{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"将O,O'-二辛基二硫代磷酸镨(PrDODP)用作天然橡胶(NR)硫黄硫化的促进剂.结果显示,PrDODP对NR硫化有显著促进效果;硫化动力学研究表明,含PrDODP的NR硫化反应活化能E为87.2 kJ/mol;PrDODP用量为3.36 (质量份)的硫化胶100%定伸强度、300%定伸强度、拉伸强度和撕裂强度等力学性能最高,而扯断伸长率最小.","authors":[{"authorName":"林新花","id":"07f1cb6e-1dfb-4ee8-be25-e9660dc398fb","originalAuthorName":"林新花"},{"authorName":"陈朝晖","id":"65918779-7578-4e5a-be47-03ffe4c0680b","originalAuthorName":"陈朝晖"},{"authorName":"王迪珍","id":"6324c3ff-a130-4be4-8398-88b64315683a","originalAuthorName":"王迪珍"}],"doi":"10.3969/j.issn.1004-0277.2007.04.014","fpage":"59","id":"6307f4bf-bb36-456d-bc0e-7d8c7a02be01","issue":"4","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"5c0a7651-87ca-4d1c-8f48-e3bb12d39ce5","keyword":"O,O'-二辛基二硫代磷酸镨","originalKeyword":"O,O'-二辛基二硫代磷酸镨"},{"id":"108dad1b-363b-43ca-85be-dd7ad50a50b4","keyword":"无亚硝胺促进剂","originalKeyword":"无亚硝胺促进剂"},{"id":"45cb9131-179d-404a-b33f-95a46915e40b","keyword":"NR","originalKeyword":"NR"},{"id":"f60eb5e4-c450-4273-b023-cc1554a34586","keyword":"硫化动力学","originalKeyword":"硫化动力学"}],"language":"zh","publisherId":"xitu200704014","title":"O,O'-二辛基二硫代磷酸镨对天然橡胶硫化及力学性能的影响","volume":"28","year":"2007"},{"abstractinfo":"为开发新型缓蚀剂，拓展O，O’-二烃基二硫代磷酸盐的应用领域，合成了O，O’-二苯基二硫代磷酸-N，N-二乙铵（DEDBDP），采用失重试验和电化学方法研究了DEDBDP在HCl介质中对Q235钢的缓蚀性能，结果表明：DEDBDP是一种优良缓蚀剂，（25±1）℃，5％HCl溶液中，DEDBDP浓度为120mg／L时，缓蚀率达85．23％；DEDBDP属阳阴极混合型缓蚀剂，适用于低温、较高酸度环境，具有持久的缓蚀性能；DEDBDP在QZ35钢表面吸附符合Langmuir吸附等温式，为自发的物理和化学吸附。","authors":[{"authorName":"谢斌","id":"42f70108-f6c3-4a51-a85a-5a29c89d0660","originalAuthorName":"谢斌"},{"authorName":"赖川","id":"ebd5e9a3-cb47-4f9c-b78f-d56b7b9c33ca","originalAuthorName":"赖川"},{"authorName":"邹立科","id":"cda80410-f809-4903-b03c-84263ce82f6c","originalAuthorName":"邹立科"},{"authorName":"易建","id":"b910cc61-1bd0-4abe-83f1-9ad77d211a33","originalAuthorName":"易建"},{"authorName":"曾倪","id":"1557063d-2998-48d7-856c-32d46adfcb2e","originalAuthorName":"曾倪"},{"authorName":"黄春","id":"f04af57c-b8d3-49f6-bd7c-d5e9f86fbcdb","originalAuthorName":"黄春"},{"authorName":"王艳美","id":"e5a20222-4f5e-4df8-8a86-a2a0d9336083","originalAuthorName":"王艳美"}],"doi":"","fpage":"63","id":"83dba16e-1249-4a4b-9002-6b6074e8bad8","issue":"12","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"be7ca3da-6ec0-4a5f-acac-a8d1420183e9","keyword":"缓蚀剂","originalKeyword":"缓蚀剂"},{"id":"713158d0-c107-462c-bb91-7dcb7748ac6c","keyword":"缓蚀性能","originalKeyword":"缓蚀性能"},{"id":"fb60605a-5f71-4d94-b1a1-a0b115d57164","keyword":"HCl","originalKeyword":"HCl"},{"