材料期刊网

Melting Characteristics of Iron Ore Fine During Sintering Process

LI Hongge , ZHANG Jianliang , PEI Yuandong , ZHAO Zhixing , MA Zejun

钢铁研究学报(英文版)

The whole melting curve of iron ore during sintering process was obtained, and the melting characteristics of iron ore were defined and explained. The whole melting process of mixture, mixed by iron ore and CaO reagent at basicity of 20 and 40, respectively, was observed using a SiC heating furnace with camcorder unit, and the melting curves of mixture that were relative height vs temperature curves were obtained. Besides, the melting characteristics of iron ore during sintering were introduced through defining some points in the melting curves, such as liquid forming temperature, inflexion temperature and flowing temperature, and the meaning of different shapes of the melting curves was clarified.

关键词: iron ore , sintering , melting characteristic , melting curve

1998 COMPREHENSIVE TABLE OF CONTENTS

中国腐蚀与防护学报

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Noncollinear magnetic ground state of PrFeAsO

Europhysics Letters

Noncollinear magnetic investigations of the ground state in PrFeAsO have been performed by the density-functional theory. We calculated the total energy and made structure optimization, and the electronic density of states of PrFeAsO was analyzed. There are three different magnetic structures in PrFeAsO defined by experiments. Based on these magnetic structures, we studied four collinear and four noncollinear cases. The ground state is found to take the ordering proposed by Zhao, in which the FeAs plane is of stripe antiferromagnetism and Pr spins are perpendicular to Fe spins. The electronic density of states indicates that for PrFeAsO the increase of the electron Coulomb interaction leads to a decrease in conductivity. Copyright (C) EPLA, 2011

关键词: high-temperature superconductivity;phase-diagram;oxypnictides;instability

LC4铝合金稀土转化膜耐蚀性及影响因素

张巍 , 李久青 , 许江涛 , 陈昆

腐蚀学报（英文） doi:10.3969/j.issn.1002-6495.1999.06.004

开发了IC4铝合金稀土转化膜碱性两步成膜工艺ZH1,利用正交优化设计方法确定了最佳工艺参数.采用多种实验方法研究了经ZH1处理的LC4铝合金在氯化物环境中的耐蚀性及其影响因素,结果表明:经ZHI工艺处理过的LC4铝合金耐全面腐蚀和点蚀性能均有明显提高,稀土转化膜既抑制了腐蚀的阴极过程,也抑制了阳极过程.具有ZH1转化膜的LC4铝合金对氯离子浓度和pH值的变化不甚敏感.

关键词: 高强铝合金 , 稀土转化膜 , 耐蚀性学科

硝酸羟胺的热稳定性评估及热分解机理研究

刘建国 , 安振涛 , 张倩 , 杜仕国 , 姚凯 , 王金

材料导报 doi:10.11896/j.issn.1005-023X.2017.04.030

为评估氧化剂硝酸羟胺的热稳定性,使用标准液体铝皿于3 K/min、4 K/min、5 K/min加热速率下进行热分析.借助非等温DSC曲线的参数值,应用Kissinger法和Ozawa法求得热分解反应的表观活化能和指前因子,根据Zhang-Hu-Xie-Li公式、Hu-Yang-Liang-Xie公式、Hu-Zhao-Gao公式以及Zhao-Hu-Gao公式,计算硝酸羟胺的自加速分解温度和热爆炸临界温度,并对热分解机理函数进行了研究.设计了7条热分解反应路径,采用密度泛函理论B3LYP/6-311++G(d,p)方法对硝酸羟胺的热分解进行了动力学和热力学计算.计算结果表明,硝酸羟胺热分解的自加速分解温度TsADT=370.05 K,热爆炸临界温度Te0=388.68K,Tbp0=397.54 K,热分解最可几机理函数的微分形式为f(a) =17×(1-α)18/17.硝酸羟胺热分解各路径中,动力学优先支持路径Path 6、Path 5、Path 4和Path 1生成NO和NO2,其次是Path 2、Path 7和Path 3生成N2和N2O.温度在373 K以下时,Path 1'反应无法自发进行,硝酸羟胺无法进行自发的热分解.从热力学的角度来看,硝酸羟胺在370.05K以下储存是安全的.

关键词: 硝酸羟胺 , 热分析 , 热稳定性 , 热分解机理 , 密度泛函理论