Zhigang CHEN (Ceramic Research Lab.
,
Jiangsu University of Science and Technology
,
212013
,
Zhenjiang
,
China)
材料科学技术(英文)
Wear resistance of several zirconia toughened ceramics in comparison with a metal-ceramic CoWC has been studied in drawing wire field test. Result indicates that the harder the ceramic die, the longer the service life. Excellent wear resistance of ceramic die is obtained with a very high hardness (19 GPa). The service life is nearly three times that of Co-WC die. SEM observation on wear surfaces showed that material removal is mainly caused by plastic flow and ploughing process. But when the ceramic is composed of zirconia, alumina and some titanium carbide, micro-chipping and tribochemical reaction take place, and wear rate increases. Wear and friction induced martensite was detected by XRD. The T-M (tetragonal to monoclinic) phase transformation has a contribution to inhibiting microfracture.
关键词:
Guoqing CHEN
,
Kaifeng ZHANG
,
Guofeng WANG
,
Y
,
ong YU
材料科学技术(英文)
Numerical simulation of hot-press sintering of nano-sized ceramic powders was introduced by the commercial finite element code MSC.MARC. The powder plastic model and the thermo-mechanical coupled quadrilateral element were developed and adopted in the simulation. The mechanical and thermal properties of the nano-sized alumina based powders were determined. In addition, the experimental research and numerical simulation of the sintering process of different initial densities were carried out. The stress state in sintering of green compacts with different initial densities was analyzed by the densification theory. The reason for the density fluctuations of as-sintered ceramic bulks was found out.
关键词:
Sintering
,
null
,
null
,
null
李开明
,
李亚洲
,
冯维贵
,
林长
量子电子学报
doi:10.3969/j.issn.1007-5461.2007.05.014
采用非线性反馈控制,用附加了带参数的正弦项对Chen系统进行了有效的控制.随着参数k的逐渐增大,系统的动力学行为呈现出一系列的变化.数值研究结果表明:随控制参数的增大,驱动信号的强度渐大,混沌系统由混沌运动到周期轨道,最终到一相点.
关键词:
混沌
,
Chen系统
,
不动点
,
Lyapunov指数
,
反馈控制
郑树起
,
闵光辉
,
邹增大
,
王效志
,
韩建德
金属学报
系统研究了利用La2O3和B4C粉制备LaB6粉末的反应合成工艺.La2O3-B4C系反应热力学分析表明反应产物的气体分压对LaB6的形成有重要影响,减小气体分压可以明显降低LaB6的合成温度,结合DTA测定结果,确定了LaB6粉末的合成温度.利用X射线衍射分析了不同温度和保温时间条件下所生成粉末的相组成,并分别用扫描电镜和化学分析方法分析了所生成LaB6粉末的颗粒尺寸、形貌及纯度.实验结果表明,La2O3-B4C系制备LaB6粉末的优化工艺是真空度133 Pa,1673 K保温2.5 h,所合成的LaB6粉末颗粒比较规整,大多呈近似圆球形,平均直径3μm,纯度达98.2%.
关键词:
La2O3
,
null
,
null
,
null
,
null
郑树起
,
闵光辉
,
邹增大
,
王效志
,
韩建德
金属学报
doi:10.3321/j.issn:0412-1961.2001.04.018
系统研究了利用La2O3和B4C粉制备LaB6粉末的反应合成工艺.La2O3-B4C系反应热力学分析表明反应产物的气体分压对LaB6的形成有重要影响,减小气体分压可以明显降低LaB6的合成温度,结合DTA测定结果,确定了LaB6粉末的合成温度.利用X射线衍射分析了不同温度和保温时间条件下所生成粉末的相组成,并分别用扫描电镜和化学分析方法分析了所生成LaB6粉末的颗粒尺寸、形貌及纯度.实验结果表明,La2O3-B4C系制备LaB6粉末的优化工艺是真空度133 Pa,1673 K保温2.5 h,所合成的LaB6粉末颗粒比较规整,大多呈近似圆球形,平均直径3μm,纯度达98.2%.
关键词:
La2O3
,
B4C
,
反应
,
合成
,
LaB6
徐秀华
,
肖汉宁
,
郭文明
,
高朋召
,
彭苏华
无机材料学报
doi:10.3724/SP.J.1077.2011.00417
以La2O3和B4C为原料, 在常压下合成了LaB6粉末. 计算了常压合成LaB6的热力学条件, 采用XRD、 SEM、激光粒度分析表征了不同温度和保温时间合成的LaB6粉末的物相组成、颗粒形貌和粒度分布, 探讨了LaB6粉末的合成反应机理. 结果表明, 常压下1650℃保温2h的产物经酸洗后, 能得到纯度为99.22%具有立方体结构的LaB6粉末. 当La2O3颗粒尺寸远小于B4C时, 合成过程中LaB6首先在B4C表面生成, 随温度升高和保温时间延长, 未反应的La2O3和LaBO3通过LaB6壳不断扩散到B4C核表面直至反应完全. 合成LaB6粉末的初始形貌和尺寸主要取决于反应物B4C原料 .
关键词:
LaB6
,
thermodynamic
,
solid-state reaction
,
reaction mechanism
徐秀华
,
肖汉宁
,
郭文明
,
高朋召
,
彭苏华
无机材料学报
doi:10.3724/SP.J.1077.2011.00417
以La2O3和B4C为原料,在常压下合成了LaB6粉末.计算了常压合成LaB6的热力学条件,采用XRD、SEM、激光粒度分析表征了不同温度和保温时间合成的LaB6粉末的物相组成、颗粒形貌和粒度分布,探讨了LaB6粉末的合成反应机理.结果表明,常压下1650℃保温2h的产物经酸洗后,能得到纯度为99.22%具有立方体结构的LaB6粉末.当La2O3颗粒尺寸远小于B4C时,合成过程中LaB6首先在B4C表面生成,随温度升高和保温时间延长,未反应的La2O3和LaBO3通过LaB6壳不断扩散到B4C核表面直至反应完全.合成LaB6粉末的初始形貌和尺寸主要取决于反应物B4C原料.
关键词:
LaB6
,
热力学
,
固相反应
,
反应机理