ZHU Ziyong V.A.Marichev Institute of Physical Chemistry of the Academy of Sciences of the USSR
,
Moscow
,
117171
,
USSR.
材料科学技术（英文）
The ambiguous effect of cathodic polarization on SCC of two high strength steels in 0.1 M Na_2HPO_4 and 0.1 M NaNO_3 has been investigated by means of meas- uring electric resistance(R)and recording acoustic emis- sion(AE)signals simultaneously.Results showed that AE sensitivity strongly depends on K value in different solu- tions.Both anodic and cathodic polarization can acceler- ate crack growth rate at high K values,but it appears that there are only subtle differences in their AE characteristics.AE signals only reflect the macroprocesses of crack growth rather than the elementary ones and can not be used for identification of the micro-mechanisms of SCC.
关键词:
acoustic emission
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null
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null
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null
B.W. Wang
,
H. Shen
金属学报(英文版)
Ni-Cr System solar selective thin solid films were prepared by d.c. magnetron reactivesputtering under the atmosphere of O2 and N2. Ni-Cr alloy was chosen as targetmaterial and copper sheets as substrate. Using SEM, Spectrophotometer and Talystepto analyze the relations between the selective characteristic and the structure, theformation and the thickness of the thin films. The aim is to obtain good solar selectivethin films with high absorptance and low emittance, which is applied to flat plate solarheat collectors.
关键词:
solar selective thin film
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null
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null
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null
PAN Tao
,
YANG Cai-fu
钢铁研究学报(英文版)
Chemistry and process optimization of N80 seamless tube was studied by thermo-mechanical simulation tester Gleeble 1500D. Several heats of V-microalloyed steel with different N contents were firstly made at lab in order to simulate N80 seamless tube steel. The results showed that N addition increased strength under condition that toughness was kept at a high level compared with low-N steel. In this study N content with 120-200 ppm enhanced combination performance of strength and toughness whether in-line normalizing process was adopted or not. In-line normalizing process was helpful to improve the toughness though it lowered strength by some degree. However, direct final rolling after tandem rolling (without in-line normalizing) helped increase strength while the toughness remained somehow poor. The above phenomena concerning N80 seamless tube was closely associated with dissolution and precipitation behavior of V(CN). V(CN) precipitation was optimized when N content was increased. When in-line normalizing process was adopted, V(CN) precipitation in austenite increased due to low temperature history during intermediate (in-line) normalizing process. V(CN) particles existing in austenite contributed to grain refinement for VN induced intergranular ferrite, while they weakened precipitation strengthening effect since V precipitating in ferrite wais reduced.
关键词:
seamless tube;in-line normalizing;V-N microalloying;reheating;mechanical properties;Gleeble simulation
新型炭材料
The 2011 Annual World Conference on Carbon (Carbon 2011) was held in Shanghai, China, during 24-29 July, 2011. This conference was hosted jointly by East China University of Science and Technology, University of Shanghai for Science and Technology, and Institute of Coal Chemistry Chinese Academy of Sciences. About 800 attendees from 42 countries/regions participated in this conference, and 797 papers were accepted for presentation, including 5 plenary lectures, 42 keynote lectures, 280 oral presentations, and 470 posters, involving 10 topics: graphene; nanocarbon, carbon for energy storage and conversion, porous carbon and adsorption, carbon fiber and composites, precursor/carbonization and graphitization, computation and modeling, bio-carbon and safety, novel experimental techniques and characterization, bulk carbon and industrial applications. Research and development of nanocarbons are quite active and in particular, graphene received tremendous interest. Rapid progress has also been made on the electrochemical properties, energy conversion and energy storage applications of carbon materials.
关键词:
Acta Physico-Chimica Sinica
Adsorption of thiourea (TU) and ethylthiourea( ETU) on roughened silver electrode was investigated using in situ surf. enhanced Raman spectroscopy(SERS) Using quantum chemistry and HSAB theories, the influences of electrode potential and the different substituent groups on SERS were disc i. TU is chemisorbed perpendicularly by Ag-S bond on silver at E = -0.3 V and adsorption of TU turns into a parallel orientation at E = -0.9 V. ETU is always chemisorbed at an angle from Ag. The adsorption of ETU is through and C=C and C=O groups at E = -0.3 V, and mainly through C=C at E = -0.9V.
关键词:
Surface enhanced Raman spectroscopy;Adsorption;Quantum chemistry;Thiourea;Inhibitor
Journal of Applied Physics
A CO2 sensor made of nano crystalline CuO-BaTiO3 semiconductor, which has a giant capacitance effect, is designed based on the principle of the physical effect in the nano cluster. After an experimental investigation of its microstructure, the correlation between the quantum size effect and the giant capacitance effect is suggested. The characteristic physical quantities relating to the giant capacitance effect of the sensor are studied systematically with the aid of a gas detector. The quantum size effect is introduced as an interpretation for the mechanism of the giant capacitance effect and a model is proposed for describing the giant capacitance effect of the sensor. (C) 2000 American Institute of Physics. [S0021-8979(00)05020-9].
关键词:
mixed-oxide capacitor;transitions;powders
Shanthi Subramanian
,
David Muller
,
John Silcox and Stephen L.Sass (Department of Materials Science and Engineering and Department of Applied and Engineering Physics
,
Cornell University
,
Ithaca. NY 14853)
金属学报(英文版)
Local chemistry plays an important role in determining the cohesive strength of grain boundaries in Ni3Al. Doping with B increases the room temperature ductility and changes the fracture mode from intergranular to transgranular, while doping with Zr increases the ductility but leaves the fracture mode predominantly intergranular.Electron Energy Loss Spectroscopy (EELS) and Energy Dispersive X-ray Spectroscopy (EDS) were used to probe the changes in local bonding (and hence the cohesive strength) produced by changes in local chemistry at large angle boundaries in Ni3Al.In addition , small angle tilt boundaries were studied to correlate structure with Nienrichment at the interface. B segregation to Ni-rich grain boundaries was shown to make the bonding similar to that of the bulk, thereby increasing their fracture resistance. Ni-enrichment does not occur in the presence of Zr segregation to grain boundaries. Ni-enrichment to antiphase boundaries (APB) in small angle tilt boundaries lowers the APB energy by reducing the number of high energy Al-Al interactions across the interface. Ni-enrichment to large angle boundaries is expected to produce a similar effect on energy.
关键词:
: grain boundary chemistry
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null
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null
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null
材料科学技术（英文）
BIOSS4 steel is essentially a nickel-free austenitic stainless steel developed by the Institute of Metal Research, Chinese Academy of Sciences, in response to nickel allergy problems associated with nickel-containing stainless steels that are widely used in medical applications. The high nitrogen content of this steel effectively maintains the austenitic stability and also contributes to the high levels of corrosion resistance and strength. BIOSS4 steel possesses a good combination of high strength and toughness, better corrosion resistance, and better blood compatibility, in comparison with the medical 316L stainless steel. Potential applications of BIOSS4 steel can include medical implantation material and orthodontic or orthopedic devices, as well as jewelries and other decorations.
关键词:
medical stainless steel;nitrogen;nickel-free;nickel-allergy;blood;compatibility;austenitic steels;high-nitrogen;corrosion;cells
