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Relationship Between Grain Boundary Segregation of Antimony and Temper Embrittlement in TitaniumDoped Nickel-Chromium Steel

ZHENG Lei , ZHANG Maicang , DONG Jianxin , MENG Ye

钢铁研究学报(英文版)

The observations given by Ohtani et al are analyzed in the present paper and it is concluded that the kinetics of temper embrittlement in titanium-doped low carbon NiCr steel agree well with those of non-equilibrium grain-boundary segregation of Sb. Besides, the mechanism of non-equilibrium grain-boundary segregation of Sb is determined to be the most satisfactory one among the existed mechanisms in the literature to interpret the Sb-induced embrittlement kinetics in the NiCr steel. Based on the conclusion and the determination, the activation energy and frequency factor of diffusion of Sb-vacancy complexes are obtained for the first time according to the concept of critical time in non-equilibrium grain-boundary segregation theory. The calculated results can give theoretical basis for predicting and controlling over the Sb-induced embrittlement in steels.

关键词: grain-boundary segregation;temper embrittlement;critical time;diffusion activation energy

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

改性曼尼希胺水性环氧固化剂的制备及性能

李楚新 , 段颖 , 丁嘉欣 , 夏新年

涂料工业 doi:10.3969/j.issn.0253-4312.2012.08.008

以聚醚胺(D - 230)和DMP - 30为原料,利用胺交换反应制得一种新型的改性曼尼希胺(MAI).然后以自制的端官能环氧聚合物( PEG - EP)与低相对分子质量液体环氧树脂(EP)为扩链剂对MAI进行扩链改性,并用苯基缩水甘油醚(PGE)封端,最后采用相反转法制得了一种新型的改性曼尼希水性环氧固化剂.讨论了PEG - EP的添加量、MAI与EP的加料比及封端剂的添加量对水性固化剂体系稳定性的影响.并采用物理化学方法对反应程度及涂膜的性能进能了表征分析.优化体系固化涂膜硬度229s,柔韧性1mm,附着力0级,适用期5h,耐水性优异.

关键词: 水性 , 环氧固化剂 , 改性 , 曼尼希胺

Broer-Kaup-Kupershmidt方程的新精确解

杨立娟 , 杨琼芬 , 杜先云

量子电子学报 doi:10.3969/j.issn.1007-5461.2012.02.003

CK方法是求解非线性发展方程的一种有效的直接方法.利用推广的CK方法,求得(2+1)维Broer-Kaup-Kupershmidt方程的Backlund公式,从而获得方程的大量新的精确解,推广了Xu和Zhang的结果.

关键词: 非线性发展方程 , Broer-Kaup-Kupershmidt方程 , 精确解 , CK方法 , Backlund变换

Three-dimensional (3D) Ising universality in magnets and critical indices at fluid-fluid phase transition

Phase Transitions

Experimental data for critical exponents in some magnetic materials are compared with recent theoretical results on the three-dimensional (3D) Ising model, as derived by one of us (ZDZ) based on two conjectures [Z.D. Zhang, Conjectures on the exact solution of three-dimensional (3D) simple orthorhombic Ising lattices, Phil. Mag. 87 (2007), pp. 5309-5419]. It is found that critical exponents in some bulk magnetic materials indeed form a 3D Ising universality. Our attention is then focused on the critical indices at fluid-fluid phase transition. We suggest to use Zhang's exponent = 3/8 to fit the experimental data over the wider asymptotic region near the critical point of a fluid-fluid phase transition. The 3D Ising universality should exist for critical indices in a certain class of magnets and at fluid-fluid phase transition.

关键词: magnetically ordered materials;fluid-fluid;phase transitions;order-disorder effects;ferromagnetic curie temperature;liquid critical phenomena;x-ray-scattering;critical exponents;critical-point;coexistence;curves;binary-solutions;ionic-solutions;behavior;equation

Response to the Comment on 'Conjectures on exact solution of three-dimensional (3D) simple orthorhombic Ising lattices'

Philosophical Magazine

The error of Equation (15b) in my article [Z.D. Zhang, Phil. Mag. 87 (2007) p.5309] in the application of the Jordan-Wigner transformation does not affect the validity of the putative exact solution, since the solution is not derived directly from that equation. Other objections of Perk's comment [J.H.H. Perk, Phil. Mag. 89 (2009) p.761] are the same as those in Wu et al.'s comments [F.Y. Wu et al., Phil. Mag. 88 (2008) p.3093; p.3103], which do not stand on solid ground and which I have sought to refute in my previous response [Z.D. Zhang, Phil. Mag. 88 (2008) p.3097]. The conjectured solution can be utilized to understand critical phenomena in various systems, whereas the conjectures are open to rigorous proof.

关键词: 3D Ising model;exact solution;conjecture;critical phenomena;ferromagnetism;magnetic phase transition;model;analyticity

不同掺杂的钇系-123薄膜磁通特性

张鹰子 , 王志 , 向建勇 , 闻海虎

低温物理学报 doi:10.3969/j.issn.1000-3258.2005.z1.087

我们在磁场中分别测量了最佳掺杂的YBa2Cu3O7-δ、钙0.2掺杂的Y1-xCaxBa2Cu3O7-δ及钙0.5掺杂的Pr1-xCaxBa2Cu3O7-δ薄膜的电阻温度关系.利用最近Zhang et al. [Phys. Rev. B 71(2005), 052502 ]提出的热激活能的分析方法对薄膜的磁通特性进行了分析、比较与讨论.

关键词: Y-123薄膜 , 涡旋特性 , 激活能

1998 COMPREHENSIVE TABLE OF CONTENTS

中国腐蚀与防护学报

N。1Atmospheric Corrosivlty for Steels………………………………………………… .LIANG Caideng HO[I i。-tat(6)Caustic Stress Corrosion Cr。king of Alloy 800 Part 2.The Effect of Thiosul执e……………………………………… KONG De-sheng YANG Wu ZHAO Guo-zheng HUANG De.ltL。ZHANG Yu。。he CHEN She。g-bac(13)SERS slid E16CttOCh6iniC81 Stlldy Of Illhibit1Oli M6ch&tllsth Of ThlollY68 Oil ITOll ID H....

关键词:

Proposed magnetic equation of state for the three-dimensional Ising model near criticality: Is the insulating ferromagnet CrBr(3) a candidate?

Physics Letters A

In a magnetic system, consistent with Griffiths analyticity requirements one can parameterize the equation of state near criticality by writing H = r(beta delta)h(theta), T = rt(theta) and the magnetization M = r(beta)m(theta), where T is measured from the critical temperature. For the insulating ferromagnet CrBr(3), the experimental data of Ho and Litster [J.T. Ho, J.D. Litster, Phys. Rev. Lett. 22 (1969) 6031 is well fitted by m(theta) as a linear function of theta [P. Schofield, J.D. Litster, J.T Ho, Phys. Rev. Lett. 23 (1969) 1098]. Also Ho and Litster give beta = 0.368, gamma = 1.215 and delta = 4.3. Those critical experiments are very close to the recent 31) king results of Zhang [Z.D. Zhang, Philos. Mag. 87 (2007) 5309], namely beta = 3/8, gamma = 5/4 and delta = 13/3. We therefore predict that m(theta) will be proportional to theta as a fingerprint of the 3D Ising Hamiltonian. (C) 2009 Elsevier B.V. All rights reserved.

关键词: Critical-point effects;Critical exponents;Ising model;Criticality;Ferromagnet;Magnetic equation of state;critical exponents

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