{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"对壳聚糖<span style=\"color:red\">均相接枝</span>L-谷氨酸甲酯产物的结构和性能进行了研究.IR、CP/MAS13CNMR结果表明,谷氨酸甲酯侧链通过酰胺键与壳聚糖结合,形成了梳状<span style=\"color:red\">接枝</span>产物.XRD谱图中,在2θ=8.3°处出现衍射峰,这是因接入侧链使壳聚糖主链堆砌结构发生改变而引起的.DSC、TG/DTG测试发现,<span style=\"color:red\">均相接枝</span>物高温一侧吸放热峰的数量与位置有明显改变,并互有不同,反映出结构和<span style=\"color:red\">接枝</span>量的差异使壳聚糖<span style=\"color:red\">接枝</span>产物具有不同的热稳定性.","authors":[{"authorName":"冯芳","id":"d6947aea-b542-4b3e-8c27-c187e4044187","originalAuthorName":"冯芳"},{"authorName":"刘预","id":"5c639409-e85b-47c9-bad6-30f87473a4e4","originalAuthorName":"刘预"},{"authorName":"胡克鳌","id":"85f291fd-43d4-46bc-a95f-58e3e1133340","originalAuthorName":"胡克鳌"}],"doi":"","fpage":"33","id":"d3a6c460-b4d3-4a8c-ad54-8e38ac07e299","issue":"14","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"e95c1787-da5e-4fd7-aae3-b79683b83bbf","keyword":"壳聚糖","originalKeyword":"壳聚糖"},{"id":"2364406f-14b8-4cf6-89d1-6d9628cf5798","keyword":"L-谷氨酸甲酯","originalKeyword":"L-谷氨酸甲酯"},{"id":"46ccedd7-585c-48c0-ac25-49d72ac3752b","keyword":"<span style=\"color:red\">均相接枝</span>","originalKeyword":"均相接枝"},{"id":"449c241c-638a-4bf5-b1ec-1079a1d25205","keyword":"开环聚合","originalKeyword":"开环聚合"}],"language":"zh","publisherId":"cldb200914010","title":"壳聚糖<span style=\"color:red\">均相接枝</span>L-谷氨酸甲酯的结构与性能","volume":"23","year":"2009"},{"abstractinfo":"系统地研究了甲基丙烯酸缩水甘油酯(GMA)固<span style=\"color:red\">相接枝</span>聚丙烯(PP)的反应工艺,探讨了反应温度、引发剂浓度、单体浓度、反应时间和PP粒径等因素对<span style=\"color:red\">接枝</span>反应的影响关系.采用红外光谱表征了PP-g-GMA,并用WAXD、TGA等研究了<span style=\"color:red\">接枝</span>物的结晶性能和热性能.结果表明,在BPO引发下,于100～140 ℃范围内,GMA和PP可进行固<span style=\"color:red\">相接枝</span>反应,<span style=\"color:red\">接枝</span>率最高可达6%.<span style=\"color:red\">接枝</span>物阻碍了PP β晶型的生成,并提高了热稳定性.","authors":[{"authorName":"阮吉敏","id":"786f3c5b-2b59-447b-ab0c-be6a891d15d3","originalAuthorName":"阮吉敏"},{"authorName":"潘泳康","id":"edf249e0-1d01-42cc-b636-c5d6c78f09ec","originalAuthorName":"潘泳康"},{"authorName":"陈其","id":"8e84da1f-fa6e-4688-9d80-b084c57edec3","originalAuthorName":"陈其"},{"authorName":"周达飞","id":"4076f925-29f5-4847-87b2-0044f68a3ffd","originalAuthorName":"周达飞"}],"doi":"","fpage":"84","id":"8f4d768c-12a2-4bda-bafe-40360be56cbe","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"7437758a-3dd1-44f7-b693-39fe75468822","keyword":"甲基丙烯酸缩水甘油酯","originalKeyword":"甲基丙烯酸缩水甘油酯"},{"id":"6a46828c-2624-47b4-a8f1-f398734e7f41","keyword":"聚丙烯","originalKeyword":"聚丙烯"},{"id":"e6d2b786-5c35-41ac-b8f8-d144250e671a","keyword":"固<span