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FRACTURE BEHAVIOUR AND FRACTURE TOUGHNESS OF Al-2.5Li-1.3Cu-0.9Mg-0.13Zr ALLOY

WU Yilei QIANG Jun WANG Shuncai LI Yongwei GUO Bichao LIU Bocao Institute of Aeronautical Materials , Beijing Engineer , Institute of Aeronautical Materials , Beijing 100095 , China

金属学报(英文版)

The fracture mechanism for Al-2.5Li-1.3Cu-0.9Mg-0.13Zr alloy is quite different from undergone various regimes of heat treatment.With the decrease of solution temperature and the increase of aging temperature,the intergranular delamination and necking fracture on the fracture surface increase and the shearing facture decreases.Thus,the toughness of the alloy may be much improved.

关键词: Al-Li alloy , null , null , null

Image analysis of periodic rain accelerated corrosion of aeronautical aluminium alloys

Materials Science and Engineering a-Structural Materials Properties Microstructure and Processing

Periodic rain tests have been carried out for simulating atmospheric corrosion of aeronautical aluminium alloys. A digital image preprocessing and analysis method based on wavelet transformation was used to study the corrosion morphology of aluminium alloys samples, through which an image feature parameter 8 was extracted and discussed. The influences of orthogonal experiment parameters on acceleration were analyzed according to image feature parameter 6 with analysis of variance (ANOVA) method, and the optimal parameters for accelerated corrosion test were also obtained. The result was shown to be consistent with that from weight loss method. (c) 2007 Elsevier B.V. All rights reserved.

关键词: aeronautical aluminium alloys;accelerated corrosion;linage analysis;simulated environment;atmospheric corrosion;electrochemical impedance;pitting corrosion;exposure;steel;zinc

Improved hydrogen storage performance of Li-Mg-N-H materials by optimizing composition and adding single-walled carbon nanotubes

International Journal of Hydrogen Energy

A systematic investigation on the hydrogen storage properties of Li-Mg-N-H materials with various compositions was performed. Li-Mg-N-H hydrogen storage materials were prepared by mechanically milling LiNH2/MgH2 mixtures with initial molar ratios ranging from 1.5:1 to 3: 1, followed by de/rehydriding at 200 degrees C. It was found that the hydrogen storage capacity of the system was highly dependent on the initial phase ratio of the LiNH2/MgH2 mixture. An optimum hydrogen capacity of about 5 wt% was achieved in the 2.15:1 LiNH2/MgH2 mixture. Different carbon materials, such as the single-walled carbon nanotubes (SWNTs), multi-walled carbon nanotubes, graphite and activated carbon, were used as additive to improve the hydrogen storage performance. It was found that the dehydriding kinetics of the Li-Mg-N-H material could be markedly improved by adding a small amount of SWNTs, especially in the as-prepared state. (c) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

关键词: hydrogen storage;dehydriding kinetics;carbon nanotubes;arc-discharge method;system;microstructure;desorption;absorption;behaviors;property;imides

小角度直线反走样的改进Wu算法

李铂 , 周建江 , 夏伟杰 , 吴连慧

液晶与显示 doi:10.3788/YJYXS20142904.0605

直线是机载座舱显示画面中最基本的图元,其显示质量对于整个画面的显示效果影响较大,尤其是小角度下直线显示的“麻花”现象一直是影响显示效果的关键问题之一.为了提高小角度下直线的显示效果,本文提出了一种基于Wu算法的亮度渐变改进算法.该算法通过渐进地展现直线从轴方向上的亮度变化过程,减少亮度畸变,有效地改进了显示效果.通过Matlab仿真和FPGA实现,验证了该算法反走样后的小角度直线显示效果明显优于其他算法,而且结合中点画线法后,绘制时间与Wu算法相当.同时该算法还可改善大角度直线和圆弧的显示效果,消除了大角度直线的边缘锯齿,解决了圆弧在小角度部分的虚化问题.因此本文算法可用于对实时性和显示效果要求高的机载座舱显示系统,以缓解飞行员的视觉疲劳.

关键词: 座舱显示 , 反走样 , 改进Wu算法 , 小角度 , FPGA实现

First-principles study on influence of alloying element substitution on dehydrogenation ability of Li(4) BN(3) H(10) hydrogen storage materials

Acta Physica Sinica

A first-principles plane-wave pseudopotential method based on the density functional theory is used to investigate the dehydrogenation properties and the influence mechanism of Li(4)BN(3)H(10) hydrogen storage materials. The binding energy, the density of states and the Mulliken overlap population are calculated. The results show that the binding energy of crystal has no direct correlation with the dehydrogenation ability of (LiM)(4)BN(3)H(10)(M = Ni, Ti, Al, Mg). The width of band gap and the energy level of impurity are key factors to affect the dehydrogenation properties of (LiM)(4)BN(3)H(10) hydrogen storage materials: the wider the energy gap is, the more strongly the electron is bound to the bond, the more difficulty the bond breaks, and the higher wile the dehydrogenation temperature be. Alloying introduces the impurity energy level in band gap, which leads the Fermi level to enter into the conduction band and the bond to be weakened, thereby resulting in the improvement of the dehydrogenation properties of Li(4)BN(3)H(10). It is found from the charge population analysis that the bond strengths of N-H and B-H are weakened by alloying, which improves the dehydrogenation properties of Li(4)BN(3)H(10).

