L.M Ma
,
G.J. Liang
,
CG. Fan
,
and Y Y Li(Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China)
金属学报(英文版)
Effects of γ, η precipitates and grain size on hydrogen damage (HD) of JBK-75 precipitate-strengthened austenitic steel were examined using the method of high-pressure thermal hydrogen charging and tensile tests. The hydrogen content in the charged specimens was 25.2 wppm. At the condition of η phase-free precipitating, the HD of the steel increased with increasing γ size, fine spherical γ dispersively dis-tributed was beneficial to improve the hydrogen-resistant property. η-phae precipitated at grain boundary increased HD tendency, while intragranular cellular η had less effect on it. Fine austenitic gruin Aize was beneficial to decrease the HD. At the condition of η phase-free precipitating, both hydrogen changed and uncharyed specimens of the steel fractured in ductile transgranular mode, whilst hydrogen promoted the intergranular fracture when obvious η precipitates were found.
关键词:
hydrogen damage
,
null
,
null
Transactions of Nonferrous Metals Society of China
The microstructure and mechanical properties of Mg-10.1Gd-3.74Y-0.25Zr (mass fraction, %) alloy (GW104 alloy) cast by metal mould casting (MMC) and lost foam casting (LFC) were evaluated, respectively. It is revealed that different forming modes do not influence the phase composition of as-cast alloy. In the as-cast specimens, the microstructures are similar and composed of alpha-Mg solid solution, eutectic compound of alpha-Mg+Mg(24)(Gd, Y)(5) and cuboid-shaped Mg(5)(Gd, Y) phase; whereas the average grain size of the alloy produced by metal mould casting is smaller than that by lost foam casting. The eutectic compound of the alloy is completely dissolved after solution treatment at 525 degrees C for 6 h, while the Mg5(Gd, Y) phase still exists after solution treatment. After peak-ageing, the lost foam cast alloy exhibits the maximum ultimate tensile strength of 285 MPa, and metal mould cast specimen 325 MPa at room temperature, while the tensile yield strengths of them are comparable. It can be concluded that GW104 alloy cast by lost foam casting possesses similar microstructure and evidently lower mechanical strength compared with metal mould cast alloy, due to slow solidification rate and proneness to form shrinkage porosities during lost foam casting process.
关键词:
Mg-Gd-Y-Zr alloy;lost foam casting;metal mould casting;microstructure;mechanical property;age-hardening response;tensile properties
Physica Status Solidi a-Applied Research
Amorphization behavior is studied for several Y-based binary metal systems by room temperature 360 keV xenon ion mixing of multiple metal films to doses ranging from 7 x 10(14) to 1 X 10(16) Xe/cm2. In all systems studied, amorphization is achieved after ion mixing to the relevant doses. Interesting results are observed in the Ti-Y system, having rather positive heat of formation, i.e. 16 kJ/mol. A metastable crystalline Ti-Y phase is formed, for the first time, at medium dose ion mixing, and complete amorphous phase is formed in a narrow composition range, i.e. around Ti45Y55. Recrystallization temperatures of all formed amorphous alloys are determined by both, in-situ transmission electron microscopy annealing and confined furnace annealing. Possible interpretation is given to the observations by comparing with those proposed models for predicting glass forming ability.
关键词:
amorphous alloy formation;phase formation;thin-films;prediction
桂全红
,
马禄铭
,
蒋晓军
,
梁国军
,
李依依
材料研究学报
研究了两种不同Y 含量对8090Al-Li 合金拉伸性能及断裂行为的影响。实验表明:加入0.1wt-%Y 可在不降低强度的情况下提高合金的塑性,加入0.5wt-%Y 可在不降低塑性的情况下提高合金的强度。在峰值时效条件下,不加Y 的合金断裂为穿晶韧窝型和沿晶塑性混合方式,并伴有沿晶二次裂纹,加0.1%Y 不改变合金断裂模式,但使沿晶成分减少;加0.5%Y 合金则发生快速剪切断裂。本文从晶粒结构角度对断裂行为提出了解释。
关键词:
A—Li 合金
,
rare earth element Y
,
tensile properties
,
intergranular fracture
,
transgranular fracture
Journal of Physical Chemistry C
We report the electrical, thermal, magnetic, and thermoelectric properties of Y-doped Ca(3)Co(4)O(9) from 300 down to 5 K. The results indicate that with Y doping, the increase of resistivity originates from the decreases of carrier concentration and mobility, while the increase of Seebeck coefficient is caused by the reduction of carrier concentration together with the enhanced electronic correlation. Point-defect scattering, is the dominant thermal transport mechanism in this system. Due to the considerable difference in mass between Y(3+) and Ca(2+), thermal conductivity is observably suppressed by doping. The substitution of Y also disturbs the interlayer ferrimagnetic coupling. The ground state of this System converts front ferrimagnetism to paramagnetism gradually. The alteration of transport properties of Ca(3-x)Y(x)Co(4)O(9) reveals two Crossovers: the transition from Fermi-liquid-like metal to thermally activated semiconductor occuring at x approximate to 0.25, and the transition from thermally activated semiconductor to two-dimensional variable range hopping semiconductor occurring at x approximate to 0.5. The optimal thermoelectric response In Ca(3-x)Y(x)Co(4)O(9) is found to exist only at the critical state after which the doping-induced metal-insulator transition takes place. Oil the basis of these experimental results, a possible phase diagram for Ca(3-x)Y(x)Co(4)O(9) is proposed.