style=\"color:red\">相接枝</span>","originalKeyword":"固相接枝"}],"language":"zh","publisherId":"gfzclkxygc199901022","title":"GMA固<span style=\"color:red\">相接枝</span>PP的研究","volume":"","year":"1999"},{"abstractinfo":"以1-丁基-3-甲基咪唑氯盐([BMIM]Cl)、1-丁基-3-甲基咪唑醋酸盐([BMIM]Ac)为<span style=\"color:red\">均相</span>介质,以二甲基亚砜为非<span style=\"color:red\">均相</span>介质,研究了L-丙交酯与壳聚糖<span style=\"color:red\">接枝</span>共聚物的合成,并考察其<span style=\"color:red\">接枝</span>反应的反应效率,利用红外光谱(FT-IR)、热重分析(TGA)、差示扫描量热仪(DSC)、X射线衍射分析(XRD)等对<span style=\"color:red\">接枝</span>共聚物进行了表征.结果表明,<span style=\"color:red\">均相</span>反应能缩短反应时间,具有更高的反应效率,且在[BMIM]Cl中更高;<span style=\"color:red\">均相接枝</span>共聚物趋于无定型,但其热稳定性高于非<span style=\"color:red\">均相接枝</span>共聚物.","authors":[{"authorName":"韩小进","id":"e131a7ea-9b87-4431-8c25-8ea27f12ca48","originalAuthorName":"韩小进"},{"authorName":"程春祖","id":"5c340fc2-4f29-44e2-893d-4bd7cbc80480","originalAuthorName":"程春祖"},{"authorName":"朱庆松","id":"8988539d-e294-449f-89f2-d28dcaa2bbb0","originalAuthorName":"朱庆松"},{"authorName":"武长城","id":"182efcdd-88f1-4c34-8d3e-6ff777f88c3c","originalAuthorName":"武长城"}],"doi":"","fpage":"20","id":"27b56068-17df-43b7-adba-864b44ae79ce","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"8cc1dfb4-d4b7-4e22-b997-b1e4f31da510","keyword":"壳聚糖","originalKeyword":"壳聚糖"},{"id":"918a983c-8607-492f-a902-c74514535984","keyword":"L-丙交酯","originalKeyword":"L-丙交酯"},{"id":"03ea50ac-e29f-4acb-bcae-95c37240873f","keyword":"<span style=\"color:red\">接枝</span>共聚","originalKeyword":"接枝共聚"},{"id":"ff891a6f-4ae4-4305-9724-eedbf47d44a7","keyword":"<span style=\"color:red\">均相</span>","originalKeyword":"均相"},{"id":"0841ae9e-07aa-4e43-bb41-f3f119f6cbca","keyword":"非<span style=\"color:red\">均相</span>","originalKeyword":"非均相"}],"language":"zh","publisherId":"gfzclkxygc201101006","title":"壳聚糖与L-丙交酯<span style=\"color:red\">接枝</span>共聚物的<span style=\"color:red\">均相</span>和非<span style=\"color:red\">均相</span>合成","volume":"27","year":"2011"},{"abstractinfo":"以过氧化苯甲酰(BPO)、过氧化二异丙苯(DCP)为引发剂,用固<span style=\"color:red\">相接枝</span>法在聚丙烯(PP)粉表面<span style=\"color:red\">接枝</span>马来酸酐(MAH).