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Effect of Niobium and Titanium on Dynamic Recrystallization Behavior of Low Carbon Steels

MA Liqiang , LIU Zhenyu , JIAO Sihai , YUAN Xiangqian , WU Di

钢铁研究学报(英文版)

Using a Gleeble 3800 thermomechanical simulator, the effect of niobium and titanium on the dynamic recrystallization (DRX) behavior of low carbon steels was investigated. Isothermal single compression tests were performed in the temperature range of 850 to 1 150 ℃ at constant strain rates of 01 to 5 s-1. The experimental results showed that the addition of niobium and titanium to the low carbon steels significantly increased both the peak stress and steady state stress. The activation energy of deformation Qd was larger than the activation energy associated with the steady state stress Qss. Furthermore, the difference between Qd and Qss became significant because of the addition of niobium and titanium. DRX is effectively retarded because of solute dragging and dynamic precipitate pinning of niobium and titanium, resulting in higher values of the peak strain and steady state strain. Finally, the influence of niobium and titanium on the DRX kinetics and steady state grain size was determined.

关键词: peak strain;activation energy;dynamic recrystallization It is known that the experimental

Modeling of StrainInduced Precipitation Kinetics and Evolution of Austenite Grains in Nb Microalloyed Steels

ZHOU Xiaoguang , LIU Zhenyu , YUAN Xiangqian , WU Di , WANG Guodong , LIU Xianghua

钢铁研究学报(英文版)

Considering the effect of strain and chemical composition on precipitation behavior, new models for the start and end time of Nb(C,N) precipitation in austenite under the conditions of different temperatures and strains have been investigated for Nb microalloyed steel. The value of n in the precipitation kinetic equation has been determined by using the available experimental data in literature, which indicated that n is a constant and independent of temperature. The values of the start and end time of the predicted precipitation are compared with the experimental values. Calculated results are in good agreement with the experimental results. Also, the evolution of austenite grains before ferrite transformation is simulated by taking the effect of precipitation into consideration. The measured austenite grain size is in good agreement with predicted one prior to ferrite transformation.

关键词: straininduced precipitation;start time;precipitation;static recrystallization;grain size

Mathematical Model of RH Blow Argon Mode Affecting:Decarburization Rate in Ultra-Low Carbon Steel Refining

LI Chong-wei , CHENG Guo-guang , WANG Xin-hua , ZHU Guo-sen , CUI Ai-min

钢铁研究学报(英文版)

A mathematical model in present study has been established to investigate the effect of Rheinstahl Heraeus (RH) blow argon mode on the decarburization rate in ultra-low carbon steel refining based on the RH equipment of Shougang Qian′an Iron and Steel Co Ltd (SQISCO). The calculated results show that the increase of argon flowrate promotes the carbon elimination from argon gas bubble surface, molten steel free surface in vacuum as well as splash droplet surface, while reduces that from the interior of liquid steel. It has been found the critical turning point of flowrate ascension is at the 5th minute and the optimum blow argon flowrate in later stage is 2100 L/min in accordance with the 2 stages argon blow mode, which have been confirmed in the commercial production in SQISCO.

关键词: RH , vacuum , mathematical model , argon flowrate , decarburization

Intensified alkaline leaching pretreatment of refractory gold concentrates at common temperature and pressure

Transactions of Nonferrous Metals Society of China

A new process for the hydrometallurgy of refractory gold concentrates was presented. The process comprises grinding-leaching, intensified alkaline leaching (IAL), cyanidation and adsorption. In a stirring-type pulverizing-leaching tower mill, the concentrate is ground to <35. 6 μm of 95. 5 % while simultaneously leached by NaOH of 12 kg/t, then carried out intensified alkaline leaching for 48 h by NaOH of 108 kg/t in enhanced agitation tanks with the pulp concentration of 40% solids at the environmental temperature of 9. 5 &SIM; 13. 5 &DEG;C and the environmental pressure of 10(5) Pa. The oxidation rate of As is 94. 9%, and 47. 6% for S. The total consumption of NaOH is only 20% of that theoretically calculated under the conditions of full oxidation at the same oxidation rates of arsenic to arsenate and sulfur to sulfate. The gold leaching rate by NaCN in 24 h is increased from 9. 2% before pretreatment to 94. 2%. The consumption of NaCN is 7. 5 kg/t, which is one times less than that before pretreatment. The extraction cost of gold is about 422 Yuan/t.

关键词: refractory gold concentrates;grinding-leaching;intensified alkaline;leaching (IAL);pretreatment;common temperature and pressure

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