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Optimization Study of Calcium Leaching From Steelmaking Slag

XU An-jun , ZHANG Hui-ning , YANG Yi , CUI Jian , HE Dong-feng , TIAN Nai-yuan

钢铁研究学报(英文版)

Abstract: In order to study calcium leaching behavior for the steelmaking slag, factors that influence the leaching yield have been optimized. The results show that granularity of the slag, liquid to solid ratio (in short for L/S), temperature and reaction time have a significant effect on the leaching yield. The optimal conditions for leaching are determined as follows: 1) the granularity at 75 μm, L/S at 100, temperature at 60 ℃; 2) the granularity at 75 μm, L/S at 50, temperature at 40 ℃. Finally, the optimal leaching yield under these conditions is about 15%.

关键词: Key words: steelmaking slag , leaching yield , calcium content

Establishment of Neural Network Prediction Model for Terminative Temperature Based on Grey Theory in Hot Metal Pretreatment

ZHANG Hui-ning , XU An-jun , CUI Jian , HE Dong-feng , TIAN Nai-yuan

钢铁研究学报(英文版)

In order to improve the accuracy of model for terminative temperature in steelmaking, it is necessary to predict and control before decarburization. Thus, an optimization neural network model of terminative temperature in the process of dephosphorization by laying correlative degree weights to all input factors related was used. Then simulation experiment of model newly established is conducted utilizing 210 data from a domestic steel plant. The results show that hit rate arrives at 5645% when error is within plus or minus 5%, and the value is 100% when within ±10%. Comparing to the traditional neural network prediction model, the accuracy almost increases by 6839%.Thus, the simulation prediction fits the real perfectly, which accounts for that neural network model for terminative temperature based on grey theory can reflect accurately the practice in dephosphorization. Naturally, this method is effective and practicable.

关键词: grey theory , correlation degree , dephosphorization , terminative temperature , neural network model

Improving the electrochemical properties of natural graphite spheres by coating with a pyrolytic carbon shell

新型炭材料

Two kinds of modified natural graphite (MNG) spheres with a pyrolytic carbon shell on smooth or granular surface were obtained using fluidized bed chemical vapor deposition of acetylene by adjusting the reaction parameters. The core of the NING has a highly ordered graphite structure and the shell has a disordered structure. Compared with natural graphite (NG) spheres, MNG with a core-shell structure shows improved first cycling efficiency and cyclability. Especially, the NING spheres with a granular surface possess 84% retention of the first discharge capacity after 41 cycles, owing to effective decrease of the contact resistance and increase of contact area between the NING spheres.

关键词: fluidized bed chemical vapor deposition;core-shell structure;pyrolytic;carbon;modified natural graphite;lithium ion secondary battery;lithium-ion batteries;chemical-vapor-deposition;1st-cycle charge loss;anode material;encapsulated graphite;surface-area;infiltration;performance;improvement;pyrocarbon

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

预测复合材料非线性有效介电系数的割线方法

周萧明 , 胡更开

复合材料学报 doi:10.3321/j.issn:1000-3851.2004.06.026

提出了预测复合材料非线性电位移和电场强度关系的一种解析方法,该方法基于各向材料的割线介电常数,将非线性问题转化成一系列线性问题来求解.该方法适用于任意各向异性复合材料和组分材料的非线性性质,而常用的Stroud和Hui的模型只适用于各向同性复合材料和组分材料的弱线性.证明了本文方法具有Ponte Castaneda提出的变分结构.计算结果表明,当基体非线性较小时,本文模型的预测与Stroud和Hui的模型一致,但当基体非线性系数增大时,本文模型能给出合理的预测结果,而Stroud和Hui的模型则会超出基体和夹杂的性能范围.

关键词: 复合材料 , 介电常数 , 非线性 , 割线方法

Broer-Kaup-Kupershmidt方程的新精确解

杨立娟 , 杨琼芬 , 杜先云

量子电子学报 doi:10.3969/j.issn.1007-5461.2012.02.003

CK方法是求解非线性发展方程的一种有效的直接方法.利用推广的CK方法,求得(2+1)维Broer-Kaup-Kupershmidt方程的Backlund公式,从而获得方程的大量新的精确解,推广了Xu和Zhang的结果.

关键词: 非线性发展方程 , Broer-Kaup-Kupershmidt方程 , 精确解 , CK方法 , Backlund变换

Three-dimensional (3D) Ising universality in magnets and critical indices at fluid-fluid phase transition

Phase Transitions

Experimental data for critical exponents in some magnetic materials are compared with recent theoretical results on the three-dimensional (3D) Ising model, as derived by one of us (ZDZ) based on two conjectures [Z.D. Zhang, Conjectures on the exact solution of three-dimensional (3D) simple orthorhombic Ising lattices, Phil. Mag. 87 (2007), pp. 5309-5419]. It is found that critical exponents in some bulk magnetic materials indeed form a 3D Ising universality. Our attention is then focused on the critical indices at fluid-fluid phase transition. We suggest to use Zhang's exponent = 3/8 to fit the experimental data over the wider asymptotic region near the critical point of a fluid-fluid phase transition. The 3D Ising universality should exist for critical indices in a certain class of magnets and at fluid-fluid phase transition.

关键词: magnetically ordered materials;fluid-fluid;phase transitions;order-disorder effects;ferromagnetic curie temperature;liquid critical phenomena;x-ray-scattering;critical exponents;critical-point;coexistence;curves;binary-solutions;ionic-solutions;behavior;equation

Response to the Comment on 'Conjectures on exact solution of three-dimensional (3D) simple orthorhombic Ising lattices'

Philosophical Magazine

The error of Equation (15b) in my article [Z.D. Zhang, Phil. Mag. 87 (2007) p.5309] in the application of the Jordan-Wigner transformation does not affect the validity of the putative exact solution, since the solution is not derived directly from that equation. Other objections of Perk's comment [J.H.H. Perk, Phil. Mag. 89 (2009) p.761] are the same as those in Wu et al.'s comments [F.Y. Wu et al., Phil. Mag. 88 (2008) p.3093; p.3103], which do not stand on solid ground and which I have sought to refute in my previous response [Z.D. Zhang, Phil. Mag. 88 (2008) p.3097]. The conjectured solution can be utilized to understand critical phenomena in various systems, whereas the conjectures are open to rigorous proof.

关键词: 3D Ising model;exact solution;conjecture;critical phenomena;ferromagnetism;magnetic phase transition;model;analyticity

不同掺杂的钇系-123薄膜磁通特性

张鹰子 , 王志 , 向建勇 , 闻海虎

低温物理学报 doi:10.3969/j.issn.1000-3258.2005.z1.087

我们在磁场中分别测量了最佳掺杂的YBa2Cu3O7-δ、钙0.2掺杂的Y1-xCaxBa2Cu3O7-δ及钙0.5掺杂的Pr1-xCaxBa2Cu3O7-δ薄膜的电阻温度关系.利用最近Zhang et al. [Phys. Rev. B 71(2005), 052502 ]提出的热激活能的分析方法对薄膜的磁通特性进行了分析、比较与讨论.

关键词: Y-123薄膜 , 涡旋特性 , 激活能

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