研究了引发剂浓度、单体浓度、反应温度及时间等因素对<span style=\"color:red\">接枝</span>率的影响,并采用X射线光电子能谱(XPS)与广角X射线衍射(WAXD)对MAH-g-PP的<span style=\"color:red\">接枝</span>效果和晶态结构进行了表征.","authors":[{"authorName":"顾辉","id":"6f3d1e78-4bdd-4753-a10e-8e8529d8dc51","originalAuthorName":"顾辉"},{"authorName":"柴超","id":"e270ff61-8f8c-4250-b252-531d88efe8d9","originalAuthorName":"柴超"},{"authorName":"张志谦","id":"999597e2-862e-4651-b472-d9aa59b1e68c","originalAuthorName":"张志谦"},{"authorName":"魏月贞","id":"a7d1c824-389a-4e88-bdb0-12d5c7311679","originalAuthorName":"魏月贞"}],"doi":"10.3969/j.issn.1001-4381.1999.01.003","fpage":"10","id":"1de072fe-8343-47aa-a6c8-c3204222fdc2","issue":"1","journal":{"abbrevTitle":"CLGC","coverImgSrc":"journal/img/cover/CLGC.jpg","id":"9","issnPpub":"1001-4381","publisherId":"CLGC","title":"材料工程"},"keywords":[{"id":"903117b0-af73-4759-9d27-803f6e838a7b","keyword":"PP粉","originalKeyword":"PP粉"},{"id":"9778add9-3663-455d-ba4e-162635a244c6","keyword":"固<span style=\"color:red\">相接枝</span>","originalKeyword":"固相接枝"},{"id":"572c6a46-a6e3-42b8-bdfd-1620d8b7a8b4","keyword":"马来酸酐","originalKeyword":"马来酸酐"},{"id":"303c09e7-90b0-4192-ba64-4517d21e723b","keyword":"<span style=\"color:red\">接枝</span>率","originalKeyword":"接枝率"}],"language":"zh","publisherId":"clgc199901003","title":"PP粉表面固<span style=\"color:red\">相接枝</span>及其表征","volume":"","year":"1999"},{"abstractinfo":"研究了低等规度聚丙烯(LIPP)固<span style=\"color:red\">相接枝</span>马来酸酐(MAH).红外谱图证实了MAH成功地<span style=\"color:red\">接枝</span>在LIPP链上.用化学滴定法测定了<span style=\"color:red\">接枝</span>物的<span style=\"color:red\">接枝</span>率,考察了<span style=\"color:red\">接枝</span>率与单体,引发剂和时间的关系.另外将LIPP按等规度进行分级,用NMR对每个级份进行了表征.最后将<span style=\"color:red\">接枝</span>物也分级,测定了每个级份的<span style=\"color:red\">接枝</span>率,探讨了等规度与<span style=\"color:red\">接枝</span>率的关系.","authors":[{"authorName":"陶颖","id":"17151ccd-0daf-45a2-8205-07545ae92a94","originalAuthorName":"陶颖"},{"authorName":"李剑","id":"d4e56eb6-7532-4525-9492-b16d76ee42b9","originalAuthorName":"李剑"},{"authorName":"周持兴","id":"721464aa-9947-4bb6-a36b-e2879fc71821","originalAuthorName":"周持兴"}],"doi":"","fpage":"72","id":"82dd8d33-29e3-41c5-9a32-5251095dc731","issue":"4","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"523297f2-8423-4cb4-b378-41977faceeae","keyword":"聚丙烯","originalKeyword":"聚丙烯"},{"id":"db15718c-714f-45a4-970a-03dbb58240ed","keyword":"<span style=\"color:red\">接枝</span>","originalKeyword":"接枝"},{"id":"9fb4755e-b9ef-41cf-9dbc-8c6c98a3e772","keyword":"马来酸酐","originalKeyword":"马来酸酐"},{"id":"2726e3b7-aede-4ac3-bd43-681f44ec2a07","keyword":"等规度","originalKeyword":"等规度"}],"language":"zh","publisherId":"gfzclkxygc200304018","title":"低等规度聚丙烯固<span style=\"color:red\">相接枝</span>","volume":"19","year":"2003"},{"abstractinfo":"对淀粉进行了流变<span style=\"color:red\">相接枝</span>改性, 测定织造区域内经纱表面浆膜温度, 分析了PVA共混浆膜及原淀粉共混浆膜的动态力学行为。