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Characterization of Rust Layer Formed on Low Alloy Steel Exposed in Marine Atmosphere

Quancheng ZHANG , Jiansheng WU , Wenlong ZHENG , Jianjun WANG , Jiaguang CHEN , Xiaofang YANG , Aibai LI

材料科学技术(英文)

The iron rust phases formed on low alloy steels containing different quantities of Cr element have been characterized using EPMA, Raman spectroscopy, TEM, optical microscopy etc. The ion selective properties of synthesized rust films with the same phase constituent as the atmospheric corrosion products were investigated using self-made apparatus. The results showed that corrosion loss of steels exposed in marine atmosphere decreased rapidly as the Cr content of the steel was increased. Cr-containing steels were covered by a uniform compacted rust layer composed of fine particles with an average diameter of several nanometers. Inner rust layer of Cr-containing steel (2 mass fraction) was composed of a-CrxFe1-xOOH, with Cr content of about 5 mass fraction. Such rust layer showed cation selective property, and could depress the penetration of Cl- to contact substrate steel directly.

关键词: Corrosion , null , null , null

Analysis of Orange Peel Defect in St14 Steel Sheet by Electron Backscattered Diffraction (EBSD)

Shengquan CAO , Jinxu ZHANG , Jiansheng WU , Jiaguang CHEN

材料科学技术(英文)

In this paper, the orange peel defect in the surface range of the st14 steel sheet has been investigated using the electron backscattered diffraction (EBSD) technique. It has been found that the orange peel defect in the st14 steel sheet was resulted from the local coarse grains which were produced during hot-rolling due to the critical deformation in dual-phase zone. During deep drawing, the coarse grains with {100}<001> microtexture can slip on the {112}<111> slip system to form bulging and yields orange peel defects, while the coarse grains with {112}<110> orientation do not form the defect as the Schmid factor of {112}<111> slip system in it equals zero.

关键词: Electron backscattered diffraction (EBSD) , null , null , null

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