关键词: hydrogen storage materials;first-principles calculation;element;substitution;dehydrogenation;linh2

Nanosized Li(4)Ti(5)O(12)/graphene hybrid materials with low polarization for high rate lithium ion batteries

Journal of Power Sources

We report a simple strategy to prepare a hybrid of lithium titanate (Li(4)Ti(5)O(12), LTO) nanoparticles well-dispersed on electrical conductive graphene nanosheets as an anode material for high rate lithium ion batteries. Lithium ion transport is facilitated by making pure phase Li(4)Ti(5)O(12) particles in a nanosize to shorten the ion transport path. Electron transport is improved by forming a conductive graphene network throughout the insulating Li(4)Ti(5)O(12) nanoparticles. The charge transfer resistance at the particle/electrolyte interface is reduced from 53.9 Omega to 36.2 Omega and the peak currents measured by a cyclic voltammogram are increased at each scan rate. The difference between charge and discharge plateau potentials becomes much smaller at all discharge rates because of lowered polarization. With 5 wt.% graphene, the hybrid materials deliver a specific capacity of 122 mAh g(-1) even at a very high charge/discharge rate of 30C and exhibit an excellent cycling performance, with the first discharge capacity of 132.2 mAh g(-1) and less than 6% discharge capacity loss over 300 cycles at 20C. The outstanding electrochemical performance and acceptable initial columbic efficiency of the nano-Li(4)Ti(5)O(12)/graphene hybrid with 5 wt.% graphene make it a promising anode material for high rate lithium ion batteries. (C) 2011 Elsevier B.V. All rights reserved.

关键词: Lithium titanate;Graphene;High rate anode materials;Lithium-ion;batteries;anode material;electrochemical performance;nanocrystalline li4ti5o12;reversible capacity;cyclic performance;spinel li4ti5o12;rate;capability;graphene;composite;insertion

Two-step magnetization in a spin-chain system on the triangular lattice: Wang-Landau simulation

Physical Review B

The Wang-Landau algorithm is used to study the thermodynamic and magnetic properties of triangular spin-chain system based on two-dimensional Ising model in order to understand the magnetic-order dynamics in Ca(3)Co(2)O(6) compound. The calculated results demonstrate that the equilibrium state of the rigid spins produces the two-step magnetization curve at low temperature even when the random-exchange term is considered. This work indicates that the four-step magnetization behavior observed experimentally must be due to the nonequilibrium magnetization.

关键词: calcium compounds;exchange interactions (electron);Ising model;magnetisation;thermodynamics;one-dimensional ca3co2o6;density-of-states;compound ca3co2o6;phase-diagram;proteins;crystal

基于Wu反走样的三角形光栅化边缘反走样算法

吴连慧 , 周建江 , 夏伟杰 , 陈雅雯

液晶与显示 doi:10.3788/YJYXS20153001.0163

对于光栅化的三角形,其边缘存在明显的锯齿现象,因此需要进行反走样处理.基于Wu直线反走样算法的思想,考虑了水平直线外侧直接添加插值点的算法和三角形三边外侧反走样的算法.综合两者的优点,在绘制光栅化的三角形的同时,边缘叠加Wu反走样直线,并考虑背景像素灰度值的作用.结果表明,改进的三角形光栅化的边缘反走样算法有效提高了三角形光栅化后边缘的显示效果,该算法计算量小,便于FPGA实现,可用于对图形显示质量要求很高的机载显示系统.

关键词: 反走样 , Wu算法 , 光栅化 , FPGA

Effects of the nanostructured SiO2 coating on the performance of LiNi0.5Mn1.5O4 cathode materials for high-voltage Li-ion batteries

Electrochimica Acta

LiNi0.5Mn1.5O4 spinels coated with various amounts of fumed silica have been synthesized and investigated as cathode materials for high-voltage lithium-ion batteries at the elevated temperature (55 degrees C). The morphology and structure of the coated LiNi0.5Mn1.5O4 samples were characterized by XRD, TEM and EDX. It was found that the surfaces of the coated LiNi0.5Mn1.5O4 samples are covered with a porous, amorphous, nanostructured SiO2 layer. The results of electrochemical experiments showed that the SiO2-coated LiNi0.5Mn1.5O4 samples display obviously improved capacity retention rate, and the improvement effect enhances with the increase of SiO2 content. The XPS results revealed that the surfaces of the SiO2-coated LiNi0.5W1.5O4 cathode materials have relatively low content of LiF, and this is mainly responsible for their improved electrochemical cycling stability. (c) 2007 Elsevier Ltd. All rights reserved.

关键词: LiNi0.5Mn1.5O4 spinel;surface modification;fumed silica;LiF;XPS;licrymn2-yo4 0-less-than-or-equal-to-y-less-than-or-equal-to-1;composite electrolytes;interfacial stability;elevated-temperatures;lithium batteries;surface-films;fumed silica;xps analysis;spinel;cells

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