结果表明: 在经纱表面浆膜的温度28.3--35.1℃范围内PVA共混浆膜的阻尼特性优于原淀粉共混浆膜, 其储能模量(400--450 MPa)和耗能模量(25--30 MPa)均远大于原淀粉共混浆膜的储能模量($&lt;$50 MPa)和耗能模量($&lt;$5 MPa); 经流变<span style=\"color:red\">相接枝</span>改性后, <span style=\"color:red\">接枝</span>淀粉的储能模量和耗能模量分别达到500--520 MPa和35--40 MPa, 分别提高了900\\%和600\\%。流变<span style=\"color:red\">相接枝</span>改性改善了原淀粉共混浆膜的阻尼特性, 解决了浆膜脆、硬、落浆落物等问题。","authors":[{"authorName":"王建坤韩大伟吕海荣","id":"2f39ae62-2e3a-4a48-a0fa-c5dff27e62c5","originalAuthorName":"王建坤韩大伟吕海荣"}],"categoryName":"|","doi":"","fpage":"348","id":"28c576e2-ee36-49e9-a76e-440f01d40d43","issue":"4","journal":{"abbrevTitle":"CLYJXB","coverImgSrc":"journal/img/cover/CLYJXB.jpg","id":"16","issnPpub":"1005-3093","publisherId":"CLYJXB","title":"材料研究学报"},"keywords":[{"id":"fa4a9745-20ca-43c1-bf9e-ef0bc73ea8ed","keyword":"高分子材料 ","originalKeyword":"高分子材料 "},{"id":"6744ee02-7db4-486a-8187-44327c8c18ca","keyword":" &nbsp;textile sizing starch ","originalKeyword":" &nbsp;textile sizing starch "},{"id":"01a2f473-0cae-49ed-aaff-a01cb42c88bb","keyword":" &nbsp;grafted by rheological phase method ","originalKeyword":" &nbsp;grafted by rheological phase method "},{"id":"b29e20d8-3636-4d7c-9b21-c703769bac1d","keyword":" &nbsp;damping characteristic","originalKeyword":" &nbsp;damping characteristic"}],"language":"zh","publisherId":"1005-3093_2010_4_4","title":"基于阻尼特性的淀粉流变<span style=\"color:red\">相接枝</span>改性","volume":"24","year":"2010"},{"abstractinfo":"对淀粉进行了流变<span style=\"color:red\">相接枝</span>改性,测定织造区域内经纱表面浆膜温度,分析了PVA共混浆膜及原淀粉共混浆膜的动态力学行为.结果表明:在经纱表面浆膜的温度28.3-35.1℃范围内PVA共混浆膜的阻尼特性优于原淀粉共混浆膜,其储能模量(400-450 MPa)和耗能模量(25-30 MPa)均远大于原淀粉共混浆膜的储能模量(<50 MPa)和耗能模量(<5 MPa);经流变<span style=\"color:red\">相接枝</span>改性后,<span style=\"color:red\">接枝</span>淀粉的储能模量和耗能模量分别达到500-520 MPa和35-40 MPa,分别提高了900%和600%.流变<span