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THERMODYNAMIC TREATMENT OF MULTICOMPONENT SYSTEMS USING INTERACTION PARAMETERS

Z. T. Ma , J Ohser and D. Janke(Institute of Iron and Steel Technology , Freiberg University of Mining and Technology , Germany )

金属学报(英文版)

The partial thermodynamic functions of solvent and solutes in multicomponent systems have been expressed in terms of the interaction parameters. The corresponding analytical expressions of the activity coefficients of solvent and solutes enable to de scribe the thermodynamic properties of multicomponent systems. The advantages of this treatment are found in its thermodynamic consistency and a rather small influ ence of the higher order interaction parameters on the properties of the systetms.

关键词: thermodynamics; activity; model

T型接头蒙皮厚度对Z-pin增强效果的影响

李梦佳 , 陈普会 , 孔斌 , 彭涛 , 姚正兰 , 邱学仕

复合材料学报 doi:10.13801/j.cnki.fhclxb.20150930.002

在关于拉脱载荷下Z-pin增强T型接头的有限元模拟方法基础上,通过对2组蒙皮厚度分别为7.2 mm和4.0 mm的试验件的试验结果进行分析,研究了T型接头蒙皮厚度对 Z-pin增强效果的影响。结果表明:Z-pin增强效果随着蒙皮厚度的减小而增大。蒙皮厚度大于5 mm,Z-pin不能提高结构的最大承载能力,但可显著提高结构首次掉载后的承载性能,使T型接头在较大的加载位移下仍保持较高的承载能力;无论蒙皮厚薄,结构首次掉载后,各Z-pin增强T型接头可达到的载荷平台是相当的,且该载荷平台随蒙皮的变厚有降低的趋势。

关键词: 复合材料 , T型接头 , Z-pin , 蒙皮厚度 , 有限元模拟

Z-pin参数对复合材料T型接头拉脱承载能力的影响

李梦佳 , 陈普会 , 孔斌 , 彭涛 , 姚正兰 , 邱学仕

复合材料学报 doi:10.13801/j.cnki.fhclxb.201502.002

利用二维平面应变模型对Z-pin增强T型接头试样进行失效分析,采用内聚力模型模拟界面的破坏情况,通过在分层的上下界面加入非线性弹簧元模拟Z-pin的增强作用,非线性弹簧元的力学性能(桥联律)由细观力学方法获得,数值结果与试验值吻合较好.在已验证有限元方法的基础上,研究了Z-pin直径、密度及植入角度等对T型接头拉脱承载能力的影响.结果表明:Z-pin增强可显著提高T型接头的拉脱承载能力,与未Z-pin增强的T型接头相比,Z-pin增强明显延缓了掉载;T型接头的拉脱承载能力随Z-pin直径和密度的增加而增大,随植入角度的增大而减小;在所研究的角度范围内,当植入角度为60°时,T型接头的拉脱承载能力最好;Z-pin直径和密度对拉脱承载能力的影响远比植入角度的影响显著.

关键词: 复合材料 , T型接头 , Z-pin , 非线性弹簧 , 桥联律

z-pin增强复合材料T型接头层间性能的建模与分析

李成虎 , 燕瑛

复合材料学报

提出了基于z-pin桥联力试验的z-pin增强复合材料T型接头层间性能的模拟方法.每根z-pin的作用有两部分:增加了分层的张开阻力与剪切阻力.在有限元模拟中通过在相应的节点上加两个方向(竖直方向和水平方向)的非线性弹簧模拟张开阻力和剪切阻力.通过张开型z-pin桥联力试验和剪切型z-pin桥联力试验得到两条力-位移曲线,再把曲线各自赋予到所有竖直非线性弹簧和水平非线性弹簧,从而模拟z-pin对复合材料T型接头层间性能的增强效果.在T型接头拉拔试验模拟分析中,研究了不同跨距和不同z-pin间距对拉拔力的影响.模拟分析表明跨距对拉脱位移影响较大,z-pin间距对最大拉拔力影响较大.

