{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"电容器储能以其轻便、高效、环保等特点正在逐步引起人们的重视.为制备高储能密度的电容器介质材料,研究以聚偏氟乙烯(PVDF)为基体,以纳米尺度的导电聚苯胺(PANI)为填料,采用溶液法及后续的球磨工艺制备了高储能密度的全有机复合薄膜介质材料.研究了添加物含量、频率等因素对复合介质材料介电性能的影响.发现当PANI体积分数达到0.05时(略高于渗流阈值fc=0.041),复合薄膜的介电常数在100Hz条件下高达456,击穿场强为60 MV/m,储能密度达到了7.2 J/cm 3,与PVDF基体相比提高了3倍多.另外还发现即使在渗流阈值附近,复合薄膜介电性能仍具有一定的频率稳定性.介电常数在低频范围(102~104Hz)内基本保持不变.利用SEM对复合薄膜的表面形貌进行了分析,发现有机填料PANI粒子在PVDF基体内有很好的分散性.另外利用XRD分析了复合薄膜的晶体结构,发现该制备工艺条件下所得复合材料基体主要以β-PVDF形式存在,这有助于发挥PVDF基体的功能性.渗流阈值理论可用来解释介电常数随添加物含量和频率的变化规律.研究结果表明,该制备工艺可得到适用于较宽频率范围的高储能密度复合薄膜.","authors":[{"authorName":"苑金凯","id":"2e41d714-acbd-483f-82f4-6de4ef60c458","originalAuthorName":"苑金凯"},{"authorName":"党智敏","id":"b8c561e3-6a28-47d4-a641-5adcee689717","originalAuthorName":"党智敏"}],"doi":"10.3969/j.issn.1009-9239.2008.05.001","fpage":"1","id":"51bbd7f1-c7be-43a1-981c-486b287485ed","issue":"5","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"2114ba60-276d-4cf6-9174-a10183d31c0c","keyword":"高介电","originalKeyword":"高介电"},{"id":"85bd133b-cce5-49a7-b872-4977926c20bc","keyword":"储能密度","originalKeyword":"储能密度"},{"id":"67dbd5ed-9379-40f5-a5ab-84e3fbb8da85","keyword":"全有机","originalKeyword":"全有机"},{"id":"453d8726-97eb-4e3a-a2b6-2534feb5910f","keyword":"复合薄膜","originalKeyword":"复合薄膜"},{"id":"7d4d4520-4d1d-4051-99f2-f6eb6ca745f8","keyword":"导电聚苯胺","originalKeyword":"导电聚苯胺"}],"language":"zh","publisherId":"jycltx200805001","title":"高储能密度全有机复合薄膜介质材料的研究","volume":"41","year":"2008"},{"abstractinfo":"全有机电活性复合材料(All-organic Composites,AOC)是一种智能材料,具有特殊的电性能和机械性能.综述了全有机电活性聚合物的近期研究状况,分析了高介电机理,介绍了制备、复合过程,并对全有机电活性复合材料的应用前景进行了展望.","authors":[{"authorName":"苑金凯","id":"2417fbb8-72a0-4412-a183-d61619c60773","originalAuthorName":"苑金凯"},{"authorName":"党智敏","id":"1a83f475-728b-4eb6-a7b5-f4fadea90969","originalAuthorName":"党智敏"}],"doi":"10.3969/j.issn.1009-9239.2007.03.007","fpage":"22","id":"f6efd798-2dce-4f6f-ac8f-ed73232fa5e5","issue":"3","journal":{"abbrevTitle":"JYCL","coverImgSrc":"journal/img/cover/JYCL.jpg","id":"50","issnPpub":"1009-9239","publisherId":"JYCL","title":"绝缘材料"},"keywords":[{"id":"01036904-1e3f-4426-b18b-ced885021633","keyword":"电活性聚合物","originalKeyword":"电活性聚合物"},{"id":"b1df6ae8-708b-4367-8b84-d81b952f2cfc","keyword":"场致应变","originalKeyword":"场致应变"},{"id":"f3823443-0e24-4db2-8737-4c8cf108e000","keyword":"高介电常数","originalKeyword":"高介电常数"},{"id":"8c2bf8e4-fd36-46ba-ae9a-a3eb509fee74","keyword":"全有机复合材料","originalKeyword":"全有机复合材料"}],"language":"zh","publisherId":"jycltx200703007","title":"全有机电活性复合材料的研究进展","volume":"40","year":"2007"},{"abstractinfo":"通过正交实验对有机导电涂料进行了研究,得到了有机导电涂料的最佳配比,经测试涂料具有良好的导电、导热等性能.","authors":[{"authorName":"郝建军","id":"a7456ff2-e3c5-41b1-aa9f-f528ae79661a","originalAuthorName":"郝建军"}],"doi":"10.3969/j.issn.1005-748X.2000.09.007","fpage":"404","id":"78f88185-ca8e-4ec8-b898-7079af94602f","issue":"9","journal":{"abbrevTitle":"FSYFH","coverImgSrc":"journal/img/cover/FSYFH.jpg","id":"25","issnPpub":"1005-748X","publisherId":"FSYFH","title":"腐蚀与防护"},"keywords":[{"id":"8bb872c2-d8b4-4aa2-8689-97778d7173ec","keyword":"正交设计","originalKeyword":"正交设计"},{"id":"fd18f8c6-9789-4667-a906-939825b88c7e","keyword":"有机导电涂料","originalKeyword":"有机导电涂料"}],"language":"zh","publisherId":"fsyfh200009007","title":"有机导电涂料的制备","volume":"21","year":"2000"},{"abstractinfo":"介绍了有机亲水涂料的合成方法,讨论了反应温度、单体加入方式及A与B组分对有机亲水涂料性能的影响.","authors":[{"authorName":"朗书玲","id":"5e5672d1-0f67-4868-a0e6-94004ff3129d","originalAuthorName":"朗书玲"},{"authorName":"李爱先","id":"9059a48b-3d7e-4e7c-82f6-6bba0c763c99","originalAuthorName":"李爱先"}],"doi":"10.3969/j.issn.0253-4312.2004.05.015","fpage":"50","id":"575adf59-6710-467b-a5b5-d5170a4290e9","issue":"5","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"8683d742-86e0-401b-9c35-eb59a866d5c6","keyword":"亲水涂料","originalKeyword":"亲水涂料"},{"id":"5f91a07a-d5f6-484f-9dd2-6ec875fd38ca","keyword":"有机涂料","originalKeyword":"有机涂料"},{"id":"1a8e644e-bb8d-431d-a035-8d348b19ad53","keyword":"有机-无机硅丙复合聚合物","originalKeyword":"有机-无机硅丙复合聚合物"},{"id":"c609b63e-4d56-427c-bd0d-fea4e7d142d7","keyword":"合成","originalKeyword":"合成"},{"id":"1d9c43dc-344e-4dca-8c17-e387988668e5","keyword":"研制","originalKeyword":"研制"}],"language":"zh","publisherId":"tlgy200405015","title":"有机亲水涂料研制","volume":"34","year":"2004"},{"abstractinfo":"","authors":[],"doi":"","fpage":"46","id":"fd8668d6-e102-4a89-80c1-6caf7517e160","issue":"1","journal":{"abbrevTitle":"LZ","coverImgSrc":"journal/img/cover/LZ.jpg","id":"52","issnPpub":"1005-4006","publisherId":"LZ","title":"连铸"},"keywords":[{"id":"7115653f-52d7-4837-ab82-c139ae7f2308","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"lz200401032","title":"全有机抑制物提高连铸机冷却系统","volume":"","year":"2004"},{"abstractinfo":"本文主要介绍了有机材料在制备光子晶体中的应用以及几种常用的制备方法.","authors":[{"authorName":"李文华","id":"cdf1a4cc-edee-4c8b-8048-61002ed5d2aa","originalAuthorName":"李文华"},{"authorName":"彭景翠","id":"7004dca0-7a22-49c9-bd78-df8d324a9b2f","originalAuthorName":"彭景翠"},{"authorName":"徐玉峰","id":"0e0ba36e-751b-4e2e-a3a8-151ee4af8d9f","originalAuthorName":"徐玉峰"},{"authorName":"张高明","id":"aa488592-ccb7-4b6b-992f-434d7bb0ba96","originalAuthorName":"张高明"},{"authorName":"周仁龙","id":"e0d2dee2-c679-4afc-96ab-4605380fe0ad","originalAuthorName":"周仁龙"},{"authorName":"林峰","id":"2cae0da3-d7dc-46a1-81c6-c9c0e3b1aecd","originalAuthorName":"林峰"}],"doi":"","fpage":"399","id":"b4e962b7-e87f-486f-8b06-ca6328fa5856","issue":"z1","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"a453bf80-fedf-483c-bedb-e3b38e0d0ac1","keyword":"光子晶体","originalKeyword":"光子晶体"},{"id":"df1821ab-a315-409f-a026-3d1793b39308","keyword":"制备","originalKeyword":"制备"},{"id":"8bdc1d2e-5e04-4733-b360-1d88546cacb4","keyword":"双光子聚合法","originalKeyword":"双光子聚合法"},{"id":"2a9e24a6-6ae3-4021-a712-09379bd93383","keyword":"胶体粒子法","originalKeyword":"胶体粒子法"},{"id":"3fe3a333-051a-4f20-8f32-1cbfd46d859d","keyword":"激光全息印刷法","originalKeyword":"激光全息印刷法"}],"language":"zh","publisherId":"gncl2004z1098","title":"有机光子晶体的制备","volume":"35","year":"2004"},{"abstractinfo":"以天然钙基膨润土为原料,经过提纯、钠化、有机化改性,研究了有机改性剂的类型及体系的pH值对有机膨润土性能的影响,并采用X-ray衍射分析(XRD)、傅立叶红外(FTIR)光谱分析等测试手段对其表征.研究表明,钠基土在中性偏碱的环境下,以有机阳离子季铵盐为改性剂,可以制备出性能优良的有机膨润土.","authors":[{"authorName":"刘国玉","id":"a9e57439-3963-4259-b1f9-e3c37129bce8","originalAuthorName":"刘国玉"},{"authorName":"刘曙光","id":"6605cf9b-77db-4782-95d0-ec07645a1abb","originalAuthorName":"刘曙光"}],"doi":"","fpage":"285","id":"45094fb6-d756-44fd-bf81-7d590c5fb599","issue":"2","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报 "},"keywords":[{"id":"0997ea18-008e-427a-bf47-ea594fb15c65","keyword":"膨润土","originalKeyword":"膨润土"},{"id":"0af34c2d-e67e-4f3b-963f-3aba2d43c7bb","keyword":"蒙脱石","originalKeyword":"蒙脱石"},{"id":"b14684ba-ab5c-424f-9fe4-2b286272ad44","keyword":"钠化","originalKeyword":"钠化"},{"id":"8ff7abf9-e8dd-4f9f-b44b-a78a27ee0f67","keyword":"有机化","originalKeyword":"有机化"}],"language":"zh","publisherId":"gsytb200902015","title":"膨润土的有机改性研究","volume":"28","year":"2009"},{"abstractinfo":"报道一系列有机锡,有机钛,有机锆和有机膦取代多酸化合物对两种人体肿瘤细胞SSMC-7721和Hela的抗肿瘤活性.其中有机钛多酸化合物表现为高于其他具有相同多酸阴离子的化合物的抗肿瘤活性.发现化合物具有很高的体内抗肿瘤活性和较低的毒性,并发现化合物的抗肿瘤活性与化合物的氧化还原能力呈顺变关系.","authors":[{"authorName":"刘景福","id":"f94eb1ad-fbf2-4d0e-9c98-ca014be329b8","originalAuthorName":"刘景福"},{"authorName":"王晓红","id":"b493de0e-8ae0-4a91-af7e-8e7cfd9b57be","originalAuthorName":"王晓红"},{"authorName":"孙振刚","id":"361aa49f-6ef1-4f50-ad5e-686073df63bb","originalAuthorName":"孙振刚"},{"authorName":"李恒达","id":"161ea05d-fde6-4b1f-9a5e-1a2592ef26fd","originalAuthorName":"李恒达"}],"doi":"10.3969/j.issn.1000-0518.2001.05.016","fpage":"357","id":"b96682c2-17d1-43b0-baba-6386513f6f93","issue":"5","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"40dae385-1d35-47b9-8417-9008c6e094d5","keyword":"有机金属","originalKeyword":"有机金属"},{"id":"cc02701f-28bf-49bd-b81e-38dd92f9dc9f","keyword":"多酸化合物","originalKeyword":"多酸化合物"},{"id":"70e906ca-0d71-43c8-9eed-963d6fa3818a","keyword":"抗肿瘤活性","originalKeyword":"抗肿瘤活性"}],"language":"zh","publisherId":"yyhx200105016","title":"有机和有机金属多酸化合物生物活性研究","volume":"18","year":"2001"},{"abstractinfo":"采用有机发光二极管(OLEDs)的有机半导体照明(有机照明)是绿色环保、健康安全的新型面光源,有望在固态照明领域得到广泛的应用.