style=\"color:red\">相接枝</span>改性改善了原淀粉共混浆膜的阻尼特性,解决了浆膜脆、硬、落浆落物等问题.","authors":[{"authorName":"王建坤","id":"400fac81-8362-4987-8cff-bbfa7261ad1c","originalAuthorName":"王建坤"},{"authorName":"韩大伟","id":"98d861bb-3694-4403-ba51-20be8033d2e4","originalAuthorName":"韩大伟"},{"authorName":"吕海荣","id":"ac12797a-6ddd-4e51-9dd0-fe20a3991970","originalAuthorName":"吕海荣"}],"doi":"","fpage":"348","id":"08445775-3051-4f68-b506-840696eb84ea","issue":"4","journal":{"abbrevTitle":"CLYJXB","coverImgSrc":"journal/img/cover/CLYJXB.jpg","id":"16","issnPpub":"1005-3093","publisherId":"CLYJXB","title":"材料研究学报"},"keywords":[{"id":"767a8aa2-6d46-4789-a4af-5745112aa128","keyword":"高分子材料","originalKeyword":"高分子材料"},{"id":"bbdcb0fa-3e99-4f58-9bef-0b988282eeb2","keyword":"纺织浆料","originalKeyword":"纺织浆料"},{"id":"0ae2cdad-9b85-4828-8949-265453c78b30","keyword":"流变<span style=\"color:red\">相接枝</span>","originalKeyword":"流变相接枝"},{"id":"9d56e592-98b2-429b-9bf3-a2abd36ebcf3","keyword":"阻尼特性","originalKeyword":"阻尼特性"}],"language":"zh","publisherId":"clyjxb201004003","title":"基于阻尼特性的淀粉流变<span style=\"color:red\">相接枝</span>改性","volume":"24","year":"2010"},{"abstractinfo":"采用气<span style=\"color:red\">相接枝</span>方法研究了硅烷交联聚丙烯材料.探讨了在过氧化物作用下乙烯基三甲氧基硅烷(VTMS)气体在聚丙烯粉末表面进行气<span style=\"color:red\">相接枝</span>反应的机理,及引发剂过氧化二异丙苯(DCP)和VTMS单体浓度对硅烷<span style=\"color:red\">接枝</span>率和水解交联产物凝胶含量的影响.用富里叶变换红外光谱(FTIR)和富里叶变换红外光声光谱(FTIR-PAS)对反应产物进行了分析.结果表明,单体和引发剂在聚丙烯中的扩散情况对硅烷<span style=\"color:red\">接枝</span>率存在较大影响.增加引发剂和硅烷单体的用量,硅烷的<span style=\"color:red\">接枝</span>率上升,其增加趋势在单体浓度为0.026 mol/L和引发剂质量分数大于0.6%后逐渐变缓.","authors":[{"authorName":"胡淼","id":"f466ee63-8b9b-4512-8854-88c7021eea92","originalAuthorName":"胡淼"},{"authorName":"王正洲","id":"a44b2603-3a5b-41bb-be43-a6881ebf5659","originalAuthorName":"王正洲"},{"authorName":"瞿保钧","id":"342fcaf9-6aec-4482-bd4f-4aee043af8da","originalAuthorName":"瞿保钧"}],"doi":"10.3969/j.issn.1000-0518.2006.04.001","fpage":"349","id":"59cdd747-2aef-4fc2-b750-c48cf7cf7c5d","issue":"4","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"fd7e40b2-db32-48af-9325-0174f0508814","keyword":"聚丙烯","originalKeyword":"聚丙烯"},{"id":"f20c86a2-c8c7-4f7a-b418-2c230033cfe0","keyword":"气<span style=\"color:red\">相接枝</span>","originalKeyword":"气相接枝"},{"id":"ac009d3f-40f0-4593-bfd5-93490f44dd78","keyword":"硅烷交联","originalKeyword":"硅烷交联"}],"language":"zh","publisherId":"yyhx200604001","title":"硅烷气<span style=\"color:red\">相接枝</span>水解交联聚丙烯","volume":"23","year":"2006"},{"abstractinfo":"研究了马来酸酐(MAH)固<span style=\"color:red\">相接枝</span>微晶纤维素(MCC)的反应工艺,并通过红外光谱、X射线衍射对微晶纤维素及其<span style=\"color:red\">接枝</span>产物进行了对比表征.红外结果表明,<span style=\"color:red\">接枝</span>产物在1719.13 cm~(-1)处出现了酯基的伸缩振动吸收峰,可定性地说明马来酸酐与微晶纤维素发生了<span style=\"color:red\">接枝</span>反应.X射线衍射结果表明,<span style=\"color:red\">接枝</span>反应并没有改变微晶纤维素的结晶结构,仅使其结晶度下降.