{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"通过1,4-对苯二酚二缩水甘油醚和2,2＇-二苯并咪唑二乙胺反应合成四苯并咪唑单体( TBMZ),经甲醛等缩合生成酚醛聚合物为基质的苯并咪唑螯合树脂(PTBMzS).新型螯合树脂配基含量达2.1～3.02 mmol/g.新树脂及其单体结构经13C核磁共振谱、FT-IR红外光谱、元素分析和DSC分析确证.测定了Cu2、Ni2、Zn2、Cd2和Co2氯化物在pH值为1.0 ～6.0的缓冲溶液中的配位容量.实验结果表明,该类螯合树脂对Cu2+有高度的选择性,KCux≥4.3非竞争条件下,PTBMZ-1的最大配位容量为1.15 mmoL/g( pH=5.0,CU2+),PTBMZ-2的最大配位容量为0.97 mmol/g( pH=5.0,Cu2),配基占有率分别为35.9％,33.4％.PTBMZ-1树脂对Cu2+吸附较快,t1/2=21 min.电子顺磁共振谱和FT-IR光谱分析结果表明,形成n(金属离子):n(配基)=1∶2的螯合物为主.","authors":[{"authorName":"曹宇","id":"ccd26670-7815-4401-8f3e-31588598c5d5","originalAuthorName":"曹宇"},{"authorName":"束怡","id":"fb0e9e28-c4f9-46f4-aa2a-373339483a52","originalAuthorName":"束怡"},{"authorName":"洪春雪","id":"1ce871b6-47c3-4e5c-83be-ce97cfacfd57","originalAuthorName":"洪春雪"},{"authorName":"娄杰","id":"e178da4e-3715-499a-b775-9cf00068881e","originalAuthorName":"娄杰"},{"authorName":"束家有","id":"1037608d-a32a-4905-b895-7223e6569451","originalAuthorName":"束家有"}],"doi":"10.3724/SP.J.1095.2012.00118","fpage":"174","id":"41ec9d1c-558c-43cc-8483-49ddfb0cbf21","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"b70cddbe-3157-4b2b-a0a8-3f91b5db3b7a","keyword":"螯合树脂","originalKeyword":"螯合树脂"},{"id":"19370234-b44a-4de5-819d-59de7c98a1c1","keyword":"酚醛基质","originalKeyword":"酚醛基质"},{"id":"80238108-0fcb-4b85-b451-0cb8057ec788","keyword":"二苯并咪唑二乙胺","originalKeyword":"二苯并咪唑二乙胺"},{"id":"a9d553ae-a648-4a3e-a44f-2df20436bddc","keyword":"金属离子吸附","originalKeyword":"金属离子吸附"}],"language":"zh","publisherId":"yyhx201202010","title":"酚醛基质苯并咪唑螯合树脂的合成及配位性能","volume":"29","year":"2012"},{"abstractinfo":"用基质辅助激光解吸电离飞行时间质谱(MALDI-TOF-MS)技术研究了F-46和JF-43型酚醛环氧树脂。获得了该类树脂的聚合度及其不同聚合度组分的分子结构;发现该类树脂中含有环氧氯丙烷的聚合物,给出了可能的分子结构。","authors":[{"authorName":"李智立","id":"8853c714-d405-42a6-b7cd-70e5e88edb03","originalAuthorName":"李智立"},{"authorName":"张银生","id":"a1cc66a5-2296-4741-a345-bfd6a0587609","originalAuthorName":"张银生"},{"authorName":"冀克俭","id":"d19e1b6f-ca44-45c1-a00f-386d7d3b6c0f","originalAuthorName":"冀克俭"},{"authorName":"王少明","id":"a56d5f8d-38d5-49ab-b497-fdae2b62a6b1","originalAuthorName":"王少明"},{"authorName":"郭兴华","id":"a91a25a1-39e9-4300-8912-c37acd0f1ff8","originalAuthorName":"郭兴华"},{"authorName":"刘淑莹","id":"5ccd9870-4b9e-4ea7-9c0f-8eb3dd170785","originalAuthorName":"刘淑莹"},{"authorName":"季怡萍","id":"d2fb7bef-e1da-4284-8ae8-74172ddde94d","originalAuthorName":"季怡萍"}],"categoryName":"|","doi":"","fpage":"419","id":"80d402ab-67bd-4944-bd50-aa7e874596fc","issue":"4","journal":{"abbrevTitle":"CLYJXB","coverImgSrc":"journal/img/cover/CLYJXB.jpg","id":"16","issnPpub":"1005-3093","publisherId":"CLYJXB","title":"材料研究学报"},"keywords":[{"id":"d69c3fc3-f722-4032-9a34-020206d66bfd","keyword":"盘基质辅助激光解吸电离飞行时间质谱","originalKeyword":