LIN Jialiu ZHU Shigen YU Zhenzong Tsinghua University
,
Beijing
,
China
金属学报(英文版)
The stress-strain relation for cast low alloy carbon steel at solidification temperature has been examined by the authors' own desingned apparatus for rheological properties measurement.The rheology model,the stress-strain constitutive equation and the rheological parameters therefrom of the cast steel were proposed.Thus the theoretical basis and calcula- ting data for computerized s#nulation on the stress-strain relation and thermal cracking of the cast steel were suggested.
关键词:
rheological behaviour
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null
,
null
,
null
,
null
JIANG Laizhu CUI Kun Huazhong University of Science and Technology
,
Wuhan
,
China
金属学报(英文版)
Studies were made of the calculation of fractal dimension of transverse impact fracture sur- face,and of the correlation between impact toughness of steel and parameters of free-cutting phase by means of the developed fractal geometry model of crack propagation.It is believed that the area fraction,f,of free-cutting phase is negligibly influential to the longitudinal im- pact toughness,as f1 .While the aspect ratio,saying ratio of length to width,of free-cut. ting phase is inversely influential to the transverse impact toughness.This may .be the reason why the transverse impact toughness of free-cutting steel containing more rare earth contrast to sulphur is even higher than the low sulphur containing steel.
关键词:
fractal geometry
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null
,
null
Liu Zhengyi Fu Jian Zhuang Yuzhi South China University of Technology
,
Guangzhou
,
China Correspondent:LIU Zhengyi professor
,
Dept.of Mechanical Engineering No.2
,
South China University of Technology
,
Guangzhou
,
China
金属学报(英文版)
The nature of“white layer”found in 55SiMnMo steel subjected to friction test has been stu- died using TEM,SEM,X-ray diffraction and EPMA techniques.It is shown that the struc- ture of the“white laver”on the rubbing surface is duplex,consisting of a special martensite and some austenite.This layer may be 25—50 μm thick.It is ultrafine,with grain diametric approximately 30 nm.Its micro-hardness may be as high as Hm 1500 and is capable of cut- ting glass.It has superb corrosion resistance and resists tempering.Its mierostructure and hardness undergo changes only when the steel is tempered above 500℃.
关键词:
friction
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null
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null
李小琳
,
王昭东
金属学报
doi:10.11900/0412.1961.2014.00582
采用热膨胀实验研究了等温温度对Nb-Ti微合金钢组织、性能及析出行为的影响规律,利用TEM对不同温度等温后试样的析出行为进行观察和分析.结果表明,不同温度等温后试样中均可观察到相间析出碳化物,且降低等温温度可显著细化相间析出碳化物所在面面间距、相间析出碳化物所在面内析出物间距及相间析出碳化物尺寸.具有层状分布特征的相间析出碳化物所在面呈现弯曲和平直2种形态,其中平直型相间析出碳化物所在面平行于铁素体的{011},{012},{013}和{035}面.经HRTEM确定相间析出碳化物具有NaC1型晶体结构,晶格常数为0.434 nm,且与铁素体基体符合Baker-Nut-ting(B-N)关系,经EDS分析确定相间析出碳化物为(Nb,Ti)C.利用Orowan机制对析出强化量进行估算,结果表明不同等温温度下析出强化量均大于300MPa.
关键词:
Nb-Ti微合金钢
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相间析出
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Vickers硬度
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高分辨透射电子显微术
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取向关系
,
错配度
中国腐蚀与防护学报
N。1Atmospheric Corrosivlty for Steels………………………………………………… .LIANG Caideng HO[I i。-tat（6）Caustic Stress Corrosion Cr。king of Alloy 800 Part 2.The Effect of Thiosul执e……………………………………… KONG De-sheng YANG Wu ZHAO Guo-zheng HUANG De.ltL。ZHANG Yu。。he CHEN She。g-bac（13）SERS slid E16CttOCh6iniC81 Stlldy Of Illhibit1Oli M6ch＆tllsth Of ThlollY68 Oil ITOll ID H....
关键词:
Europhysics Letters
Noncollinear magnetic investigations of the ground state in PrFeAsO have been performed by the density-functional theory. We calculated the total energy and made structure optimization, and the electronic density of states of PrFeAsO was analyzed. There are three different magnetic structures in PrFeAsO defined by experiments. Based on these magnetic structures, we studied four collinear and four noncollinear cases. The ground state is found to take the ordering proposed by Zhao, in which the FeAs plane is of stripe antiferromagnetism and Pr spins are perpendicular to Fe spins. The electronic density of states indicates that for PrFeAsO the increase of the electron Coulomb interaction leads to a decrease in conductivity. Copyright (C) EPLA, 2011
关键词:
high-temperature superconductivity;phase-diagram;oxypnictides;instability
刘建国
,
安振涛
,
张倩
,
杜仕国
,
姚凯
,
王金
材料导报
doi:10.11896/j.issn.1005-023X.2017.04.030
为评估氧化剂硝酸羟胺的热稳定性,使用标准液体铝皿于3 K/min、4 K/min、5 K/min加热速率下进行热分析.借助非等温DSC曲线的参数值,应用Kissinger法和Ozawa法求得热分解反应的表观活化能和指前因子,根据Zhang-Hu-Xie-Li公式、Hu-Yang-Liang-Xie公式、Hu-Zhao-Gao公式以及Zhao-Hu-Gao公式,计算硝酸羟胺的自加速分解温度和热爆炸临界温度,并对热分解机理函数进行了研究.设计了7条热分解反应路径,采用密度泛函理论B3LYP/6-311++G(d,p)方法对硝酸羟胺的热分解进行了动力学和热力学计算.计算结果表明,硝酸羟胺热分解的自加速分解温度TsADT=370.05 K,热爆炸临界温度Te0=388.68K,Tbp0=397.54 K,热分解最可几机理函数的微分形式为f(a) =17×(1-α)18/17.硝酸羟胺热分解各路径中,动力学优先支持路径Path 6、Path 5、Path 4和Path 1生成NO和NO2,其次是Path 2、Path 7和Path 3生成N2和N2O.温度在373 K以下时,Path 1'反应无法自发进行,硝酸羟胺无法进行自发的热分解.从热力学的角度来看,硝酸羟胺在370.05K以下储存是安全的.
关键词:
硝酸羟胺
,
热分析
,
热稳定性
,
热分解机理
,
密度泛函理论