id":"44ba2c9f-b354-452f-af4e-1bee9cb3c694","keyword":"O,O’-二烃基二硫代磷酸盐","originalKeyword":"O,O’-二烃基二硫代磷酸盐"},{"id":"04ac470f-2c5c-4122-8b0c-5f827a92b913","keyword":"Q235钢","originalKeyword":"Q235钢"}],"language":"zh","publisherId":"clbh201112021","title":"O，O’-二苯基二硫代磷酸-N，N-二乙铵的合成及其缓蚀性能","volume":"44","year":"2011"},{"abstractinfo":"合成了新型酸洗缓蚀剂O,O'-二（环己基）二硫代磷酸-N,N-二乙铵（EDCDP），通过失重和电化学方法研究EDCDP在H₂SO₄溶液中对Q235钢的缓蚀性能。结果表明，(27±1)℃，5% H₂SO₄溶液中，EDCDP质量浓度为100 mg/L时，缓蚀率为97.32%；在 Q235钢表面的吸附规律符合Langmuir吸附等温式，属于自发进行的化学吸附。EDCDP是一种受H₂SO₄浓度、温度和待测时间影响较小的混合型缓蚀剂。","authors":[{"authorName":"谢斌","id":"93aff5c4-1f36-47d1-bba9-c6055e0c93ce","originalAuthorName":"谢斌"},{"authorName":"赖川","id":"7e9101ce-bc2e-4b7a-9bfc-d973737b443f","originalAuthorName":"赖川"},{"authorName":"邹立科","id":"18902584-7b48-42e5-bc27-8ebd6c3deb0e","originalAuthorName":"邹立科"},{"authorName":"何林芯","id":"e8f34195-9ee9-40dc-b0e5-25a7e695386b","originalAuthorName":"何林芯"},{"authorName":"伍一峥","id":"e934d767-d668-4f8f-bf77-22a697ecac58","originalAuthorName":"伍一峥"},{"authorName":"黄炎俊","id":"9e821394-597f-4c76-968b-b504e8aea6bb","originalAuthorName":"黄炎俊"},{"authorName":"相阳光","id":"b38d77a7-1c8a-4fe9-8748-fa63ac1cedea","originalAuthorName":"相阳光"}],"categoryName":"|","doi":"","fpage":"225","id":"7442435d-bea2-4fa8-9db2-494cbdc2c50b","issue":"3","journal":{"abbrevTitle":"ZGFSYFHXB","coverImgSrc":"journal/img/cover/中国腐蚀封面19-3期-01.jpg","id":"81","issnPpub":"1005-4537","publisherId":"ZGFSYFHXB","title":"中国腐蚀与防护学报"},"keywords":[{"id":"15f3ed93-d0d2-4181-823d-06ea76a432c6","keyword":"O,O'-二烃基二硫代磷酸盐","originalKeyword":"O,O'-二烃基二硫代磷酸盐"},{"id":"8ba0af8e-b0a4-409b-b80e-e757161d132d","keyword":"H₂SO₄","originalKeyword":"H₂SO₄"},{"id":"bb3f3ab1-5ca1-45e7-8562-5b2ea3b793eb","keyword":"corrosion inhibitor","originalKeyword":"corrosion inhibitor"},{"id":"2d5f1cd1-780f-41ac-b2d1-e5a3a69430a0","keyword":"Q235 steel","originalKeyword":"Q235 steel"},{"id":"47704d07-2659-418d-8529-cb731e2facaf","keyword":"adsorption","originalKeyword":"adsorption"},{"id":"c0d2be24-967b-43dc-8aa9-47efba3ca90f","keyword":"inhibition efficiency","originalKeyword":"inhibition efficiency"}],"language":"zh","publisherId":"1005-4537_2011_3_11","title":"O,O'-二（环己基）二硫代磷酸-N,N-二乙铵对Q235钢在硫酸溶液中的缓蚀性能研究","volume":"31","year":"2011"},{"abstractinfo":"合成了O,O＇-二(4-甲苯基)二硫代磷酸-N,N-二乙铵([ Et2NH2][(4-MeC6H4O)2PS2],NOP),采用元素分析、红外光谱、核磁共振谱和单晶X射线衍射测试技术对其结构进行了表征,同时研究了NOP的热稳定性和缓蚀性.NOP晶体属单斜晶系,P21/n空间群,晶胞参数为:a=1.424 1 (3) nm,b=2.008 7(4) nm,c=1.436 6(3) nm,V=3.959 9(15) nm3,Dc=1.286 Mg/m3,Z=8,F(000)=1 632,μ(MoKα)=0.360 mm-1,S=1.001,(△/r)max=0.001,R1=0.0776,wR2=0.174 9(I＞2σ(I)).NOP的不对称结构单元中包括2个独立的子单元,2个子单元之间通过N-H……S氢键形成了一维链结构.