文中探讨了<span style=\"color:red\">接枝</span>反应温度、时间和MAH用量等因素对<span style=\"color:red\">接枝</span>取代度的影响.当马来酸酐与微晶纤维素质量比为8%,反应温度90℃,反应时间3 h,可得到取代度达0.1的马来酸酐<span style=\"color:red\">接枝</span>微晶纤维素.","authors":[{"authorName":"刘亮","id":"84c360fc-28d9-432d-90e5-88f9630ab89f","originalAuthorName":"刘亮"},{"authorName":"杨伟","id":"3654173b-f1ce-4617-abbd-3ab82625aa90","originalAuthorName":"杨伟"},{"authorName":"杨鸣波","id":"0fc41454-1ba3-40b0-8f47-5bd3a0179cb1","originalAuthorName":"杨鸣波"}],"doi":"","fpage":"127","id":"35dab617-5aa8-4f87-8384-6da3e61921bd","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"188ad0f9-a628-4ee5-b68b-fec64a6cd0c0","keyword":"微晶纤维素","originalKeyword":"微晶纤维素"},{"id":"6cabcb27-8e8f-4602-b77a-77e8cc1696de","keyword":"马来酸酐","originalKeyword":"马来酸酐"},{"id":"74e017a2-e08c-4108-bdde-62b97e178a40","keyword":"固<span style=\"color:red\">相接枝</span>","originalKeyword":"固相接枝"}],"language":"zh","publisherId":"gfzclkxygc201003035","title":"马来酸酐固<span style=\"color:red\">相接枝</span>微晶纤维素","volume":"26","year":"2010"},{"abstractinfo":"在力化学法钛白聚苯乙烯固<span style=\"color:red\">相接枝</span>改性工艺的基础上,应用多种检测手段研究了力化学法钛白聚苯乙烯固<span style=\"color:red\">相接枝</span>改性的机理,并建立了钛白表面聚苯乙烯<span style=\"color:red\">接枝</span>模型,认为力化学法钛白聚苯乙烯固<span style=\"color:red\">相接枝</span>改性的机理主要是自由基聚合反应.","authors":[{"authorName":"毋伟","id":"764b0e29-988f-4395-bc1f-0245cd166fed","originalAuthorName":"毋伟"},{"authorName":"陈建锋","id":"6165e384-6edf-49f5-96ba-74f0bba671f6","originalAuthorName":"陈建锋"},{"authorName":"卢寿慈","id":"8baba3d1-1832-4098-92d1-dd9dfee17a38","originalAuthorName":"卢寿慈"}],"doi":"","fpage":"30","id":"9d6ae801-703d-4cf7-b412-6ea2d0096426","issue":"3","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"ac812643-4442-46b2-a326-e60e87e9eae3","keyword":"力化学","originalKeyword":"力化学"},{"id":"902f771d-f373-439c-80ec-ea726b8d3d9f","keyword":"钛白","originalKeyword":"钛白"},{"id":"4627f9e5-16c8-4d9a-a097-ab743e1ffbc2","keyword":"聚苯乙烯","originalKeyword":"聚苯乙烯"},{"id":"a8d44148-ccc0-41c7-b564-c72d4bc7c083","keyword":"<span style=\"color:red\">接枝</span>模型","originalKeyword":"接枝模型"},{"id":"d99d2472-4371-4d50-9cb5-0cd2a817af28","keyword":"机理","originalKeyword":"机理"}],"language":"zh","publisherId":"gfzclkxygc200203007","title":"力化学法钛白聚苯乙烯固<span style=\"color:red\">相接枝</span>改性机理研究","volume":"18","year":"2002"}],"totalpage":300,"totalrecord":2994}