"盘基质辅助激光解吸电离飞行时间质谱"},{"id":"625fce1e-d01e-4595-a25b-185a3d7f5ef8","keyword":"null","originalKeyword":"null"},{"id":"4e9a6795-7adf-4479-b697-de29b41c0ef0","keyword":"null","originalKeyword":"null"}],"language":"zh","publisherId":"1005-3093_1997_4_8","title":"酚醛环氧树脂的基质辅助激光解吸电离飞行时间质谱(MALDI-TOF-MS)表征","volume":"11","year":"1997"},{"abstractinfo":"采用高邻位酚醛树脂、普通酚醛树脂以及引入少量超细无机晶须填料的酚醛树脂相复合为注塑料的基质,通过配方优选和塑炼工艺优化,制得了高绝缘性快速成型酚醛注塑料.该注塑料可快速成型,其注塑制品具有优异的电绝缘性能及热性能.","authors":[{"authorName":"周大鹏","id":"f1fea7f3-d2e0-4c3a-b09c-1fc4cc5924df","originalAuthorName":"周大鹏"},{"authorName":"郭维真","id":"079e623a-0bfa-4f1e-b186-dcd6a4f4e00c","originalAuthorName":"郭维真"},{"authorName":"邹沈斌","id":"9316771a-a1b1-41a3-a5ad-bbd1454bf7e7","originalAuthorName":"邹沈斌"}],"doi":"10.3969/j.issn.1009-9239.2006.02.001","fpage":"1","id":"8d40e20c-45db-4f09-833a-4eec22b748d8","issue":"2","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"9f6e938c-4ec5-4a43-b022-fe396de5c661","keyword":"酚醛注塑料","originalKeyword":"酚醛注塑料"},{"id":"3477d586-731c-4100-ae01-30c68bb3de72","keyword":"快速成型","originalKeyword":"快速成型"},{"id":"12e3ab59-e4e5-4985-a2d0-e162942e90a8","keyword":"高绝缘性","originalKeyword":"高绝缘性"}],"language":"zh","publisherId":"jycltx200602001","title":"高绝缘性快速成型酚醛注塑料的研制","volume":"39","year":"2006"},{"abstractinfo":"在环境作用下沥青易产生静态硬化和氧化硬化,使沥青的流变特性发生改变,而严重影响沥青路面的耐久性,如何合理评价和选择沥青对确保路面使用品质至关重要.通过三种不同基质沥青的组分分析和不同老化状态下沥青的常规试验(针入度、软化点和延度试验)、SHRP试验(DSR(Dynamic Shear Rheometer)和BBR(Bending Beam Rheometer)试验)结果比较,结合FTIR(Fourier transform infrared)试验结果,分析了不同老化状态下基质沥青的老化特性和机理.结果表明,常规试验可用来描述基质沥青老化前后性能变化,但它只能提供特定温度荷载频率下的试验信息,而SHRP试验可反映沥青老化对沥青流变行为的影响,建议采用SHRP流变学指标特别是BBR试验结果评价沥青的老化特性.","authors":[{"authorName":"陈华鑫","id":"cb254e37-14ac-40c1-8e84-521c6c67ef43","originalAuthorName":"陈华鑫"},{"authorName":"陈拴发","id":"46d67929-2911-4eeb-862b-4489920da469","originalAuthorName":"陈拴发"},{"authorName":"王秉纲","id":"8c3bd310-a691-4dab-a6a6-a887ed1f657e","originalAuthorName":"王秉纲"}],"doi":"10.3969/j.issn.1671-5381.2009.01.004","fpage":"13","id":"a8ecc0aa-0084-4c39-84b5-39fa8f09fced","issue":"1","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"85df684a-937b-4506-bd66-14309633762b","keyword":"老化行为","originalKeyword":"老化行为"},{"id":"8a2731aa-c297-4947-823a-3aa39f5dd516","keyword":"常规试验","originalKeyword":"常规试验"},{"id":"2fa650b6-bd0e-4e14-bb62-e127bac174f8","keyword":"SHRP试验","originalKeyword":"SHRP试验"},{"id":"1d0c7b9b-c3df-4902-ad89-5df608bda205","keyword":"FTIR红外光谱试验","originalKeyword":"FTIR红外光谱试验"},{"id":"5a52a2f0-c87c-4809-ad37-3747b1e632cd","keyword":"温度谱","originalKeyword":"温度谱"},{"id":"d9437d67-f5d8-4992-9534-dfa93e1bf28b","keyword":"流变特性","originalKeyword":"流变特性"}],"language":"zh","publisherId":"hccllhyyy200901004","title":"基质沥青老化行为与老化机理","volume":"38","year":"2009"},{"abstractinfo":"采用中档烧结镁砂(MS95,3～1 mm和≤1 mm)作骨料,电熔镁砂(MD97,≤0.088 mm)为主要基质料,将骨料与基质料的质量比控制在65/35,研制了连铸中间包工作衬用镁质干式振动料.