ZHAO Zhiyi
,
XIE Jianxin
,
HE Xiaoming
,
DONG Kai
,
YU Yong
,
PAN Feng
钢铁研究学报(英文版)
In the process of steel tube production, continuous tube rolling is the foremost forming procedure and the critical step that decides the dimension precision and the surface quality. In the actual production of the 140 mm full floating mandrel mill in Steel Tube Branch in Baosteel, steel T91 was chosen to be the typical sample, selfmade rolling force transducer and mandrel velocity testing equipment were used, and a series of comprehensive tests on rolling parameters including the rolling force and mandrel velocity were carried out. After the experiment, the friction state between rolling tube and mandrel was analyzed. The friction coefficient was calculated and the values of 0033-0074 in each mill were obtained. The friction coefficient increases obviously along the rolling direction.
关键词:
continuous tube rolling;rolling force;mandrel velocity;friction coefficient
王丽
,
吴希文
,
张晨鼎
,
张通
,
简丽
,
武朝军
,
周涛
稀土
doi:10.3969/j.issn.1004-0277.1999.02.003
采用湿渣法研究了0℃时碘化钇(YI3)-乌洛托品氢碘酸盐(C6H12N4.HI)-水(H2O)的三元体系相平衡,绘制了该体系的等温溶解度相图,相图分析结果表明,该体系中有组成为YI3.C6H12N4.HI.14H2O的配合物生成,对所得配合物进行了化学分析、X-射线粉末衍射、红外光谱、差热-热重分析,测定了其密度、晶体轴性,确定了配合物结构中的配位关系.
关键词:
相平衡
,
碘化钇
,
乌洛托品氢碘酸盐
,
配合物
宁远涛
贵金属
评述了合金元素对Au的漂白效果和机制，介绍了白色开金的几种色度参数，如CIE-L a*b*色度参数和颜色盒，CIE-LAB-C-H-L米制色度参数和基于CIE-XYZ色度参数的ASTM D1925黄色指数YI，讨论了某些白色开金的色度参数与冶金学特征。基于金合金的漂白效应与合金成分的密切关系，ASTM D1925黄色指数YI为设计白色开金成分提供了基本的指南。
关键词:
金属材料
,
Au合金
,
白色开金
,
色度参数
,
色度图
徐旸
,
汪艳
,
傅轶
合成材料老化与应用
采用多次挤出的方法和氧化诱导期(OIT)方法考察了抗氧剂对聚丙烯热氧稳定性的影响,测定了各次挤出试样的熔体流动速率(MFR)、黄度指数(YI)、力学性能以及氧化诱导期(OIT).实验结果表明:添加由主抗氧剂1010和辅抗氧剂168组成的复合抗氧剂后聚丙烯的熔体流动速率(MFR)、黄度指数(YI)、拉伸强度和冲击强度、氧化诱导期(OIT)与未添加抗氧剂的聚丙烯相比降低明显减缓,说明抗氧剂可有效抑制聚丙烯的老化,延长其使用寿命.
关键词:
聚丙烯
,
抗氧剂
,
热稳定性
中国腐蚀与防护学报
N。1Atmospheric Corrosivlty for Steels………………………………………………… .LIANG Caideng HO[I i。-tat（6）Caustic Stress Corrosion Cr。king of Alloy 800 Part 2.The Effect of Thiosul执e……………………………………… KONG De-sheng YANG Wu ZHAO Guo-zheng HUANG De.ltL。ZHANG Yu。。he CHEN She。g-bac（13）SERS slid E16CttOCh6iniC81 Stlldy Of Illhibit1Oli M6ch＆tllsth Of ThlollY68 Oil ITOll ID H....
