TAO Dongping LIU Chunpeng ** Dept.of Metallurgy
,
Kunming Institute of Technology
,
Kunming
,
650093
,
China+ To whom correspondence should be addressed
材料科学技术（英文）
The rate processes of oxidative dearsenication of niccolite ore in microwave oven and in conventional furnace were measured with thermogravimetric technique.The results show that the dearsenication rate of niccolite ore with microwave heating becomes faster than that with conventional heating. Under the conditions of an approximate linear heating and a definite air flow,the oxidative dearsenication process of niccolite ore is mainly controlled by interfacial chemical reaction.The ex- perimental data are in agreement with the kinetic model of linear heating as follows: In{[1-(1-α)~(1/3)]/T}= In (PAM)/(r_oρφE)(1-(RT)/E)-E/(RT) Thus the apparent activation energies of oxidative dearsenication of the niccolite ore containing differ- ent additions have been obtained from the model.
关键词:
kinetics
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null
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null
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null
杨金瑞
,
余尚先
,
顾江楠
高分子材料科学与工程
通过对resol(羟甲基酚化合物和低分子量羟甲基酚树脂)DEPT135图谱的分析讨论,得到一系列计算resol微细结构参数的经验公式.根据DEPT135图谱可判断是否发生缩聚反应,根据经验公式可计算酚单体各个活性点参与反应百分率或酚羟基导入率、不同类型缩聚所占百分率及低分子量羟甲基酚树脂的平均核体数.
关键词:
羟甲基酚化合物
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羟甲基酚树脂
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DEPT135
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结构参数
LIU Chunpeng XU Yousheng HUA Yixin Kunming Institute of Technology
,
Kunming
,
650093
,
China.
材料科学技术（英文）
In applying the microwave radiation to extractive me- tallurgy,it is essential first of all to find the extent of microwave energy absorbed by various minerals experi- mentally.In this paper,more than 25 kinds of common useful minerals have been individually irradiated by a 500 W,2450 MHz microwave source in an enclosed quartz crucible to ascertain their heating temperature in a definite time.In addition,the reduction and cbloridization tests were also carried out on the titanomagnetite concentrate and pentlandite with microwave heating,respectively. These experiments indicate potential applications of util- izing microwave energy in extractive metallurgy.
关键词:
microwave radiation
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null
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null
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null
刘文鹏
,
张庆礼
,
杨华军
,
周鹏宇
,
孙敦陆
,
高进云
,
谷长江
,
罗建乔
,
王迪
,
殷绍唐
量子电子学报
doi:10.3969/j.issn.1007-5461.2011.02.018
采用固相反应法制备了Bi3+、Eu3+、Tb3+掺杂的Lu3TaO7.测量了样品的X射线衍射谱、激发和发射光谱及荧光衰减曲线.三种离子掺杂的Lu3TaO7均呈现出强的荧光发射,其中Bi3+具有峰位在431 nm处的一强发射宽带,衰减寿命为16.8μs,Eu3+、Tb3+则表现出稀土离子的特征锐发射峰,衰减寿命分别为1.26 ms和1.20 ms.因此,它们均是具有潜在应用前景的重闪烁体材料.
关键词:
材料
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闪烁体
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Lu3TaO7
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发光
Z. T. Ma and D. Janke(Institute of Iron and Steel Technology
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Freiberg University of Mining and Technology
,
Germany)
金属学报(英文版)
Useder certain conditions, nonmctallic inclusions such as oxides, sulfides, nitrides and carbides are no longer harmful to sted service properties. With the new concept of oxide metallurgy, these properties can be improved by generating fine oxide inclusions which serve as heterogeneous nuclei for sulfide and fine ferrite[1-4]. A novel continuous casting (CC) process is expected to be created with the utilization of oxide metallurgy. This is also useful for the forthcoming technologies of direct rolling and near-net-shape casting. The main idea of oxide metallurgy consists of an alternative oxidation technology. It is based on steels treated by complex metals such as Ti, Zr, Ti-Zr alloys and rare earth metals. The selected deoxidants should follow the required conditions which are concluded in this paper.
关键词:
oxide
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null
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null
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null
Yong LIU
,
Lifang CHEN
,
Weifeng WEI
,
Huiping TANG
,
Bin LIU
材料科学技术（英文）
Ti-4.5Al-6.0Mo-1.5Fe, Ti-6Al-1Mo-1Fe and Ti-6Al-4V alloys were prepared by blended elemental powder metallurgy (PM) process, and the effects of Nd on the microstructures and mechanical properties were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). It was found out that the addition of Nd increased the density of sintered titanium alloys slightly by a maximum increment of 1% because small amount of liquid phase occurred during sintering. The addition of Nd shows little effect on the improvement of tensile strength, while the elongation is significantly improved. For example, the elongation of Ti-4.5Al-6.0Mo-1.5Fe can be increased from 1% without addition of Nd to 13% at a Nd content of 1.2 wt pct.