关键词: z-pin , 复合材料 , z-pin桥联力 , 张开型 , 剪切型 , 非线性弹簧

快速凝固Al-Li-Cu-Mg-Zr合金中Z相和T相的结构关系

张立春 , 何安强 , 吴玉琨 , 叶恒强 , 张永昌

金属学报

利用高分辨电镜(HRTEM)和常规电子显微术研究了快速凝固Al-Li-Cu—Mg—Zr合金中Z相和T相的结构关系,发现两相间两种确定的晶体学取向关系,并以此为依据解释了Z相和T相的某些结构缺陷两相的结构有密切关联,其中一相中缺陷的扩展会导致另一相的形成

关键词: Al-Li-Cu-Mg-Zr合金 , Z hexagonal phase , T f.c.c. phase , shear structure

Phase transformation and magnetostriction of (R-PR)(Fe-T)(2) (R=Dy, Tb; T=Co, Ni)

材料科学技术(英文)

Structure and magnetostriction of Dy1-xPrxFe2 (0 less than or equal to x less than or equal to 0.5), Dy0.6Pr0.4(Fe1-yTy)(2) (0 less than or equal to y less than or equal to 0.6), and Tb1-zPrz(Fe0.4Co0.6)(2) (0 less than or equal to z less than or equal to 1.0) alloys (T=Co, Ni) have been investigated. It is found that the matrix of the alloys Dy1-xPrxFe2 is a single phase (Dy, Pr)Fe-2 with MgCu2-type structure and the second phase is (Dy, Pr)Fe-3 when x less than or equal to 0.2. The amount of (Dy, Pr)Fe-3 phase increases with increasing Pr content and becomes the main phase when x=0.4. The matrix of Dy1-xPrxFe2 is found to be the (Dy, Pr)(2)Fe-17 phase with Th2Zn17-type structure when x=0.5. It is found that the amount of the cubic Laves phase (Dy, Pr)(Fe, Co)(2) in the Dy0.6Pr0.4(Fe1-yCoy)(2) increases with increasing Co concentration when 0 less than or equal to y less than or equal to 0.6. The substitution of Ni for Fe is nearly not favorable for the formation of the cubic Laves phase (Dy, Pr)(Fe, Ni)(2) in (Dy1-xPrx)Fe-2. The matrix of (Tb1-zPrz)(Fe0.4Co0.6)(2) is a (Tb, Pr)(Fe, Co)(2) phase with the MgCu2-type cubic Laves structure and a second phase of small amount is (Tb, Pr)(Fe, Co)(3) phase when z less than or equal to 0.2, z=0.5 and 1.0. When 0.2<z less than or equal to 0.4, the amount of the (Tb, Pr)(Fe, Co)(3) phase with PuNi3-type structure increases with increasing z and becomes the main phase when z=0.4. When 0.5<z less than or equal to 0.6 the amount of the (Tb, Pr)(Fe, Co)(3) phase increases sharply, whereas for 0.6<z less than or equal to 0.8 it decreases with increasing z. The polycrystalline magnetostriction, lambda(parallel to) - lambda(perpendicular to), at room temperature of Dy1-xPrxFe2 exhibits a peak when x=0.3. The lambda(parallel to) - lambda(perpendicular to) for Dy0.6Pr0.4(Fe1-yMy)(2) (M=Co, Ni) and Tb1-zPrz (Fe0.4Co0.6)(2) is also examined.

关键词:

Phase transformation and magnetostriction of (R-PR)(Fe-T)(2) (R=Dy, Tb, T=Co, Ni)

Zhijun GUO , Zhidong ZHANG , Xinguo ZHAO , Bowen WANG , Dianyu GENG

材料科学技术(英文)

