X.H. Wei
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F. Ono
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null
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null
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null
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null
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null
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null
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null
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null
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null
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null
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金属学报(英文版)
Measurements of magnetic susceptibility in mechanically alloyed Fe-Ni Invar alloys were taken under pressures up to 7.5GPa. The rate of decrease in the Curie temperature for 700℃ annealed specimen was larger than that annealed at 1000℃. This result can be explained by considering the fact that the width of the concentration fluctuation becomes larger in the specimen annealed at lower temperature.
关键词:
invar alloy
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null
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null
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null
Z. Sun
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S.L. Zheng
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Y. Zhang
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null
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null
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null
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null
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null
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null
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null
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null
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null
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null
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金属学报(英文版)
Institute of Process Engineering, Chinese Academy of Sciences, China, has proposed a method for oxidative leaching of chromite with potassium hydroxide. Understanding the mechanism of chromite decomposition, especially in the potassium hydroxide fusion, is important for the optimization of the operating parameters of the oxidative leaching process. A traditional thermodynamic method is proposed and the thermal decomposition and the reaction decomposition during the oxidative leaching of chromite with KOH and oxygen is discussed, which suggests that chromite is mainly destroyed by reactions with KOH and oxygen. Meanwhile, equilibrium of the main reactions of the above process was calculated at different temperatures and oxygen partial pressures. The stable zones of productions, namely, K2CrO4 and Fe2O3, increase with the decrease of temperature, which indicates that higher temperature is not beneficial to thermodynamic reactions. In addition, a comparison of the general alkali methods is carried out, and it is concluded that the KOH leaching process is thermodynamically superior to the conventional chromate production process.
关键词:
chromite
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null
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null
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J.C. Li
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B.F. Wang
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J.Z. Cui
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null
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null
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null
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null
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null
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null
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null
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null
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null
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null
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null
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null
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金属学报(英文版)
With the aid of ANSYS software, the effect of different mould external part materials on magnetic flux density in the aluminum melt and magnetic field interaction of four coils applied with same currents were investigated. Calculating results showed that magnetic flux density in the aluminum melt was greatly improved and the magnetic field interaction among different coils was decreased when external part of mould is made of soft magnetic material. Based on the finding, a four-strand low-frequency electromagnetic casting 6063 aluminum alloy experiment was carried out in the laboratory. The experiment showed that the surface of the billet was smooth and had no exudations and cold shuts, the as-cast microstructures were fine, uniform, equiaxed, net-globular or globular under low-frequency electromagnetic field. The microstructure becomes finer with increased current value.
关键词:
low-frequency electromagnetic casting
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null
Y.L. Yang
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D. Zhang
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H.S. Kou
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C.S. Liu
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null
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null
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null
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null
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null
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null
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null
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null
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金属学报(英文版)
Laser cladded coatings of TiCN were produced on the surface of titanium. To obtain the optimal techniques, several conditions were tested by varying the laser scanning rate. The choice of shielding gas was also studied. The cladded coatings were then evaluated from the surface mechanics point of view based on their microhardness. The microstructure of some interesting samples was investigated by optical micrographs (OM). The results showed that under the condition of fixed pulse frequency and pulse width, the laser scanning rate and the shielding gas are the main factors influencing the components of coatings. TiCN coatings were decompounded and oxidized during the cladding process in the condition of no shielding gas of N2. X-ray diffraction results indicated that the composite coatings composed of TiCN, TiC, Ti2N, and TiO2 were produced using appropriate techniques. The results indicated that the best condition in terms of the surface microhardness is obtained when the scanning rate is 1.5mm / s, the pulse frequency is 15Hz, the pulse width is 3.0ms, and N2 is chosen as the shielding gas. The microhardness of the composite coatings is about 1331kg · mm - 2, which is about 4 times that of the substrate. The optical micrographs indicated that the cladding zone is made up of TiCN, TiO2, and some interdendritic Ti, but the diffusion zone mainly consists of the dendrites phase, and the cladded depth is about 80?滋m, which is more than 2 times that of the laser nitrided sample. There were no microcracks or air bubbles in the cladded sample, which was cladded using the above optimal techniques.
关键词:
laser cladding
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null
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null
L. Chen
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P.L. Wang
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P.N. Song
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J.Y. Zhang
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null
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null
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null
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null
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金属学报(英文版)
With the technology support of virtual reality and ANSYS software, an example on the simulation of temperature distribution of casting system during the solidification process was provided, which took the latent heat of phase change, the conditions for convection, and the interface heat transfer coefficient into consideration. The result of ANSYS was found to agree well with the test data. This research offers an unorthodox way or“Reverse Method” of defining the relevant thermal physical coefficient.
