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DIFFERENTIAL SCANNING CALORIMETRY AND X-RAY DIFFRACTION STUDIES ON AGING BEHAVIOR OF Zn-Al ALLOYS

X.L. Xu , Z.W. Yu , S.J. Ji

金属学报(英文版)

Decomposition processes of the quenched Zn-Al alloys were studied by differentiai scanning calorimetry (DSC), X-ray diffraction (XRD) and transmission electron microscopy (TEM). The results show that the stabilities of supersaturated solid solution (SSS) of Zn-Al alloy and c' phase formed by quenching would reduce with increasing Zn content and precipitating η-Zn phases even when aging at ambient temperature,so that exothermic precipitation peak in DSC curve would disappear. The activation energy of the η-Zn precipitation and their reaction enthalpy were calculated and measured. The kinetics of α' decomposition or η-Zn formation was determined by XRD.The microstructure change during aging was observed by TEM.

关键词: differential scanning calorimetry (DSC) , null , null , null

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