在H2SO4溶液中,NOP能有效抑制Q235钢的腐蚀,是一种抑制阳极反应为主的高效混合型缓蚀剂；NOP在Q235钢表面的吸附符合Langmuir吸附等温式,属自发进行的物理和化学吸附.","authors":[{"authorName":"谢斌","id":"27d606fa-e382-4186-a038-d24822a2c50a","originalAuthorName":"谢斌"},{"authorName":"赖川","id":"887311b1-dd54-4648-826a-75b1c27ed2ae","originalAuthorName":"赖川"},{"authorName":"相阳光","id":"00a0034c-2526-4236-a8a6-1b50b63cdbb7","originalAuthorName":"相阳光"},{"authorName":"邹立科","id":"b07c612f-a192-4535-937a-94d0d87a7153","originalAuthorName":"邹立科"},{"authorName":"向珍","id":"996c132d-f365-44ad-b785-19acf2000568","originalAuthorName":"向珍"},{"authorName":"黄春","id":"8cdb8f4f-f9ec-4b3f-bc79-90f097e7bb4e","originalAuthorName":"黄春"},{"authorName":"易彬","id":"9bfe9624-63b7-4f75-87a3-982012850f1a","originalAuthorName":"易彬"}],"doi":"10.3724/SP.J.1095.2012.00082","fpage":"200","id":"d0ffe5aa-5ae2-4e01-b0b9-df0cbfdac279","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"ee3ebbb0-3c50-4800-80ca-e9fc211f26b6","keyword":"O,O'-二烃基二硫代磷酸盐","originalKeyword":"O,O'-二烃基二硫代磷酸盐"},{"id":"74be0dc8-ebae-4dc4-af74-ba5587e07a52","keyword":"晶体结构","originalKeyword":"晶体结构"},{"id":"9d886094-2ade-4629-9aa0-cd3abe5fa27c","keyword":"热稳定性","originalKeyword":"热稳定性"},{"id":"2b159afe-4c9f-4230-a7d6-b5557228e4a1","keyword":"缓蚀剂","originalKeyword":"缓蚀剂"},{"id":"a3d6a782-ea37-4939-adc9-5f17a446440a","keyword":"吸附","originalKeyword":"吸附"}],"language":"zh","publisherId":"yyhx201202015","title":"O,O '-二(4-甲苯基)二硫代磷酸-N,N-二乙铵的晶体结构、热稳定性及缓蚀性","volume":"29","year":"2012"},{"abstractinfo":"合成了一种新型缓蚀剂O,O'-二(2-苯乙基)二硫代磷酸二乙铵(EPP),并用元素分析和红外光谱对其进行了表征.采用静态失重法、极化曲线法和电化学阻抗法研究了EPP在HC1溶液中对Q235钢的缓蚀性能,探讨了其在Q235钢表面的吸附行为,考察了HCl浓度、腐蚀体系温度等因素对其缓蚀率的影响.结果表明:EPP是一种高效的混合型缓蚀剂,其缓蚀率随缓蚀剂浓度增加而增大,随腐蚀系统温度升高而缓慢减小.在30℃,1.0 mol·L-1的HCl溶液中,EPP浓度为60 mg·L-1时,其缓蚀率高达98.48％.EPP在Q235钢表面的吸附符合Langmuir吸附等温式,属于自发进行的化学吸附.量子化学计算结果表明,EPP通过配位键和反馈键与金属Fe形成了多中心、稳定的化学吸附.","authors":[{"authorName":"谢斌","id":"ba448d9e-26ae-4f7a-89d5-b1a89d9ee078","originalAuthorName":"谢斌"},{"authorName":"朱莎莎","id":"dbecf2c2-7e73-444e-b278-d9cbe2de9c23","originalAuthorName":"朱莎莎"},{"authorName":"李玉龙","id":"aaa0acff-42b3-4e9f-8878-45147d07dcd3","originalAuthorName":"李玉龙"},{"authorName":"赖川","id":"ac9680ea-e8f9-42dc-a1c3-f0daaf4ab695","originalAuthorName":"赖川"},{"authorName":"林肖","id":"f9428aac-ab18-4dae-b29b-eaf08a4cbb21","originalAuthorName":"林肖"},{"authorName":"邹立科","id":"d0887c04-300d-4