Structure and magnetostriction of Dy1-xPrxFe2 (0 less than or equal to x less than or equal to 0.5), Dy0.6Pr0.4(Fe1-yTy)(2) (0 less than or equal to y less than or equal to 0.6), and Tb1-zPrz(Fe0.4Co0.6)(2) (0 less than or equal to z less than or equal to 1.0) alloys (T=Co, Ni) have been investigated. It is found that the matrix of the alloys Dy1-xPrxFe2 is a single phase (Dy, Pr)Fe-2 with MgCu2-type structure and the second phase is (Dy, Pr)Fe-3 when x less than or equal to 0.2. The amount of (Dy, Pr)Fe-3 phase increases with increasing Pr content and becomes the main phase when x=0.4. The matrix of Dy1-xPrxFe2 is found to be the (Dy, Pr)(2)Fe-17 phase with Th2Zn17-type structure when x=0.5. It is found that the amount of the cubic Laves phase (Dy, Pr)(Fe, Co)(2) in the Dy0.6Pr0.4(Fe1-yCoy)(2) increases with increasing Co concentration when 0 less than or equal to y less than or equal to 0.6. The substitution of Ni for Fe is nearly not favorable for the formation of the cubic Laves phase (Dy, Pr)(Fe, Ni)(2) in (Dy1-xPrx)Fe-2. The matrix of (Tb1-zPrz)(Fe0.4Co0.6)(2) is a (Tb, Pr)(Fe, Co)(2) phase with the MgCu2-type cubic Laves structure and a second phase of small amount is (Tb, Pr)(Fe, Co)(3) phase when z less than or equal to 0.2, z=0.5 and 1.0. When 0.2<z less than or equal to 0.4, the amount of the (Tb, Pr)(Fe, Co)(3) phase with PuNi3-type structure increases with increasing z and becomes the main phase when z=0.4. When 0.5<z less than or equal to 0.6 the amount of the (Tb, Pr)(Fe, Co)(3) phase increases sharply, whereas for 0.6<z less than or equal to 0.8 it decreases with increasing z. The polycrystalline magnetostriction, lambda(parallel to) - lambda(perpendicular to), at room temperature of Dy1-xPrxFe2 exhibits a peak when x=0.3. The lambda(parallel to) - lambda(perpendicular to) for Dy0.6Pr0.4(Fe1-yMy)(2) (M=Co, Ni) and Tb1-zPrz (Fe0.4Co0.6)(2) is also examined.

关键词:

尼龙1212/SEBS-g-MA/DIDP/BSBA共混体系的结晶行为

赵清香 , 王玉东 , 刘民英 , 董静 , 申小清

高分子材料科学与工程

用WAXD、PLM及DSC研究了尼龙1212/SEBS-g-MA/DIDP/BSBA共混体系的结晶行为.WAXD结果显示,增韧剂的加入改变了尼龙1212的晶型.PLM观察表明共混体系中由于MA与尼龙之间的相互作用,增韧剂充当了成核剂,使得尼龙1212球晶向细晶化发展.用修正Avrami方程的Jeziorny法研究共混体系的非等温结晶动力学,发现共混体系的半结晶时间t1/2缩短,增韧剂对尼龙1212有明显的异相成核作用.

关键词: 尼龙1212 , 共混体系 , 结晶行为

钢包渣线用超低碳MgO-MA-C砖的研制与应用

薛军柱

耐火材料 doi:10.3969/j.issn.1001-1935.2011.02.008

以高纯电熔镁砂、镁铝尖晶石微粉和纳米炭素为主要原料,分别加入总量为4%(质量分数)的硅粉、铝粉和硅粉-铝粉复合粉为防氧化剂,加入清洁的自来水混练均匀后,在500 t 摩擦压砖机上成型为碳质量分数小于1%的超低碳MgO-MA-C 标型砖试样.在对比各试样(包括普通MgO-C砖试样)的抗氧化性能、高温抗折强度、体积稳定性和抗渣性的基础上,对配方和生产工艺进行了优化,研制出了性能较好的超低碳(碳质量分数小于1%)MgO-MA-C砖.所研制砖在武钢200 t转炉钢包渣线区使用,平均使用次数达75次.

关键词: 钢包 , 渣线 , 超低碳 , 方镁石-尖晶石-碳砖 , 纳米碳

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