Z.H. Zou
,
X.M. Yu
,
B.S. Zhang
,
Y. Qi
,
null
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null
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null
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null
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null
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null
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null
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null
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null
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null
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null
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null
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金属学报(英文版)
A reactive co-deposition processing for obtaining high-quality single-phase Bi2Sr2Cax-1CuxOy (Bi2212) thin films has been investigated using molecular beam epitaxy (MBE) with 2.7 × 10-3Pa ozone gas introduction for oxidation. The thin films with a constant composition of almost 2 : 2 : 1 : 2 were designed to be fabricated at the substrate temperature between 675 and 780℃, the substrate temperature dependence of the surface morphology and the emergence phases were investigated in detail. A noticeable result is that the distribution of Cu element in the thin films is sensitively changed with the substrate temperature. At 750℃ it is inclined to locate in the periphery of each grain through the diffusion process. At 780℃ the Cu-compositional fluctuation brought around the dendritic crystal growth in the thin films. Below 705℃, the Bi2212 single-phase cannot be achieved in the thin films.
关键词:
Bi2212 (Bi2Sr2Cax-1CuxOy) single-phase
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null
H.Z. Yang
,
X.G. Sun
,
W.Q.Huang
,
M.L. Li
,
X.M. Yu
,
B.S.Zhang
,
Y.Qi
,
Q. Zhao
金属学报(英文版)
An electrochemical technique has been introduced and applied to fabricate superconducting MgB2 films in molten salts. MgCl2, Mg(BO2)2, NaCl, and KCl were used as electrolyte, graphite was used as the anode, and copper was used as the cathode, respectively. X-ray diffraction (XRD) analysis was chosen to investigate the phase composition and crystallinity of the films at different electrolysis temperatures. Standard four-probe technique and SQUID were applied to investigate the temperature dependence of resistance (R-T) properties and magnetic properties of the films, respectively. The results indicate that MgB2 films have been fabricated on the copper cathodes, and superconducting transition takes place close to 50 K.
关键词:
MgB2 film
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null
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