165-8d4a-cf432a7cb78b","originalAuthorName":"邹立科"},{"authorName":"何林芯","id":"4186f7f6-c9c5-40df-8e04-f5339d7eea31","originalAuthorName":"何林芯"},{"authorName":"陈能","id":"482c88ee-13bf-4c90-b29b-cad91e4a66a0","originalAuthorName":"陈能"}],"doi":"10.11902/1005.4537.2013.139","fpage":"366","id":"73d37cd9-cae0-4e9e-a3b9-04b160378ad2","issue":"4","journal":{"abbrevTitle":"ZGFSYFHXB","coverImgSrc":"journal/img/cover/中国腐蚀封面19-3期-01.jpg","id":"81","issnPpub":"1005-4537","publisherId":"ZGFSYFHXB","title":"中国腐蚀与防护学报"},"keywords":[{"id":"21de7edc-dc8a-4a44-b4f6-c278e2bcc870","keyword":"O,O'-二(2-苯乙基)二硫代磷酸二乙铵","originalKeyword":"O,O'-二(2-苯乙基)二硫代磷酸二乙铵"},{"id":"8eae20c7-460a-44d1-986c-123836314b81","keyword":"缓蚀剂","originalKeyword":"缓蚀剂"},{"id":"21c415ee-e7ea-4078-9de1-febc8be87d79","keyword":"Langmuir吸附等温式","originalKeyword":"Langmuir吸附等温式"},{"id":"fe6bba6e-05c7-41b9-bb25-f0f70a00df87","keyword":"量子化学","originalKeyword":"量子化学"}],"language":"zh","publisherId":"zgfsyfhxb201404012","title":"O,O'-二(2-苯乙基)二硫代磷酸二乙铵在HCl溶液中对Q235钢的缓蚀性研究","volume":"34","year":"2014"},{"abstractinfo":"合成了O,O'-(2-甲基-2,4-亚戊基)二硫代磷酸-N,N-二乙铵(PDP),用元素分析、红外光谱、核磁共振谱和X射线单晶衍射等技术手段对其结构进行了表征.PDP属四方晶系,I-4空间群,其晶胞参数为:a=2.1357(3) nm,b =2.1357(3) nm,c =0.71892(11) nm,oo =β=γ =90°,V=3.2791(8) nm3,Z =8,Dc=1.156 g/cm3,F(000)=1232,μ(MoKα)=0.412 mm-1,F(000)=1232,S=0.952,R=0.0664,wR=0.1791[I＞2σ(I)].PDP通过N—H…S和C—H…S氢键作用形成了一维超分子孔道结构.PDP在HCl溶液中对Q235钢的缓蚀性研究表明:PDP能有效抑制Q235钢的腐蚀,是阴极为主的混合型缓蚀剂,在Q235钢表面的吸附符合Langmuir吸附,属自发进行的物理化学吸附;在25℃的1.0 mol/L HCl溶液中PDP浓度为140 mg/L时的缓蚀率达到98.9％.CCDC:1404464.","authors":[{"authorName":"魏健","id":"a81e0e3e-1d19-46a3-9753-99b063d74eaa","originalAuthorName":"魏健"},{"authorName":"谢斌","id":"e7d89a4c-537a-4faf-9681-a172b515844a","originalAuthorName":"谢斌"},{"authorName":"赖川","id":"46f57d4e-6f15-4ac4-8d6f-17db725a8240","originalAuthorName":"赖川"},{"authorName":"何林芯","id":"a3097e0f-6168-4dad-a6aa-da00338c96b6","originalAuthorName":"何林芯"},{"authorName":"李玉龙","id":"880c9206-4ee3-4b1f-a587-3f4c89ee052c","originalAuthorName":"李玉龙"},{"authorName":"邹立科","id":"47eb9fc1-4d21-4b07-8079-d94ea1b8b4af","originalAuthorName":"邹立科"},{"authorName":"樊义康","id":"e2ec193e-12ad-4183-ad6a-eea40f07ae87","originalAuthorName":"樊义康"}],"doi":"10.11944/j.issn.1000-0518.2016.02.150219","fpage":"190","id":"906a2a87-58b3-46fb-836a-0fea1ed1abf7","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"c5db1d6b-ddc7-4439-94ca-e52cbec48400","keyword":"O,O'-亚烷基二硫代磷酸铵","originalKeyword":"O,O'-亚烷基二硫代磷酸铵"},{"id":"85dd24a2-fe12-4e90-bc59-984f480132b7","keyword":"晶体结构","originalKeyword":"晶体结构"},{"id":"dd646f8c-3e1f-43b5-bd68-d2422fa1f1bb","keyword":"缓蚀性","originalKeyword":"缓蚀性"},{"id":"55e842be-5bb0-4bbb-bfd1-8a515ff23373","keyword":"吸附机理","originalKeyword":"吸附机理"}],"language":"zh","publisherId":"yyhx201602010","title":"O,O'-(2-甲基-2,4-亚戊基)二硫代磷酸-N,N-二乙铵的合成、表征及缓蚀性能评价","volume":"33","year":"2016"},{"abstractinfo":"研究了五种二丁基二硫代磷酸稀土配合物(REDBDP)对天然橡胶硫化特性、力学性能和老化性能的影响,并与二丁基二硫代磷酸锌(ZnDBDP)进行了对比.采用平衡溶胀法测定硫化胶的表观交联密度.结果表明,O,O'-二丁基二硫代磷酸稀土金属配合物对天然橡胶(NR)具有明显促进硫化效果,硫化速率都比相应的锌盐快.五种稀土中,O,O'-二丁基二硫代磷酸镱硫化胶的交联密度最高,力学性能也最高.二丁基二硫代磷酸稀土配合物的硫化胶力学性能和耐热老化性能都比相应的锌盐高.","authors":[{"authorName":"林新花","id":"e07bed4e-2e16-4457-8dbf-05399b451a51","originalAuthorName":"林新花"},{"authorName":"陈朝晖","id":"60d41e06-cb18-4817-8e37-1884fcacec33","originalAuthorName":"陈朝晖"},{"authorName":"王迪珍","id":"cfbb4987-7fd3-4ad2-a128-dbb752a853ca","originalAuthorName":"王迪珍"}],"doi":"10.3969/j.issn.1004-0277.2009.02.014","fpage":"61","id":"2d9e594a-ac06-45de-9411-27319a9d0d47","issue":"2","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"00b098e3-2f16-4703-bc9f-511675e46dfb","keyword":"天然橡胶","originalKeyword":"天然橡胶"},{"id":"915e0ff8-b9c7-49a6-96d3-2f33173eb3b4","keyword":"O,O'-二丁基二硫代磷酸稀土配合物","originalKeyword":"O,O'-二丁基二硫代磷酸稀土配合物"},{"id":"2b5818e6-684f-4933-8617-6c77982afb88","keyword":"促进剂","originalKeyword":"促进剂"},{"id":"b532a87e-eedb-49d9-9283-0d1b8c4248d2","keyword":"硫化","originalKeyword":"硫化"}],"language":"zh","publisherId":"xitu200902014","title":"二丁基二硫代磷酸稀土配合物的橡胶硫化促进性能的研究","volume":"30","year":"2009"},{"abstractinfo":"通过Cu片腐蚀试验、红外光谱和XPS扫描分析， 对油溶性羧酸铜铜剂和二烷基二硫代磷酸锌(T202)的抗腐蚀性能进行了研究.铜剂与 T202分别具有良好的抗腐蚀特性，两者复合后随着铜剂含量的增加抗腐蚀效果变差. 添加剂之间相互作用使元素S的活性增强，是造成Cu片腐蚀的主要原因.","authors":[{"authorName":"姜秉新","id":"4c1cbe63-2a05-4d5d-ad48-544fe7560ae9","originalAuthorName":"姜秉新"},{"authorName":"陈波水","id":"051630c5-3bdc-4908-b3b0-72369c9b4083","originalAuthorName":"陈波水"},{"authorName":"郑发正","id":"9c967b84-42e7-4481-80fa-6fa0ccf562a4","originalAuthorName":"郑发正"}],"categoryName":"|","doi":"","fpage":"103","id":"42218f0c-7989-4ccd-a5e4-419f92abcf3f","issue":"2","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"efa16c1d-3f41-480b-8c9a-ec98a2267a4a","keyword":"油溶性羧酸铜","originalKeyword":"油溶性羧酸铜"},{"id":"90279f4a-0e4e-401b-a1d1-6b55283d50b6","keyword":"corrosion inhibitione","originalKeyword":"corrosion inhibitione"}],"language":"zh","publisherId":"1002-6495_2002_2_13","title":"油溶性羧酸铜与二烷基二硫代磷酸锌的抗腐蚀效果","volume":"14","year":"2002"},{"abstractinfo":"通过Cu片腐蚀试验、红外光谱和XPS扫描分析,对油溶性羧酸铜铜剂和二烷基二硫代磷酸锌(T202)的抗腐蚀性能进行了研究.