关键词:
temperature thermoelectric properties;giant magnetoresistance;solid-solutions;conductivity;electron;system;ca3co4o9+delta;thermopower;crystals;behavior
刘成
,
杨毅
,
韩正玉
,
武晓雅
,
翁景霞
,
林璐
中国稀土学报
doi:10.11785/S1000-4343.20130408
采用溶胶-凝胶法制备Li+掺杂改性的Y2SiO5:Pr3+上转换发光材料,考察了Li+掺杂对样品晶型及发光性能的影响.采用XRD,DSC-TGA,FS对所制备的材料进行表征,结果表明Li+掺入浓度在7％～ 8％(摩尔分数)之间会引起Y2SiO5晶体类型由X型转变为X2型,且Li+掺入后样品转晶型温度由950℃降至800℃;样品经800℃煅烧处理后以X1型Y2SiO5为主相,850℃煅烧处理后以X2型Y2SiO5为主相;Li+掺入同时会提高Y2SiO5:Pr3+材料的上转换发光强度,Li+最佳掺杂浓度为10％,对于双掺杂pr3+,Li+:Y2SiO5体系中pr3+最佳掺杂浓度为1.2％.
关键词:
溶胶-凝胶法
,
上转换
,
晶相转变
,
锂掺杂
,
稀土
沙桂英
,
刘翠云
,
刘腾
,
孙晓光
,
李根
材料工程
doi:10.3969/j.issn.1001-4381.2010.07.014
利用Hopkinson压杆技术对Mg-3.5%Li及Mg-3.5%Li-0.77%Y合金在不同应变率下进行了冲击压缩实验,分析了两种合金的动态应力-应变行为及其应变率效应.结果表明,随应变率提高,Mg-3.5%Li合金的应力-应变行为表现出应变率强化效应与应变率弱化效应的双重特性.添加稀土元素Y后,合金有所强化,但其应力-应变行为仍具有应变率弱化效应,随应变率提高产生的微裂纹引起的内部损伤是导致合金应变率弱化效应的主要原因.
关键词:
Mg-Li合金
,
Mg-Li-Y合金
,
应变率
,
微裂纹
冯剑
,
黄金亮
,
贾玉鑫
兵器材料科学与工程
为改善铸态Mg-12Li-3Gd-3Y-0.6Zr合金的力学特性，对铸锭进行均匀退火处理。采用金相显微镜、SEM、XRD、显微硬度测试和拉伸力学特性测试，观察和研究了试验合金的微观组织和力学特性。结果表明：最佳的均匀化退火工艺为500℃×8 h，均匀化退火后合金的抗拉强度由铸态的114 MPa提高到133 MPa。第二相形态及分布的改变是Mg-12Li-3Gd-3Y-0.6Zr合金力学特性改变的主要原因。
关键词:
镁锂合金
,
均匀化
,
微观组织
,
力学特性
彭晓东
,
李俊辰
,
李文娟
,
杨艳
,
魏群义
稀有金属材料与工程
采用光学显微镜、SEM扫描电镜、XRD以及力学性能和电化学测试等手段,研究了不同Y含量对Mg-9Li-3Al合金组织、力学性能和腐蚀性能的影响.结果表明:随着Y的添加,α相的形貌逐渐发生变化,其体积分数也逐渐减少,并形成新的Al2Y相,Al2Y主要分布在β相和α相内部.当Y的添加量为1.6％(质量分数)时,材料的抗拉强度达到最大190.2 MPa;当Y含量为2.0％时,材料的最大延伸率为19.3％.在Y含量低于1.2％时,材料的抗腐蚀性能随Y含量的增加而减小,超过1.2％后,随着Y含量的增加而增加.
关键词:
镁合金
,
组织
,
力学性能
,
抗腐蚀性能
