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Pressure-Induced Structural Transitions of the Zinc Sulfide Nano-particles with Different Sizes

Yuewu PAN , Jie YU , Zhan HU , Hongdong LI , Qiliang CUI , Guangtian ZOU , null , null , null

材料科学技术(英文)

ZnS nano-particles with average sizes of 10 nm and 5 nm were fabricated by sol-gel method, and their pressure-induced phase transformations were in-situ examined in a diamond anvil cell by energy dispersive X-ray diffraction (EDXD) from ambient pressure to 35.0 GPa. From the obtained interplanar spacing data, the volume compression ratios were derived at different pressures, and then the bulk modulus and its pressure derivative were obtained by fitting to the Murnaghan equation. It is found that both ZnS nano-particles initially in the zinc-blende phase transformed to cubic NaCl structure in the presence of pressure and the transition was reversible when the pressure was released. Moreover, it is suggested that a smaller particle size will induce a larger transition pressure.

关键词: Nano-particles , null , null , null

Study on Non-interlayer Liquid Phase Diffusion Bonding for SiCp/ZL101 Aluminum Matrix Composite

Wei GUO , Jitai NIU , Jinfan ZHAI , Changli WANG , Jie YU , Guangtao ZHOU

材料科学技术(英文)

Through the vacuum diffusion bonding for SiCp/ZL101 aluminum matrix composite, the influence of bonding parameters on the joint properties was reported, with the aim to obtain optimal bonding parameters. The microstructure of joints was analyzed by means of optical microscope and scanning electron microscope in order to study the relationship between the macro-properties of joints and the microstructures. It was found that diffusion bonding could be used for bonding aluminum matrix composites successfully. Meanwhile, the properties of the matrix and the joint were all affected by some defects such as the reinforcement aggregation in aluminum matrix composites made by stirring casting.

关键词: Aluminum matrix composite , null , null , null

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