铜剂与T202分别具有良好的抗腐蚀特性,两者复合后随着铜剂含量的增加抗腐蚀效果变差.添加剂之间相互作用使元素S的活性增强,是造成Cu片腐蚀的主要原因.\n","authors":[{"authorName":"姜秉新","id":"54f00cf7-c876-4e88-8a4c-0ff774b22963","originalAuthorName":"姜秉新"},{"authorName":"陈波水","id":"25685003-f554-48a1-87a0-44f16a00fb30","originalAuthorName":"陈波水"},{"authorName":"郑发正","id":"1bb00059-cc00-4184-8b61-13b395a906df","originalAuthorName":"郑发正"}],"doi":"10.3969/j.issn.1002-6495.2002.02.012","fpage":"103","id":"43aa2907-4c77-408d-b227-9f049b34c5fc","issue":"2","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"75e14375-5447-4dc5-93b9-0c5648351a41","keyword":"油溶性羧酸铜","originalKeyword":"油溶性羧酸铜"},{"id":"66f547de-3058-4a6e-8096-c0c82b24a78a","keyword":"抗腐蚀性能","originalKeyword":"抗腐蚀性能"}],"language":"zh","publisherId":"fskxyfhjs200202012","title":"油溶性羧酸铜与二烷基二硫代磷酸锌的抗腐蚀效果","volume":"14","year":"2002"},{"abstractinfo":"采用改进后的四球摩擦磨损试验机,研究了电磁场对含丁辛基二硫代磷酸锌盐(T202)和含双辛基二硫代磷酸锌盐(T203)的150SN基础油润滑性能的影响,结合扫描电子显微镜和X射线光电子能谱仪的分析结果,初步探讨了电磁场的作用机理.结果表明:在有、无电磁场的作用下,T202和T203添加剂都能增强基础油的润滑性能,其最佳的质量分数分别为1.0%~1.5%和1.5%~2.0%;在电磁场作用下,两种含二烷基二硫代磷酸锌(ZDDP)基础油中钢球的磨斑直径均比无电磁场时的小,且磨斑表面的犁沟较浅,擦伤程度较轻微;电磁场通过促进钢球表面摩擦化学反应膜的生成和摩擦副表面的改性(Zn-Fe合金的生成),提高了两种含ZDDP基础油的润滑性能.","authors":[{"authorName":"李建武","id":"8a63587f-faf1-4feb-997b-831a94ee851e","originalAuthorName":"李建武"},{"authorName":"江泽琦","id":"18dc81ec-2f8a-451f-8729-933909e4ced4","originalAuthorName":"江泽琦"},{"authorName":"方建华","id":"59ce73ab-34b1-4895-9b44-a331d9552944","originalAuthorName":"方建华"},{"authorName":"陈波水","id":"d8489e06-a31b-4e5b-86b4-9ca4b45516a3","originalAuthorName":"陈波水"},{"authorName":"谷科城","id":"5066f1d9-f6f9-481b-a349-31d8f1deb3f5","originalAuthorName":"谷科城"}],"doi":"10.11973/jxgccl201705010","fpage":"49","id":"b0524adb-1f52-4719-962b-8257546eed33","issue":"5","journal":{"abbrevTitle":"JXGCCL","coverImgSrc":"journal/img/cover/JXGCCL.jpg","id":"45","issnPpub":"1000-3738","publisherId":"JXGCCL","title":"机械工程材料"},"keywords":[{"id":"c59f4cba-4569-4e31-b815-74b682aa780c","keyword":"二烷基二硫代磷酸锌","originalKeyword":"二烷基二硫代磷酸锌"},{"id":"e9e4f883-dcaa-4239-af4b-22aa2ea178f1","keyword":"电磁场","originalKeyword":"电磁场"},{"id":"6dd4b5be-ad12-4141-8a82-1362af20dd73","keyword":"润滑性能","originalKeyword":"润滑性能"},{"id":"5eaab534-5848-4482-b29a-f6f5182b2fde","keyword":"基础油","originalKeyword":"基础油"}],"language":"zh","publisherId":"jxgccl201705010","title":"电磁场对含不同二烷基二硫代磷酸锌150SN基础油润滑性能的影响","volume":"41","year":"2017"}],"totalpage":5774,"totalrecord":57733}