关键词:
Europhysics Letters
Noncollinear magnetic investigations of the ground state in PrFeAsO have been performed by the density-functional theory. We calculated the total energy and made structure optimization, and the electronic density of states of PrFeAsO was analyzed. There are three different magnetic structures in PrFeAsO defined by experiments. Based on these magnetic structures, we studied four collinear and four noncollinear cases. The ground state is found to take the ordering proposed by Zhao, in which the FeAs plane is of stripe antiferromagnetism and Pr spins are perpendicular to Fe spins. The electronic density of states indicates that for PrFeAsO the increase of the electron Coulomb interaction leads to a decrease in conductivity. Copyright (C) EPLA, 2011
关键词:
high-temperature superconductivity;phase-diagram;oxypnictides;instability
Physical Review B
An elastic Ising model for CoMnO(6) chain is proposed to explain the ferroelectricity induced by collinear magnetic order in Ca(3)CoMnO(6), and then a mean-field theory with interchain spin interactions based on this model is developed. With inclusion of the dynamics of polarization domains at finite temperature, we address the rationality of our theory by the good agreement of the calculated electric polarization and dielectric susceptibility with the reported data on Ca(3)Co(2-x)Mn(x)O(6) (x approximate to 0.96) [Y. J. Choi, H. T. Yi, S. Lee, Q. Huang, V. Kiryukhin, and S.-W. Cheong, Phys. Rev. Lett. 100, 047601 (2008)], a typical diatomic Ising spin chain system, while the predicted magnetic susceptibility shows some difference from experiment, the reason of which is discussed.
关键词:
calcium compounds;cobalt compounds;dielectric polarisation;ferroelectricity;Ising model;magnetic susceptibility;multiferroics;optical susceptibility;one-dimensional oxides;magnetic-properties;multiferroics;ca3co1+xmn1-xo6
余金秋
,
彭鹏
,
刁成鹏
,
吴浩
,
何华强
人工晶体学报
LaBr3 ∶Ce、LuI3 ∶Ce、SrI2 ∶Eu等新型卤化物闪烁晶体因其高光输出、高能量分辨率等优异的闪烁特性而引起人们的广泛关注.高纯无水稀土卤化物是生长上述闪烁晶体所必需的原料,但其制备困难和高昂成本,严重制约了这些晶体的发展和应用.本文报道了无水LaBr3、CeBr3、LaCl3、CeCl3、LuI3、GdI3、YI3、CeI3、EuI2等常用稀土卤化物的制备方法,并对其有效表征手段进行了介绍.
关键词:
闪烁晶体
,
稀土卤化物
,
制备
,
表征
刘建国
,
安振涛
,
张倩
,
杜仕国
,
姚凯
,
王金
材料导报
doi:10.11896/j.issn.1005-023X.2017.04.030
为评估氧化剂硝酸羟胺的热稳定性,使用标准液体铝皿于3 K/min、4 K/min、5 K/min加热速率下进行热分析.借助非等温DSC曲线的参数值,应用Kissinger法和Ozawa法求得热分解反应的表观活化能和指前因子,根据Zhang-Hu-Xie-Li公式、Hu-Yang-Liang-Xie公式、Hu-Zhao-Gao公式以及Zhao-Hu-Gao公式,计算硝酸羟胺的自加速分解温度和热爆炸临界温度,并对热分解机理函数进行了研究.设计了7条热分解反应路径,采用密度泛函理论B3LYP/6-311++G(d,p)方法对硝酸羟胺的热分解进行了动力学和热力学计算.计算结果表明,硝酸羟胺热分解的自加速分解温度TsADT=370.05 K,热爆炸临界温度Te0=388.68K,Tbp0=397.54 K,热分解最可几机理函数的微分形式为f(a) =17×(1-α)18/17.硝酸羟胺热分解各路径中,动力学优先支持路径Path 6、Path 5、Path 4和Path 1生成NO和NO2,其次是Path 2、Path 7和Path 3生成N2和N2O.温度在373 K以下时,Path 1'反应无法自发进行,硝酸羟胺无法进行自发的热分解.从热力学的角度来看,硝酸羟胺在370.05K以下储存是安全的.
关键词:
硝酸羟胺
,
热分析
,
热稳定性
,
热分解机理
,
密度泛函理论