通过常温性能检测和静态坩埚抗渣试验,分别研究了在基质中加入低温结合剂(固体酚醛树脂)、中温烧结剂(分别采用硼砂、氟化钠和六偏磷酸钠)以及抗渗剂(特级矾土和预合成尖晶石)对干式料强度或抗渣渗透性的影响.研究结果表明:固体树脂的加入量(质量分数,下同)在3%～5%之间时,干式料的常温强度最佳;中温烧结剂硼砂、氟化钠、六偏的加入量分别在1.5%、1%、1%左右时,对干式料中温烘烤时的促烧结作用最显著,且其促烧作用由强到弱依次是:硼砂、氟化钠、六偏;在基质中引入9%特级矾土的基础上再引入2%的尖晶石后,干式料的抗渣渗透性能最佳.","authors":[{"authorName":"吴武华","id":"9da62534-9842-4259-8476-7cc0255bc5ac","originalAuthorName":"吴武华"},{"authorName":"薛文东","id":"68881386-ecd6-4863-8cd6-4a2d69e221cd","originalAuthorName":"薛文东"},{"authorName":"高长贺","id":"ad8fbcf5-1212-48a1-a44f-d84cf68fbce1","originalAuthorName":"高长贺"},{"authorName":"孙伙长","id":"6486678a-f9fe-441d-aaf1-430e9045d962","originalAuthorName":"孙伙长"},{"authorName":"孙加林","id":"315badba-2003-4ded-ab68-1ddceacf3b1e","originalAuthorName":"孙加林"}],"doi":"10.3969/j.issn.1001-1935.2007.02.012","fpage":"126","id":"2858657e-26dc-47e0-81b5-7c46b3e6c1fb","issue":"2","journal":{"abbrevTitle":"NHCL","coverImgSrc":"journal/img/cover/NHCL.jpg","id":"55","issnPpub":"1001-1935","publisherId":"NHCL","title":"耐火材料 "},"keywords":[{"id":"8f593348-d804-45c7-8fb4-1b7a904f77de","keyword":"中间包","originalKeyword":"中间包"},{"id":"a26a181e-585d-4040-b2c4-4d360428937e","keyword":"干式振动料","originalKeyword":"干式振动料"},{"id":"fa956cd8-e0ec-4ec2-8140-2dc12412e587","keyword":"基质组成","originalKeyword":"基质组成"},{"id":"72ae12b0-e10a-4d54-91da-a2f7650abeb4","keyword":"低温结合剂","originalKeyword":"低温结合剂"},{"id":"362900bd-9585-4112-8f54-d23c115a8e23","keyword":"中温烧结剂","originalKeyword":"中温烧结剂"},{"id":"28c182d0-4160-4369-a1e1-2564fd8e79c9","keyword":"抗渗剂","originalKeyword":"抗渗剂"},{"id":"5d99782b-13a2-46e0-97c9-56e90077ec39","keyword":"强度","originalKeyword":"强度"},{"id":"cd958b8b-2382-469e-9869-562db2ff9417","keyword":"抗渣渗透性","originalKeyword":"抗渣渗透性"}],"language":"zh","publisherId":"nhcl200702012","title":"基质组成对中间包干式振动料性能的影响","volume":"41","year":"2007"},{"abstractinfo":"浇注料的流变性在很大程度上受基质流变行为的影响和控制.本工作主要研究了矾土基浇注料基质中的SiO2微粉、Al2O3微粉、水泥的加入量、分散剂以及矾土细粉粒度对基质流变性(粘度、剪切速率和剪切应力)的影响.根据研究结果,得出了具有较好流变性的基质组成.","authors":[{"authorName":"叶方保","id":"ebccc3eb-9181-47e7-b371-6645acc073af","originalAuthorName":"叶方保"},{"authorName":"","id":"49379a49-b9cd-48a5-8cba-e08bc9c90e12","originalAuthorName":""},{"authorName":"刘新红","id":"8e524f28-9bfd-4ad1-81cf-a7dd05387d1f","originalAuthorName":"刘新红"},{"authorName":"钟香崇","id":"7ce729c7-60e2-4b37-8e87-bd379bbeb248","originalAuthorName":"钟香崇"}],"doi":"10.3969/j.issn.1001-1625.2004.01.006","fpage":"26","id":"7e68f182-3763-46fe-ada3-0cd2f475ad59","issue":"1","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报 "},"keywords":[{"id":"e9699aaa-0926-4c9b-b052-6736952c79fc","keyword":"矾土","originalKeyword":"矾土"},{"id":"ff4392ca-a036-47cb-b2f6-5bcc3d7938be","keyword":"微粉","originalKeyword":"微粉"},{"id":"6ce8bdd3-afcd-44b8-b25d-3dea8ea60dc7","keyword":"浇注料","originalKeyword":"浇注料"},{"id":"16eb9548-f643-4d1c-a50b-3875c93736ef","keyword":"基质","originalKeyword":"基质"},{"id":"fc690d4f-4a66-42c9-add5-664508500ad9","keyword":"流变性","originalKeyword":"流变性"}],"language":"zh","publisherId":"gsytb200401006","title":"矾土基浇注料基质的流变性","volume":"23","year":"2004"},{"abstractinfo":"分析了与纳米粒子在固体基质表面的吸附机理相关的问题,综述了一些纳米粒子在固体基质表面上的吸附.通过控制纳米粒子和固体基质的组成,对纳米粒子和固体基质表面进行修饰等,可以使溶液中的纳米粒子靠静电作用、疏水作用、络合作用、氢键、磁性作用、粒子之间的毛细作用等在固体基质表面上吸附.在纳米粒子吸附的过程中,水力作用对吸附有重要影响.纳米粒子被固体基质表面吸附的可逆性一般较差.结合吸附机理分析了金纳米粒子在无机和有机固体基质表面上的吸附、铂纳米粒子在聚电解质表面上的吸附、带正电的发光纳米粒子在纤维上的吸附、磁性纳米粒子在磁性基质上的吸附以及量子点在藻细胞上的吸附等.在上述分析的基础上展望了纳米粒子在固体基质表面上吸附的研究方向.","authors":[{"authorName":"吴志坚","id":"36b9ad91-06f1-4256-877b-7b9bd674edb4","originalAuthorName":"吴志坚"},{"authorName":"叶秀深","id":"22d93b18-5179-475b-977a-1fe85bab6a81","originalAuthorName":"叶秀深"}],"doi":"","fpage":"8","id":"cde6cc22-c396-4576-a033-83c84e99bbcd","issue":"19","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"70bf8378-c311-44d2-a0e1-b5d4d6f65baa","keyword":"纳米粒子","originalKeyword":"纳米粒子"},{"id":"eea706f6-8808-443d-86fe-189fdef5d86e","keyword":"固体基质","originalKeyword":"固体基质"},{"id":"7dbecf39-0007-4356-bc66-08d045b70d69","keyword":"吸附机理","originalKeyword":"吸附机理"}],"language":"zh","publisherId":"cldb201019002","title":"纳米粒子在固体基质表面的吸附","volume":"24","year":"2010"},{"abstractinfo":"本文研究了聚乙烯醇改性酚醛树脂对酚醛泡沫抗压强度的影响,采用混合发泡剂制得泡孔致密、导热系数较低的酚醛泡沫.","authors":[{"authorName":"刘浩","id":"6b99b02a-9c72-45ca-bd31-abc490064717","originalAuthorName":"刘浩"}],"doi":"10.3969/j.issn.1009-9239.2000.02.003","fpage":"12","id":"622bf644-7b95-42fd-b70b-41a0001d683c","issue":"2","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"aec6c70e-5139-4440-bae7-a53da3d9daad","keyword":"酚醛树脂","originalKeyword":"酚醛树脂"},{"id":"dcecd60f-bce2-4c35-bca9-1d82a55bf2a2","keyword":"聚乙烯醇","originalKeyword":"聚乙烯醇"},{"id":"59975af9-7568-4c47-8e5b-aec79f135919","keyword":"发泡剂","originalKeyword":"发泡剂"}],"language":"zh","publisherId":"jycltx200002003","title":"酚醛泡沫塑料的研究","volume":"","year":"2000"},{"abstractinfo":"结合作者实验室的研究工作,并引用文献157篇,对高效液相色谱用硅胶基质色谱填料进行了综述.","authors":[{"authorName":"蒋生祥","id":"1c2b7318-76e5-457a-856d-a56eb55e2984","originalAuthorName":"蒋生祥"},{"authorName":"刘霞","id":"67599e20-1ee3-4864-9b5c-edc3144e1001","originalAuthorName":"刘霞"}],"doi":"10.3321/j.issn:1000-8713.2007.02.008","fpage":"163","id":"94475037-c2cc-48bb-be86-227f63ead278","issue":"2","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 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