关键词:
Powder metallurgy titanium alloy
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null
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null
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null
A.A.A. Saleh
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Y. Fu
,
X.J. Zhai
金属学报(英文版)
Nano-ZnO particle was produced by evaporating zinc powders in air at air °ow-rate
from 0.2 to 0.6m3/h. Nano-ZnO particles was formed by the oxidation of the evapo-
rated zinc vapor. X-ray di®raction shows the powders to be ZnO with lattice parame-
ters of a=0.3249nm and c=0.5205nm. The particle size is dependent upon the transit
time from the source to the collection area. The size of particles was ranged between
81 to 103nm. The average density resulted was 4.865g/cm3.
Normal ZnO and nano-ZnO were investigated to use them in aluminum metallurgy as
an inert anode material. A certain amount of both oxides were molded subsequently
inserted to the molten cryolite-aluminum oxide to investigate the corrosive behavior
of both oxides. When the sintering temperature increased up to 1300±C, the weight
loss ratio rose to 5.01%{7.33% and up to 7.67%{10.18% for nano-ZnO and normal
ZnO, respectively. However, when the samples in the molten cryolite aluminum oxide
were put for long time, the corrosive rate was found to be higher. It was found that
the corrosive loss weight ratio of nano-ZnO anode was much lower than the normal
one made from ordinary-ZnO providing that the nano-ZnO is more possible to be use
inert anode material.
关键词:
reactive evaporation method
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null
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null
Liqing CHEN
,
Naoyuki Kanetake
材料科学技术（英文）
Ingot metallurgy (IM) aluminum has long been the subject and attracted the attention of many metallurgists and textural researchers of materials. Due to the introduction of large amounts of ex situ interfaces, however, the textures in powder metallurgy (PM) processed aluminum has been rarely reported. In this article, a pure aluminum plate was prepared $via$ PM route. The starting billet was first produced with uni-axially cold compaction and flat hot-extrusion and then followed by cold rolling processes. The hot-extruded and cold rolling deformation textures of the pure PM aluminum at 50%, 80% and 90% cold rolling reductions were studied by orientation distribution functions (ODFs) analysis. The finite element polycrystal model (FEPM) was finally utilized to simulate the cold rolling textural evolution at various stages of cold rolling. In FEPM simulation, the initial hot-extruded textures were taken into account as inputs. The results showed that typical β-fiber texture formed in pure PM aluminum with the cold rolling reduction increased till 80%, and there was not much change after excessive cold rolling deformation. Homogeneous slip is not the only deformation mode in PM processed pure aluminum plate at over 80% cold rolling reduction. The experimental results were qualitatively in good agreement with the simulated ones.
关键词:
Texture
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null
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null
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null
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null
D.G. Ren
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W.Z. Chen and X.S. Fan ( Laboratory of Atomic Imaging of Solids
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Institute of Metal Research
,
The Chinese Academy of Sciences
,
Shenyang 110015
,
China
,
College of Materials Science and Engineering
,
Fuzhou University
,
Fuzhou 350002
,
China)
金属学报(英文版)
The microstructures of TiAl intermetallic compounds prepared by ingot metallurgy and centrifugal spray deposition (CSD) were compared by field ion microscopy and atom probe (AP-FIM). The samples used have nearly stoichiometric composition of TiAl but there is Mn addition for ingot metallurgy (IM) samples and Mn and Nb additions for CSD samples. The field ion image of TiAl showed two regions of ordered f.c.t crystal structure (γ-TiAl) and disordered α-Ti3Al, and the distribution of Ti and Al atoms in TiAl alloy showed a lamellar structure which was confirmed by AP profiles. AP profiles showed that the major constituent of IM TiAl alloy is γ-TiAl with some Ti-rich regions. The compositions of these Ti-rich regions are nearly Ti3Al and Ti2Al from the calculation of AP data. The sample of CSD has a similar microstructure as compared with IM sample. The effects of alloying elements (Mn and Nb) on the ordering extent ,their distribution, and their sites occupied in the lattice were explored for both TiAl alloys. But there are no obvious Ti3Al or Ti2Al phases as shown in IM sample. In addition, the distributions of Mn and Nb concentrations in the CSD sample have a characteristic of wave form.
关键词:
intermetallic compound
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null
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null
