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STUDY OF AMORPHOUS Fe-Zr-B-(Cu) ALLOYS BY MECHANICAL ALLOYING

ZHANG Jianqiang , WU Bingyao Southeast University , Nanjing , China WU Hiaohua , WANG Guiqin , ZHAO Jiwan Nanjing University , China Manuscript received 10 March 1995

金属学报(英文版)

The technique of mechanical alloying(MA) for preparing amorphous Fe-Zr-B-(Cu) alloys has been studied The structure of samples was analysed by X-ray diffractometry, electron microscopy and Mssbauer spectroscopy.The results show that Fe78Zr10B12 sample of a nearly complete amorphous phase may be prepared but in Fe91Zr7B2 sample metastable b c c phase was obtained Using the same procedure a mixture of amorphous phase and α-Fe(Zr, B) was generated in Fe85Zr7B8. Furthermore,the results of Mssbauer reveal that there are two kinds of short-range ordered phases in the sample. While adding Iat% Cu in Fe78Zr10B12 or Fe85Zr7B8 sample, it is found that the hyperfine field of amorphous phases decreases significantly.

关键词: : mechanical alloying , null , null

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