汪峰
,
Thomas M Devine
腐蚀学报（英文）
doi:10.11903/1002.6495.2015.018
利用原位表面增强型拉曼光谱(SERS)研究了Inconel 600合金和Inconel 690合金在高温高压水环境中生成的氧化膜特征.结果表明,Inconel 600合金氧化膜的内层为薄且连续的Cr2O3,外层为非连续分布的FeCr2O4/NiFe2O4晶粒.Inconel 690合金腐蚀氧化膜由单一连续的Cr2O3构成.从两个方面分析了本文SERS结果与他人研究成果之间的差异.一是合金在腐蚀的早期阶段形成Cr2O3内层,随着时间增加,转变成热力学稳定的富铬尖晶石;二是由不锈钢材料制成的高压釜和回路管道,溶液中含有大量的Fe2+和Ni2+,导致氧化膜中尖晶石相的生成.提出了合金氧化膜与腐蚀时间以及高压釜(含管道回路)材质都存在一定的关联性.
关键词:
Inconel 600合金
,
Inconel 690合金
,
氧化膜
,
模拟压水堆一回路
刘霞
,
张建军
,
陈铮
,
王永欣
稀有金属材料与工程
本文基于Thomas-Fermi(TF)模型,提出外势场与原子内势场的作用,确定外势场对体系势场边界条件的影响,建立了外电场作用下的原子势场外边界条件.应用体积相加法,把单原子TF模型推广到化合物和固溶体.并以Al,Mg,Li等元素的单原子,Al-Mg固溶体,Mg5Al8化合物为例,计算和分析了电场作用对体系的熵能的影响.结果表明:熵能在整个电场区域内呈先减小后增大的变化趋势,并且边界势下和极板电压下的整体变化趋势一致,但零点处熵能的变化趋势不同.
关键词:
Thomas-Fermi模型
,
静电场
,
铝镁合金
,
熵能
刘勤
,
周善佑
材料研究学报
超塑性m-δ关系曲线可以分为m_L=m_(max)和m_L=m_(min)两大类型。均可由下面的C.L.(刘勤)m-σ方程表示:σ(%)=〔cε~(m-m_0)-1〕×100当σ=σ_0=0时,m=m_0≠0,C=C_0=κ_0/κ_0=1。当σ=σ_1(σ_(11),σ_(12),σ_(13),…,)时,m=m_1(m_(11),m_(12),m_(13),…),C=C_1(C_(11),C_(12),C_(13),…)=κ_1(κ_(11),κ_(12),κ_(13),…)/κ_0,当σ=σ_F时,m=m_F,C=C_F=κ_F/κ_0。对C 值进行“规划”,得到的C_1~(σ_O-σ_L)-(m_L=m_(max)),C_2~(σ_F-σ_L)-(m_L=m_(min)),C_3~(m_0-m_L)-(m_L=m_(max)和C_4~(m_F-m_L)-(m_L=m_(min))四种类型的“规划”方程分别对m_L=m_(max)和m_L=m_(min)型m-σ曲线适用。若m-σ曲线属简单的下降式,C 及其“规划”值均可近似地取1。否则,C-σ关系是应加以研究的问题。m 和k 值对σ值的效应可以分为动态(直接)和静态(间接)两种。最后的σ值是两种效应的综合结果。(注:m 和κ值见基本方程σ=κε~m)
关键词:
齐召庆
,
汪宏涛
,
薛明
功能材料
doi:10.3969/j.issn.1001-9731.2016.02.010
采用改进的非接触式混凝土收缩测定仪及标靶,研究了m(M)/m(P)比值(MgO与KH2PO4的质量比)对磷酸镁水泥石自收缩行为的影响,运用八通道微量量热仪、压汞仪、X射线衍射仪、扫描电子显微镜及能谱仪等分析手段,分析了m(M)/m(P)比值对磷酸镁水泥石自收缩的作用机理.结果表明,磷酸镁水泥石的自收缩呈现出3个阶段的特征,即早期的迅速收缩阶段、微膨胀阶段、收缩缓慢发展阶段.随着m(M)/m(P)比值的增大,由于磷酸镁水泥石的水化放热量降低,水泥石内部孔隙率增大,水化产物结晶度降低,水泥石结构疏松,所以,自收缩率减小.
关键词:
磷酸镁水泥
,
自收缩
,
m(M)/m(P)比值
Tesshu Miyahara
材料科学技术（英文）
Magnetic stripe is one of the major applications of magnetic materials. As a key component of the present card technologies magnetic stripes play reliable components for electronic data interchange in worldwide electronic payment systems such as financial cards, transit tickets and phone cards, etc. Magnetic stripes are available in various coercivity materials, widths, lengths, structures and colors with each types of transferable, lamination and pressure sensitive magnetic tapes of Deuton-M. Manufacturing process, structure and characteristics of Deuton-M magnetic tape and sheet are described.
关键词:
卞进田
,
孙晓泉
,
聂劲松
量子电子学报
doi:10.3969/j.issn.1007-5461.2008.02.019
为了得到2.7 μm波段可调谐激光辐射,设计了信号光单谐振荡KTP光参量振荡器(OPO),给出了KTP OPO II(B)类相位匹配方式下的角度调谐曲线、有效非线性系数.KTP晶体切割角为θ=62°,ψ=0°,有效非线性系数为-2.97 pm/V.利用该KTP OPO实现了2.6～2.8 μm波段范围可调谐激光输出,用脉宽为16 ns的基模高斯光束1.064 μm激光泵浦得到了最大能量578 μJ,能量转换效率达1.7%.
关键词:
非线性光学
,
可调谐红外激光
,
单谐振光参量振荡器
,
KTP
,
角度调谐
,
相位匹配
Journal of Physics-Condensed Matter
We investigated the stable (0001) surfaces of M(2)AlC (M = Ti, V and Cr) using the first-principles plane-wave pseudopotential total energy method. Four possible (0001) terminations were considered by breaking the M-Al and M-C bonds. The corresponding surface energies were calculated and compared. The Al-and M(C)-terminated (0001) surfaces demonstrated better stability than the C- and M(Al)-terminated surfaces by their much lower surface energies. In addition, the stability of surfaces was predicted under various chemical environments as a function of chemical potentials. We further investigated the character of surface relaxations. The electronic structures of the stable Al- and M(C)-terminated surfaces were analyzed.
关键词:
ab-initio calculations;ti3sic2 thin-films;electronic-structure;elastic stiffness;al;deposition;cr2alc;simulation;adhesion;solids
