WANG Hui-tao
,
WANG Hua
,
ZHANG Zhu-ming
钢铁研究学报(英文版)
Low temperature exhaust gases carrying large amount of waste heat are released by steel-making process and many other industries, Organic Rankine Cycles (ORCs) are proven to be the most promising technology to recover the low-temperature waste heat, thereby to get more financial benefits for these industries. The exergy analysis of ORC units driven by low-temperature exhaust gas waste heat and charged with dry and isentropic fluid was performed, and an intuitive approach with simple impressions was developed to calculate the performances of the ORC unit. Parameter optimization was conducted with turbine inlet temperature simplified as the variable and exergy efficiency or power output as the objective function by means of Penalty Function and Golden Section Searching algorithm based on the formulation of the optimization problem. The power generated by the optimized ORC unit can be nearly as twice as that generated by a non-optimized ORC unit. In addition, cycle parametric analysis was performed to examine the effects of thermodynamic parameters on the cycle performances such as thermal efficiency and exergy efficiency. It is proven that performance of ORC unit is mainly affected by the thermodynamic property of working fluid, the waste heat temperature, the pinch point temperature of the evaporator, the specific heat capacity of the heat carrier and the turbine inlet temperature under a given environment temperature.
关键词:
waste heat recovery
,
organic Rankine cycle
,
optimization
,
working fluid
,
exergy
,
pinch point
刘文鹏
,
张庆礼
,
杨华军
,
周鹏宇
,
孙敦陆
,
高进云
,
谷长江
,
罗建乔
,
王迪
,
殷绍唐
量子电子学报
doi:10.3969/j.issn.1007-5461.2011.02.018
采用固相反应法制备了Bi3+、Eu3+、Tb3+掺杂的Lu3TaO7.测量了样品的X射线衍射谱、激发和发射光谱及荧光衰减曲线.三种离子掺杂的Lu3TaO7均呈现出强的荧光发射,其中Bi3+具有峰位在431 nm处的一强发射宽带,衰减寿命为16.8μs,Eu3+、Tb3+则表现出稀土离子的特征锐发射峰,衰减寿命分别为1.26 ms和1.20 ms.因此,它们均是具有潜在应用前景的重闪烁体材料.
关键词:
材料
,
闪烁体
,
Lu3TaO7
,
发光
Acta Materialia
A graded microstructure was produced in the surface layer of a pure Cu sample by means of surface mechanical attrition treatment (SMAT) [Wang K, Tao NR, Liu G, Lu J, Lu K. Acta Mater 2006;54:5281.]. The diffusion behavior of (63)Ni in such a surface layer was investigated by the radiotracer technique at temperatures <438 K. It is shown that the effective diffusivity in the top 10 mu m surface layer is more than 2 orders of magnitude higher than that along conventional high-angle grain boundaries (HAGB) in Cu of similar purity. The diffusion rate increases gradually with increasing depth up to 30-50 mu m, and then decreases with further increasing depth. The enhanced diffusivities reveal higher-energy states of various interfaces in the SMAT surface layer. The excess free energy of HAGB in this layer is estimated to be similar to 30% higher than that of conventional grain boundaries. An apparent retardation of the effective diffusion rate in the top 25 mu m surface layer is induced by tracer leakage into numerous twin-boundary-like interfaces, while the gradual decrease in interface excess free energy correlates with the observed decrease in diffusivity in the subsurface layer at depths exceeding 50 mu m. (C) 2009 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
关键词:
Nanostructured material;Surface mechanical attrition treatment;Diffusion;Grain boundaries;Twin boundaries;grain-boundary diffusion;mechanical attrition treatment;severe;plastic-deformation;nanocrystalline copper;self-diffusion;nickel;alloys;bulk;temperatures;segregation
季振国
,
周荣福
,
毛启楠
,
霍丽娟
,
曹虹
无机材料学报
doi:10.3724/SP.J.1077.2009.09217
利用反应磁控溅射法制备了半导体锡锑氧化物薄膜 (TAO). 根据霍尔效应测试结果,当Sn/Sb 原子比处于0.22~0.33范围内时,TAO薄膜是p型导电的,在此范围之外,TAO薄膜是n型导电的. 光学带隙测量结果表明,不同Sn/Sb比的TAO薄膜的禁带宽度基本相同(~3.9eV).构造了一个全透明的PN结,其中n区为Sn/Sb原子比为0.5的TAO薄膜, p区为Sn/Sb原子比为0.33的TAO薄膜.n区TAO的电极用铟锡氧化物(ITO),p区TAO的电极用Cu薄膜.实验结果表明,由于两种导电类型的TAO薄膜具有相同的禁带宽度,上述透明PN结构具有典型的准同质PN结的整流特性.
关键词:
透明半导体薄膜
,
锡锑氧化物
,
PN结
Journal of Materials Research
The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.
关键词:
room-temperature
周萧明
,
胡更开
复合材料学报
doi:10.3321/j.issn:1000-3851.2004.06.026
提出了预测复合材料非线性电位移和电场强度关系的一种解析方法,该方法基于各向材料的割线介电常数,将非线性问题转化成一系列线性问题来求解.该方法适用于任意各向异性复合材料和组分材料的非线性性质,而常用的Stroud和Hui的模型只适用于各向同性复合材料和组分材料的弱线性.证明了本文方法具有Ponte Castaneda提出的变分结构.计算结果表明,当基体非线性较小时,本文模型的预测与Stroud和Hui的模型一致,但当基体非线性系数增大时,本文模型能给出合理的预测结果,而Stroud和Hui的模型则会超出基体和夹杂的性能范围.
关键词:
复合材料
,
介电常数
,
非线性
,
割线方法
材料科学技术(英文)
The effect of interstitial hydrogen on the cohesion of the Al Sigma=11(113) grain boundary (GB) is investigated based on the thermodynamic model of Rice-Wang using the first-principles density function calculation. The results indicate that interstitial H behaves as an embrittler from "strengthening energy" analysis. The reduced GB cohesion due to the presence of H at the GB is attributed to the low affinity between H and Al, and the weakened bonding of Al atomic pairs perpendicular to GB plane.
关键词:
hydrogen;grain boundary;Al-Mg alloys;pseudopotentials;1st-principles