有机照明的发展是随着有机发光材料的不断进步而进步的.有机发光材料从最初的荧光材料发展到磷光材料以及最近提出的热活化延迟荧光材料,其性能在不断地提升.基于这些材料的白光OLEDs的性能也在不断提升.最早的白光器件基于荧光小分子材料,但是由于只能利用单线态激子发光,效率很低.随后磷光材料的引入使得白光器件的效率大幅度提升,但是由于蓝色磷光材料本身的稳定性问题,全磷光白光器件的寿命较短.为了结合荧光和磷光的优点,人们提出了荧光/磷光杂化的白光器件,这是目前最有前景的一类白光器件结构.目前针对有机照明的研究,已从早期只关注效率突破阶段,进入到综合提高效率和寿命阶段.从荧光白光、磷光白光以及荧光/磷光混合白光3个方面对有机照明的研究状况、发展趋势进行了介绍.","authors":[{"authorName":"张东东","id":"9a0e8b62-a6e4-4f4d-8572-83ac53d45d85","originalAuthorName":"张东东"},{"authorName":"赵炎","id":"9fe3297a-6d2b-42a6-9fd1-a511991ffabc","originalAuthorName":"赵炎"},{"authorName":"段炼","id":"34daba59-6400-4fc0-ad7e-05c9c112a0be","originalAuthorName":"段炼"},{"authorName":"邱勇","id":"16cad5ef-eab4-47bb-9af6-9eed82f13081","originalAuthorName":"邱勇"}],"doi":"10.7502/j.issn.1674-3962.2014.12.01","fpage":"703","id":"cd626340-b1ae-4ea0-b3c4-d17d1acc735b","issue":"12","journal":{"abbrevTitle":"ZGCLJZ","coverImgSrc":"journal/img/cover/中国材料进展.jpg","id":"80","issnPpub":"1674-3962","publisherId":"ZGCLJZ","title":"中国材料进展"},"keywords":[{"id":"9cce5466-8d12-4d0a-b101-14b7d3d38055","keyword":"有机照明","originalKeyword":"有机照明"},{"id":"a4701b46-d6d9-4d5d-b550-2b454fe4f450","keyword":"有机发光二极管","originalKeyword":"有机发光二极管"},{"id":"7b44f83e-5f7c-4a87-bb5a-4f99036f9824","keyword":"荧光","originalKeyword":"荧光"},{"id":"dfe7c455-5502-4a05-a147-3fae0077b9c6","keyword":"磷光","originalKeyword":"磷光"},{"id":"81101324-328e-417d-8284-4a98d29bb5c7","keyword":"延迟荧光","originalKeyword":"延迟荧光"}],"language":"zh","publisherId":"zgcljz201412001","title":"有机半导体照明(有机照明)研究进展","volume":"33","year":"2014"},{"abstractinfo":"本文简述了有机颜料的用途、分类和颜料工业国内外发展概况.介绍了有机颜料的应用性能及用于涂料工业的有机颜料品种.","authors":[{"authorName":"缪建明","id":"9bc23b67-ac15-4e45-a1f9-f1a24d14f8d9","originalAuthorName":"缪建明"}],"doi":"10.3969/j.issn.0253-4312.2004.09.006","fpage":"20","id":"a3aa6b4b-99c3-4a96-9cb9-fbc2e15fecf9","issue":"9","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"c942ff42-90c9-4cc5-ab57-857d015712d1","keyword":"有机颜料","originalKeyword":"有机颜料"},{"id":"6988577c-b509-4eb4-8f20-70a82b666ab3","keyword":"涂料工业","originalKeyword":"涂料工业"},{"id":"92b7a8d2-306f-49e0-9508-7da9aaefac35","keyword":"应用性能","originalKeyword":"应用性能"},{"id":"18b25163-c53c-4202-81a3-b6d78094361d","keyword":"发展趋势","originalKeyword":"发展趋势"},{"id":"7c942fd2-1aa1-4ce2-8df5-672a780d558b","keyword":"述评","originalKeyword":"述评"}],"language":"zh","publisherId":"tlgy200409006","title":"有机颜料概况及应用性能","volume":"34","year":"2004"}],"totalpage":11544,"totalrecord":115434}