关键词:
solidification process
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null
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null
Z.H. Zou
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X.M. Yu
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B.S. Zhang
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Y. Qi
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null
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金属学报(英文版)
A reactive co-deposition processing for obtaining high-quality single-phase Bi2Sr2Cax-1CuxOy (Bi2212) thin films has been investigated using molecular beam epitaxy (MBE) with 2.7 × 10-3Pa ozone gas introduction for oxidation. The thin films with a constant composition of almost 2 : 2 : 1 : 2 were designed to be fabricated at the substrate temperature between 675 and 780℃, the substrate temperature dependence of the surface morphology and the emergence phases were investigated in detail. A noticeable result is that the distribution of Cu element in the thin films is sensitively changed with the substrate temperature. At 750℃ it is inclined to locate in the periphery of each grain through the diffusion process. At 780℃ the Cu-compositional fluctuation brought around the dendritic crystal growth in the thin films. Below 705℃, the Bi2212 single-phase cannot be achieved in the thin films.
关键词:
Bi2212 (Bi2Sr2Cax-1CuxOy) single-phase
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null
C.J. Sun
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H.R. Geng
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Y.S. Shen
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X.Y. Teng
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Z.X. Yang
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null
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金属学报(英文版)
The rheology feature of Sb, Bi melt and alloys was studied using coaxial cylinder high-temperature viscometer. The results showed that the curve of torsion-rotational speed for Sb melt presents a linear relation in all measured temperature ranges, whereas for the Bi melt, the curve presents obvious non-Newtonian feature within the low temperature range and at relative high shear stress. The rheology feature of Sb80Bi20 and Sb20Bi80 alloy melts was well correlated with that of Sb and Bi, respectively. It is considered that the rheology behavior of Sb melt plays a crucial role in Sb80Bi20 alloy and that of Bi melt plays a crucial role in Sb20Bi80 alloy.
关键词:
Newtonian liquid
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null
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null
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null
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R.Z. Wu
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Z.K. Qu
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B.D. Sun
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D. Shu
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J. Wang
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null
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金属学报(英文版)
The motion of melt droplets in spray degassing process was analyzed theoretically. The height of the treatment tank in spray degassing process could be determined by the results of theoretical calculation of motion of melt droplets. To know whether the melt droplets would solidify during spraying process, the balance temperature of melt droplets was also theoretically analyzed. Then proof experiments for theoretical results about temperature of melt droplets were carried. In comparison, the experimental results were nearly similar to the calculation results.
关键词:
spray degassing
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null
S.Y. Gao
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Y.Z. Zhang
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L.K. Shi
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B.L. Du
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M.Z. Xi
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H.Z. Ji
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null
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null
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金属学报(英文版)
Laser direct deposition (LDD) of metallic components is an advanced technology of combining CAD/CAM (computer aided design/computer aided manufacturing), high power laser, and rapid prototyping. This technology uses laser beam to melt the powders fed coaxially into the molten pool by the laser beam to fabricate fully dense metallic components. The present article mainly studies the LDD of Ti-6Al-4V alloy, which can be used to fabricate aircraft components. The mechanical properties of the Ti-6Al-4V alloy, fabricated by LDD, are obtained using the tension test, and the oxygen content of used powders and deposited specimens are measured. In the present article, it can be seen that the mechanical properties obtained using this method are higher than the ones obtained by casting, and equal to those got by wrought anneal. One aircraft part has been made using the LDD process. Because of this aircraft part, with sophisticated shape, the effect of the laser scanning track on the internal soundness of the deposited part was discussed.
关键词:
laser direct deposition
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null
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null
Y. Wang
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H.Z. Li
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C.N. Yu
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G.M. Wu
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I. Gordon
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P. Schattschneider
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O. Van Der Biest
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null
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null
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null
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金属学报(英文版)
Antimony induced crystallization of PVD (physics vapor deposition) amorphous silicon can be observed on sapphire substrates. Very large crystalline regions up to several tens of micrometers can be formed. The Si diffraction patterns of the area of crystallization can be observed with TEM (transmission electron microscopy). Only a few and much smaller crystals of the order of 1μm were formed when the antimony layer was deposited by MBE (molecular beam epitaxy) compared with a layer formed by thermal evaporation. The use of high vacuum is essential in order to observe any Sb induced crystallization at all. In addition it is necessary to take measures to limit the evaporation of the antimony.
关键词:
antimony
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null
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null
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