oil ITOll ID H....
关键词:
Nuclear Instruments & Methods in Physics Research Section B-Beam Interactions with Materials and Atoms
A static Monte Carlo simulation program has been used to study the influence of primary and secondary knock-on atoms on the angular distribution and the fractionation, for zero-fluence sputtering of Mo-92-Mo-100. At 10 keV Xe ion energy, calculations show that significant depth-dependent momentum asymmetry exists in the near-surface region, as in Refs. (L.P. Zheng, R.S. Li, M.Y.LI, Nucl. Instr, and Meth. B 100 (1995) 490; L.P. Zheng, M.Y. Li, Nucl. Instr. and Meth. B 114(1996) 28). The calculations also show that at the polar emission angle range between 0 degrees and 90 degrees the probabilities of the sputtered primary knock-on atoms for Mo-92 and Mo-100 are small (6.1% for Mo-92 and 6.6% for Mo-100), especially, between 0 degrees and 30 degrees they are very small (2.5% for Mo-92 and 2.8% for Mo-100). At 0.1 keV Ar ion energy, the calculations show that partial momentum flux ratios, for the primary and the secondary knock-on atoms, deviate far from one, through marker plane 1 (about an atomic layer distance from the surface). (C) 1998 Elsevier Science B.V. All rights reserved.
关键词:
mo-92-mo-100;targets
李红
,
孙克
,
李艳萍
,
石毅
,
郭金花
,
卢志超
金属功能材料
提出了采用推杆式热膨胀仪测试非晶合金薄带热膨胀特性的新方法.分析了Fe80Si9B11非晶薄带的热膨胀曲特性和非晶合金晶化过程.根据R.G.Zheng理论分析了结构弛豫中自由体积比变化,发现自由体积比曲线出现双峰.结合晶化前发生相分离的理论分析了这种变化的原因.分析表明:铁基非晶Fe80Si9B11晶化过程中先形成α-Fe(Si)相,再析出Fe3B、二次α-Fe(Si)相.晶化前先发生相分离,自由体积比增大,然后析出结晶相α-Fe(Si),自由体积比降低.随温度升高,B偏聚,自由体积比增大,随后析出Fe3B、二次α-Fe(Si)相,自由体积比降低.
关键词:
铁基非晶薄带
,
热膨胀系数
,
自由体积比
,
结构弛豫
陈修帅
,
侯传金
,
李晴
,
刘彦军
,
杨瑞丰
,
胡向平
催化学报
doi:10.1016/S1872-2067(16)62488-9
手性2,3-二氢呋喃衍生物是一类重要的杂环化合物,广泛存在于天然产物和生物活性分子中.它们也经常被用于手性四氢呋喃化合物的不对称合成.因此,人们发展了很多合成手性2,3-二氢呋喃化合物的方法,如有机小分子催化的多米诺迈克尔-烷基化反应、“中断的”Feist-Bénary反应或改进的 Feist-Bénary反应.此外,过渡金属催化的手性2,3-二氢呋喃的不对称合成在近些年引起了人们的极大关注. Ozawa等通过 Pd-催化2,3-二氢呋喃的动力拆分方法获得了手性2-芳基-2,3-二氢呋喃. Evans发展了一种 Sc-催化联烯硅和乙醛酸乙酯的[3+2]环加成反应合成手性2,3-二氢呋喃的方法.最近, Fu和 Tang等发展了 Cu催化烯酮和重氮化合物的[4+1]环加成反应合成手性2,3-二氢呋喃的方法.在 Nishibayashi和 van Maarseveen的开创性工作之后, Cu催化的不对称炔丙基转化反应取得了很大的进展.最近,我们发展了一类新的三齿手性 P,N,N-配体,在 Cu催化不对称炔丙基取代、脱羧炔丙基取代、[3+2]、[3+3]和[4+2]环加成反应中表现出优秀的对映和非对映选择性.其中,我们发现采用 Cu催化炔丙醇酯和β-酮酯的[3+2]环加成反应,能高对映选择性地获得手性2,3-二氢呋喃.我们设想,采用β-羰基膦酸酯代替β-酮酯,通过这种 Cu催化[3+2]环加成反应,将可以合成一类具有重要生物活性的手性膦酰化2,3-二氢呋喃化合物.基于这种设想,本文使用手性 P,N,N-配体,通过 Cu催化炔丙醇酯与β-羰基膦酸酯的不对称[3+2]环加成反应,以很好的收率和最高92% ee的对映选择性获得了一系列光学活性的膦酰化2,3-二氢呋喃化合物.我们以炔丙醇酯1a与β-羰基膦酸酯2a为标准底物,优化了反应条件,考察了配体、Cu盐、碱和反应温度等对反应收率和对映选择性的影响.我们确定了最佳的反应条件：以4b为配体,以 Cu(OTf)2为铜盐,以t-BuOK为碱,以 MeOH为溶剂,–20oC反应24 h.在此条件下,我们对β-羰基磷酸酯2的适用范围进行了考察.结果表明,各种苯基取代的β-羰膦磷酸酯均能得到很好的收率和对映选择性.苯环上取代基的空间效应对反应的对映选择性影响不大,但对反应收率影响较大,与相应3-取代或4-取代底物相比较,2-取代的底物获得的收率较低.苯环对位取代基的电子效应对反应的影响不大,给电子基或吸电子基的底物,均得到了较好的收率和对映选择性.杂环取代的底物同样适用于该反应,以90%的收率和89% ee的对映选择性获得了相应的[3+2]环加成产物.对于烷基底物,虽然反应的产率略低,但是得到了高达92% ee的产物.此外,我们对炔丙醇酯底物的适用范围也进行了考察.结果表明,该体系对于各种取代的炔丙醇酯底物均可以获得较高的收率和良好的对映选择性.总之,本文发展了一种铜催化炔丙醇酯与β-羰基膦酸酯的不对称[3+2]环加成反应的方法,成功合成了手性膦酰化2,3-二氢呋喃化合物.通过使用一个结构刚性的酮亚胺三齿 P,N,N-配体,以很好的收率和最高92% ee的对映选择性获得了一系列光学活性的膦酰化2,3-二氢呋喃化合物.
关键词:
铜
,
不对称合成
,
3+2环加成
,
β-羰基膦酸酯
,
膦酰化 2,3-二氢呋喃
